Enhancement in the performance of a vanadium-manganese redox flow battery using electrospun carbon metal-based electrode catalysts

This study investigates the performance of both a vanadium/manganese redox flow battery (V/Mn RFB) and an all-vanadium redox flow battery (VRFB), employing carbon metal fabrics (CMFs) prepared through electrospinning followed by carbonization. Noteworthy advancements are observed in both systems upon coupling CMFs with thermally treated graphite felt (GF) electrodes. Nearly doubled peak power density and 50 % higher capacity utilization over 150 charge/discharge cycles at 75 mA cm−2 are achieved for the V/Mn RFB with the incorporation of CMFs alongside graphite felt as catalysts. The VRFB demonstrates notable enhancements too, achieving approximately 200 cycles at a current density of 80 mA cm−2, with high efficiencies (85 %) and electrolyte utilization (79 %) when CMFs are used in combination with graphite felts. These advancements may facilitate pilot-scale testing and integration of the V/Mn RFB for the employment in the renewable energy storage sector and grid-balancing studies.