Phenoxo bridged dinuclear Zn(II) Schiff base complex as new precursor for preparation zinc oxide nanoparticles: Synthesis, characterization, crystal structures and photoluminescence studies
Source abstract
Abstract
Abstract Nanoparticles of a novel Zn(II) Schiff base complex, [Zn(HL)NO3]2 (1), (H2L = 2-[(2-hydroxy-propylimino) methyl] phenol), was synthesized by using solvothermal method. Shape, morphology and chemical structure of the synthesized nanoparticles were characterized by scanning electron microscopy (SEM), X-ray powder diffraction (XRD), Fourier Transform Infrared Spectoscopy (FT-IR) and UV–vis spectroscopy. Structural determination of compound 1 was determined by single-crystal X-ray diffraction. The results were revealed that the zinc complex is a centrosymmetric dimer in which deprotonated phenolates bridge the two five-coordinate metal atoms and link the two halves of the dimer. The thermal stability of compound 1 was analyzed by thermal gravimetric analysis (TGA) and differential scanning calorimetry (DSC). The effect of the initial substrates concentration and reaction time on size and morphology of compound 1 nanostructure was investigated as well. Furthermore, the luminescent properties of the complex 1 were examined. ZnO nanoparticles with diameter between 15 and 20 nm were simply synthesized by solid-state transformation of compound 1 at 700 °C.
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Research context
OpenAlex topics: Metal-Organic Frameworks: Synthesis and Applications · Metal complexes synthesis and properties · Nonlinear Optical Materials Research
SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.
References (47)
Show source-provided references
1. Cyanido-bridged heterometallic oligonuclear complexes and coordination polymers constructed using tridentate Schiff-base ligands: synthesis crystal structures, and magnetic and luminescence properties10.1021/cg2016947 ↗
2. Syntheses, structures and properties of pentacoordinated zinc(II) halide complexes containing a tridentate Schiff base as end capping ligand
3. Synthesis and structures of tridentate ketoiminate zinc complexes that act as l-lactide ring-opening polymerization catalysts10.1021/om200865w ↗
4. Influence of co-ligands in synthesis, photoluminescence behavior and catalytic activities of zinc complexes of 2-((E)-((pyridin-2-yl) methylimino) methyl) phenol10.1016/j.poly.2014.08.011 ↗
5. Three new pseudohalide bridged dinuclear Zn(II), Cd(II) complexes of pyrimidine derived Schiff base ligands: synthesis, crystal structures and fluorescence studies10.1016/j.poly.2011.11.031 ↗
6. Synthesis characterization, crystal structure. DNA- and HSA-binding studies of a dinuclear Schiff base Zn(II) complex derived from 2-hydroxynaphtaldehyde and 2-picolylamine10.1016/j.molstruc.2015.04.033 ↗
7. Molecular structures of dinuclear zinc(II) complexes of chiral tridentate imine and amine ligands: effect of ligand geometry on diastereoselectivity10.1016/j.ica.2012.06.041 ↗
8. Crystal structure and magnetic interactions in nickel(II) dibridged complexes formed by two azide groups or by both phenolate oxygen-Azide −thiocyanate-carboxylate, or −cyanate groups10.1021/ic0352553 ↗
9. Metal–organic framework materials as catalysts10.1039/b807080f ↗
10. Low temperature X-ray diffraction analysis electronic density distribution and photophysical properties of bidentate N,O-donor salicylaldehyde Schiff bases and zinc complexes in solid state10.1016/j.jphotochem.2010.12.011 ↗
11. Spectroscopic crystal structural and electrochemical studies of Zinc(II)-Schiff base complex obtained from 2 3-diaminobenzeneand 2-hydroxy naphthaldehyde10.1016/j.saa.2014.07.034 ↗
12. Synthesis structure, photo- and electroluminescent properties of zinc(II) complexes with aminomethylene derivatives of 1-phenyl-3-methyl-4-formylpyrazol-5-one and 3- and 6-aminoquinolines10.1016/j.synthmet.2015.02.028 ↗
13. Structural influence of counter-ions in lead(II) complexes:[Pb (phen)n (NO2) X], X=CH3COO− NCS− and, phen=1. 10-phenanthroline10.1016/j.solidstatesciences.2005.08.013 ↗
14. Sonochemical syntheses of strawberry-like nano-structure mixed-ligand lead(II) coordination polymer: thermal, structural and X-ray powder diffraction studies10.1016/j.ica.2009.12.049 ↗
15. Sonochemical synthesis of a new nano-plate lead(II) coordination polymer constructed of maleic acid10.1016/j.ica.2010.04.024 ↗
16. Controlled multiscale synthesis of porous coordination polymer in nano/micro regimes10.1021/cm101778g ↗
17. Sonochemical syntheses of a new nano-sized porous lead(II) coordination polymer as precursor for preparation of lead(II) oxide nanoparticles10.1016/j.molstruc.2009.07.041 ↗
18. Thermolysis preparation of zinc(II) oxide nanoparticles from a new micro-rods one-dimensional zinc(II) coordination polymer synthesized by ultrasonic method10.1016/j.ica.2011.07.012 ↗
19. Preparation and characterization of ZnO nanoparticles by a novel sol-gel route10.1016/j.matlet.2006.11.089 ↗
20. Sonochemical synthesis of a novel nano-rod two-dimensional zinc(II) coordination polymer; preparation of zinc(II) oxide nanoparticles by direct thermolyses10.1016/j.ultsonch.2010.09.017 ↗
21. MERCURY 1.4.1, Copyright Cambridge Crystallographic Data Centre, 12 Union Road, Cambridge, CB 2 1EZ, UK, 2001–2005.
22. X-AREA, version 1.30, program for the acquisition and analysis of data, Stoe & Cie GmbH, Darmstadt, Germany, 2005.
23. X-RED, version 1.28b, program for data reduction and absorption correction, Stoe & Cie GmbH, Darmstadt, Germany, 2005.
24. X-SHAPE, version 2.05, program for crystal optimization for numerical absorption correction, Stoe & Cie GmbH, Darmstadt, Germany, 2004.
25. SIR2004: an improved tool for crystal structure determination and refinement10.1107/S002188980403225X ↗
26. A short history of SHELX10.1107/S0108767307043930 ↗
27. Conley · 1966
28. Nakamoto · 1986
29. Synthesis spectroscopic, photoluminescence properties and biological evaluation of novel Zn(II) and Al(III) complexes of NOON tetradentate Schiff bases10.1016/j.saa.2012.06.023 ↗
30. Infrared combination frequencies in coordination complexes containing nitrate groups in various coordination environments. A probe for the metal-nitrate interaction10.1139/v71-315 ↗
31. Group IV organometallic compounds.: IX. Preparation and spectroscopic studies of complexes of bis (β-carbomethoxyethyl) tin dichloride10.1016/S0020-1693(00)90475-4 ↗
32. Tandon · Inorg. Chim. Acta · 2000 · 300–302 · 68310.1016/S0020-1693(00)00010-4 ↗
33. Tandon · Inorg. Chim. Acta · 1994 · 219 · 5510.1016/0020-1693(94)03818-X ↗
34. Synthesis, structure, and spectroscopic properties of copper(II) compounds containing nitrogen–sulphur donor ligands; the crystal and molecular structure of aqua [1,7-bis (N-methylbenzimidazol-2′-yl)-2, 6-dithiaheptane] copper(II) perchlorate10.1039/DT9840001349 ↗
35. Synthesis, characterization, X-ray structure, spectroscopic and electrochemical studies of copper and zinc complexes with two new polydentate ligands10.1016/j.ica.2014.01.039 ↗
36. Synthesis, characterization and luminescent property of a novel zinc(II) 1,2,3,4-tetra(4-pyridyl) thiophenemetal-organic framework10.1016/j.inoche.2009.07.027 ↗
37. Blue to red fluorescent emission tuning of a cadmium coordination polymer by conjugated ligands10.1002/ejic.200300230 ↗
38. A Zn(II) ion selective fluorescence sensor that is not affected by Cd(II)10.1016/j.tetlet.2007.08.040 ↗
39. Zinc(II) complexes with 1,8-naphthyridinebased ligand: crystal structures and luminescent properties10.1016/j.ica.2007.11.035 ↗
40. Three new pseudohalide bridged dinuclear Zn(II) Schiff base complexes: synthesis, crystal structures and fluorescence studies10.1016/j.poly.2007.07.025 ↗
41. A new Schiff base system bearing two naphthalene groups as fluorescent chemodosimeter for Zn2+ ion and its logic gate behavior10.1016/j.saa.2011.10.013 ↗
42. Interactions of transition-metal ions with photoexcited states of flavines. Fluorescence quenching studies10.1021/ja00758a037 ↗
43. Zn(II)-azide complexes of diimine and azoimine functions: synthesis, spectra and X-ray structures10.1016/j.poly.2006.01.033 ↗
44. Three zinc(II) complexes constructed from aromatic dicarboxylate and 1,4-bis((2-(pyridin-2-yl)-1H-imidazol- 1-yl) methyl) benzene: syntheses, crystal structures and luminescent properties10.1016/j.ica.2010.07.047 ↗
45. Synthesis and crystallization of fine SiC-Si3N4 composite powders by a vapor phase reaction
46. Morphology of nanometric size particulate aluminium-doped zinc oxide films10.1016/S0927-7757(01)00959-1 ↗
47. Sol–gel preparation of transparent zinc oxide films with highly preferential crystal orientation10.1016/j.vacuum.2004.08.003 ↗