Synthesis, structure and properties of Pb2CuB2O6
Source abstract
Abstract
Abstract Single crystals of Pb2CuB2O6 were grown from a PbO/CuO/B2O3 flux, and crystallize in a monoclinic cell of dimensions a = 5.6311(6), b = 8.7628(9), c = 6.2025(6) A, and β = 115.7060(10)° with Z = 2; the space group is P21/c (no. 14). The structure was determined from 662 unique reflections and refined to the final residuals R1 = 0.0217, w R2 = 0.0586. The structure is characterized by the two-dimensional layer of interconnected rectangular planar CuO4 and triangular planar BO3 groups. The results of quantitative analysis ICP, DTA, vibrational spectroscopy, and magnetic investigations are also presented.
Source: openaire · Quality: candidate unverified · Source record ↗
Research context
OpenAlex topics: Advanced Condensed Matter Physics · Crystal Structures and Properties · High-pressure geophysics and materials
SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.
References (35)
Show source-provided references
1. Hiroi · J. Solid State Chem. · 1991 · 95 · 23010.1016/0022-4596(91)90394-W ↗
2. Azuma · Phys. Rev. Lett. · 1994 · 73 · 346310.1103/PhysRevLett.73.3463 ↗
3. Eccleston · Phys. Rev. Lett. · 1998 · 81 · 170210.1103/PhysRevLett.81.1702 ↗
4. Vander Griend · J. Am. Chem. Soc. · 1999 · 121 · 478710.1021/ja984436e ↗
5. Azuma · Phys. Rev. · 2000 · 62B · R358810.1103/PhysRevB.62.R3588 ↗
6. Kageyama · Phys. Rev. Lett. · 1999 · 82 · 316810.1103/PhysRevLett.82.3168 ↗
7. Miyahara · Phys. Rev. Lett. · 1999 · 82 · 370110.1103/PhysRevLett.82.3701 ↗
8. Kodama · Science · 2000 · 298 · 39510.1126/science.1075045 ↗
9. Chen · Sci. Sin. · 1984 · B7 · 597
10. Chen · J. Opt. Soc. Am. · 1989 · B6 · 61610.1364/JOSAB.6.000616 ↗
11. Wu · Appl. Phys. Lett. · 1993 · 62 · 261410.1063/1.109262 ↗
12. Mei · J. Appl. Phys. · 1993 · 74 · 701410.1063/1.355060 ↗
13. Chen · Nature · 1995 · 373 · 32210.1038/373322a0 ↗
14. Mori · Jpn. J. Appl. Phys. · 1995 · 34 · 29610.1143/JJAP.34.L296 ↗
15. Chen · J. Appl. Phys. · 1995 · 77 · 226810.1063/1.358814 ↗
16. Aka · Eur. J. Solid State Inorg. Chem. · 1996 · 23 · 727
17. Zargarova · Inorg. Mater. · 1997 · 33 · 1235
18. SAINT-Plus, Version 6.02A; Bruker Analytical X-Ray Instruments Inc., Madison, WI, 2000.
19. Sheldrick · 2003
20. Bruker SMART Version 5.054, and SADABS Version 2.05, Bruker Analytical X-ray Systems Inc., Madison, WI, 2003.
21. Belokoneva · Crystallogr. Rep. · 2002 · 47 · 1710.1134/1.1446903 ↗
22. Corker · Acta Crystallogr. · 1996 · 52B · 26010.1107/S0108768195013310 ↗
23. Smith · Acta Crystallogr. · 1990 · 46C · 370
24. Behm · Acta Crystallogr. · 1982 · 38B · 278110.1107/S0567740882009947 ↗
25. Koenig · Z. Anorg. Allg. Chem. · 1977 · 434 · 22510.1002/zaac.19774340128 ↗
26. Vegas · Acta Crystallogr. · 1975 · 31B · 141610.1107/S0567740875005316 ↗
27. Pardo · Acta Crystallogr. · 1974 · 30B · 3710.1107/S0567740874002160 ↗
28. Brown · Acta Crystallogr. · 1985 · 41B · 24410.1107/S0108768185002063 ↗
29. Brese · Acta Crystallogr. · 1991 · 47B · 19210.1107/S0108768190011041 ↗
30. Kamitsos · J. Phys. Chem. · 1987 · 91 · 107310.1021/j100289a014 ↗
31. Jia · Spectrochim. Acta · 2000 · 56A · 1291
32. Liu · J. Alloys Compd. · 2005 · 394 · 27710.1016/j.jallcom.2004.10.039 ↗
33. Belik · J. Magn. Magn. Mater. · 2004 · 272–276 · 93710.1016/j.jmmm.2003.12.009 ↗
34. Belik · Inorg. Chem. · 2003 · 42 · 857210.1021/ic034825w ↗
35. Y. Qiu, C. Broholm, S. Ishiwata, M. Azuma, M. Takano, R. Bewley, W.J.L. Buyers, Phys. Rev. B 71(21) (2005) 214439/1.10.1103/PhysRevB.71.214439 ↗