Thermal stability and transport studies of (100−2x)TeO2–xAg2O–xWO3 (7.5≤x≤30) glass system

Differential scanning calorimetry (DSC), infrared (IR) and direct current (DC) conductivity studies have been carried out on (100 − 2x)TeO2–xAg2O–xWO3 (7.5 ≤ x ≤ 30) glass system. The IR studies show that the structure of glass network consists of [TeO4], [TeO3]/[TeO3+1], [WO4] units. Thermal properties such as the glass transition (Tg), onset crystallization (To), thermal stability (ΔT), glass transition width (ΔTg), heat capacities in the glassy and liquid state (Cpg and Cpl), heat capacity change (ΔCp) and ratios Cpl/Cpg of the glass systems were calculated. The highest thermal stability (237 °C) obtained in 55TeO2–22.5Ag2O–22.5WO3 glass suggests that this new glass may be a potentially useful candidate material host for rare earth doped optical fibers. The DC conductivity of glasses was measured in temperature region 27–260 °C, the activation energy (Eact) values varied from 1.393 to 0.272 eV and for the temperature interval 170–260 °C, the values of conductivity (σ) of glasses varied from 8.79 × 10−9 to 1.47 × 10−6 S cm−1.