Novel environmentally friendly synthesis of superparamagnetic magnetite nanoparticles using mechanochemical effect

A novel method for synthesizing superparamagnetic magnetite nanoparticles in water system via coprecipitation under an environmentally friendly condition has been developed. In this method, an almost neutral suspension containing ferrous hydroxide and goethite is used as the starting suspension and subjected to a ball-milling treatment. The product was characterized by transmission electron microscopy, X-ray diffraction, energy dispersive X-ray spectroscopy, dynamic light scattering, superconducting quantum interference device magnetometry, and Mossbauer spectroscopy. The mechanochemical effect generated by the ball-milling treatment promoted the reaction between ferrous hydroxide and goethite even at room temperature, resulting in the formation of homogeneous magnetite nanoparticles. Simultaneously, it also contributed to crystallize the formed magnetite nanoparticles while inhibiting the particle growth. This resulted in the formation of ultrafine magnetite nanoparticles of about 10 nm having a single crystal structure. This method could provide ferromagnetic magnetite nanoparticles with superparamagnetism under the moderate condition without neither heating nor any additives such as surfactant and organic solvent.