journal article·2021-06

Chloride ion storage performance of polyaniline/graphene nanocomposite in aqueous sodium chloride solution

Tiantian Zhu, Hui Kong, Tianchen Xia, Yuyin Shen, Yingchun Miao, Xiangyu Zhao

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Abstract

Abstract The use of anion storage materials has played an important role in the development of electrochemical energy storage systems and water desalination. Herein, the graphene-supported polyaniline (PANI/GN) nanomaterial is developed as a new chloride ion storage electrode in aqueous sodium chloride solution. The as-prepared PANI/GN electrode exhibits highly reversible electrochemical stability in both a three-electrode system and a full desalination battery using a sodium ion storage electrode. Competitive electrochemical properties with a reversible capacity of 126 mA h g−1, a coulombic efficiency of more than 95 % and a high rate capability are achieved for the PANI/GN electrode compared to the previously reported electrodes of metals, antimony oxychloride, and polypyrrole. The anionic chloride species instead of covalent chloride species in the as-prepared PANI/GN is demonstrated to be electrochemically active.
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Research context

OpenAlex topics: Advanced Battery Materials and Technologies · Membrane-based Ion Separation Techniques · Advanced battery technologies research

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