Preparation of hexagonal-MoO3 and electrochemical properties of lithium intercalation into the oxide

Abstract Metastable hexagonal molybdenum trioxide has been synthesized by chemical precipitation and hydrothermal treatment at low temperature. X-ray diffraction (XRD), X-ray photoelectron spectroscopy (XPS) and scanning electron microscopy (SEM) were used to characterize the product, which has a unique hexagonal prism-like morphology. Excellent electrochemical performances were exhibited: the first reversible discharge specific capacity can reach 402 mAh g −1 versus Li metal at 0.1 mA cm −2 (voltage range 1.2–4.0 V).