journal article·2024-12Open access

Robust Ag-Co bimetallic nanoparticles: Dual role in catalytic and triboelectric performance

Nanditha T․K․, Shreepooja Bhat, Sebghatullah Amini, Rumana Farheen S․M․, Maqsood R. Waiker, Rajendra G Sonkawade, Sangamesha M․A․, Mamatha Ballal, Krishnaveni S, Gurumurthy S․C․

Abstract

Bimetallic nanoparticles are of great significance in numerous areas due to their unique properties and diverse applications. In the present study, silver (Ag) and cobalt (Co) monometallic nanoparticles (MNPs) and AgCo bimetallic nanoparticles (BNPs), are synthesized using a simple wet chemical route. Various analytical techniques are adopted for the confirmation of the BNPs. Powder X-ray diffraction (PXRD) analysis revealed the formation of FCC-structure. Transmission Electron Microscopy (TEM) micrographs confirmed the bimetallic nature and Janus structure. The synthesized nanoparticles exhibit higher catalytic activity for degrading 4-nitrophenol dye. Recognizing the potential of metal nanoparticles to significantly boost the efficiency of triboelectric nanogenerators (TENG), the synthesized AgCo bimetallic nanoparticles are incorporated into polymer matrix to meticulously analyze the impact on the triboelectric performance. Interestingly, TENG with a higher composite quantity of 8 ml BNPs exhibited greater performance, generating an output voltage of about 270.52 V and a current of 5.24 µA. Hence, the procured synergistic BNPs show their promising avenue towards both water treatment and energy harvesting applications.
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Research context

OpenAlex topics: Conducting polymers and applications · Nanomaterials for catalytic reactions · Electromagnetic wave absorption materials

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References (65)

Show source-provided references
1. Novel development of nanoparticles to bimetallic nanoparticles and their composites: a review10.1016/j.jksus.2017.06.012 ↗
2. Synthesis, structure, properties, and applications of bimetallic nanoparticles of noble metals
3. A library of carbon-supported ultrasmall bimetallic nanoparticles10.1007/s12274-020-2920-8 ↗
4. Mono- and bimetallic nanoparticles in catalysis10.3390/catal14010068 ↗
5. Ag-based nanocomposites: synthesis and applications in catalysis10.1039/C9NR01408J ↗
6. Synthesis and anti-bacterial activity of cu, ag and cu–ag alloy nanoparticles: a green approach10.1016/j.materresbull.2010.12.001 ↗
7. Current methods for synthesis and potential applications of cobalt nanoparticles: a review10.3390/cryst12020272 ↗
8. Prepa- ration of cobalt nanoparticles10.1002/ejic.202100367 ↗
9. Tailoring the structural motif of agco nanoalloys: core/shell versus janus- like10.1021/jp909773x ↗
10. Measuring the actual voltage of a triboelectric nanogenerator using the non-grounded method10.1016/j.nanoen.2020.105108 ↗
11. Bimetallic nanoparticles in alternative solvents for catalytic purposes10.3390/catal7070207 ↗
12. Facile route to hierarchical silver microstructures with high catalytic activity for the reduction of p-nitrophenol10.1016/j.materresbull.2013.08.059 ↗
13. Synthesis of pd/au bimetallic nanoparticle-loaded ultrathin graphitic carbon nitride nanosheets for highly efficient catalytic reduction of p-nitrophenol10.1016/j.jcis.2016.12.017 ↗
14. Bimetallic PtNi nanoparticles can catalyze reduction of aromatic nitro compounds by sodium borohydride in aqueous solution10.1016/j.apcata.2004.03.017 ↗
15. Mono- and bimetallic nanoparticles for catalytic degradation of hazardous organic dyes and antibacterial applications10.1021/acsomega.2c03784 ↗
16. Advanced triboelectric nanogenerator based self-powered electrochemical system10.1016/j.cej.2024.148640 ↗
17. Piezo-triboelectric nanogenerator based on bczt/mcnts/pdms piezo- electric composite for compressive energy harvesting10.1016/j.materresbull.2024.112686 ↗
18. Advances in triboelectric nanogenerators for sustainable and renewable energy: working mechanism, tribo-surface structure, energy storage-collection system, and applications10.3390/pr11092796 ↗
19. Economical polypropylene-based triboelectric nanogenerator for self-powered biomechanical sensor application
20. Robust PVA-MWCNTs-based triboelectric energy harvesting device: self-powered smart-door technology
21. Polyvinyl alcohol- based economical triboelectric nanogenerator for self-powered energy harvesting applications10.1088/1361-6528/ad0503 ↗
22. Toward large-scale energy harvesting by a nanoparticle-enhanced triboelectric nanogenerator10.1021/nl4001053 ↗
23. Coulomb block effect inducing distinctive dielectric properties in electroless plated barium titanate@silver/poly(vinylidene fluoride) nanocomposites10.1039/C5RA11496A ↗
24. Investigating the annealing effects on the performance of polyvinyl alcohol-graphite-based triboelectric nanogenerator10.1016/j.sna.2024.115309 ↗
25. Effects of magnetic field treatment on dielectric properties of ccto@ni/pvdf composite with low concentration of ceramic fillers10.1063/1.4935270 ↗
26. Influence of nanoparticles on thermal and electrical conductivity of composites10.3390/polym12040742 ↗
27. Investigating the annealing effects on the performance of polyvinyl alcohol- graphite-based triboelectric nanogenerator10.1016/j.sna.2024.115309 ↗
28. Effects of metal nanoparticles on the performance of pdms based triboelectric nanogenerators10.1016/j.physb.2022.413952 ↗
29. A four-coordinate cobalt(ii) single-ion magnet with coercivity and a very high energy barrier10.1038/ncomms10467 ↗
30. Spinach-mediated green synthesized nife2o4 nanoparticle-based triboelectric nanogenerator: a smart tollgate controller10.1021/acsaelm.3c00859 ↗
31. Cobalt-nanoporous carbon functionalized nanocomposite-based triboelectric nanogenerator for contactless and sustainable self-powered sensor systems
32. Effect of humidity on the performance of polyvinyl chloride based triboelectric nano generator
33. Silver nanoparticles: green synthesis and their antimicrobial activities10.1016/j.cis.2008.09.002 ↗
34. Ultraviolet–visible absorption spectra of the colloidal metallic elements10.1039/FT9918703881 ↗
35. Formation, absorption spectrum, and chemical reactions of nanosized colloidal cobalt in aqueous solution10.1021/jp000608u ↗
36. A sustainable approach to fabricating ag nanoparticles/pva hybrid nanofiber and its catalytic activity10.3390/nano5021124 ↗
37. M.A. Raza, Z. Kanwal, S. Riaz, and S. Naseem, “Synthesis, characterization and antibacterial properties of nano-sized cobalt particles,” 08 2016.
38. Cobalt@silver bimetallic nanoparticles: solution based seedless surfactant assisted synthesis, optical properties, and morphology10.1016/j.molliq.2016.07.043 ↗
39. Electrooxidation on methanol on ag, catalysts prepared by combustion synthesis technique10.1002/er.8696 ↗
40. F. De Boer, R. Boom, W. Mattens, A. Miedema, and A. Niessen, “Cohesion in metals, edited by fr de boer and dg pettifor,” 1989.
41. R.R. Hultgren, P.D. Desai, D.T. Hawkins, M. Gleiser, K.K. Kelley, and D.D. Wagman, “Selected values of the thermodynamic properties of the elements,” 1973.
42. Nanoscale effects on phase separation10.1021/acs.nanolett.7b01994 ↗
43. General trends in core–shell preferences for bimetallic nanoparticles10.1021/acsnano.1c01500 ↗
44. Transition from core–shell to janus chemical configuration for bimetallic nanoparticles10.1039/c2nr11954d ↗
45. Photochemical deposition of SERS active silver nanoparticles on silica gel and their application as catalysts for the reduction of aromatic nitro compounds10.1016/j.jcis.2003.11.046 ↗
46. Ionic liquid-facilitated synthesis and catalytic activity of highly dispersed ag nanoclusters supported on tio210.1039/b910610c ↗
47. Antibacterial and catalytic activities of green synthesized silver nanoparticles10.1016/j.saa.2014.07.045 ↗
48. Synthesis of bimetallic gold-silver (au-ag) nanoparticles for the catalytic reduction of 4-nitrophenol to 4-aminophenol10.3390/catal8100412 ↗
49. A one-pot route to the synthesis of alloyed cu/ag bimetallic nanoparticles with different mass ratios for catalytic reduction of 4-nitrophenol10.1039/C4TA06567K ↗
50. Facile one-pot green synthesis of Ag–Fe bimetallic nanoparticles and their catalytic capability for 4-nitrophenol reduction10.1016/j.jmrt.2021.02.063 ↗
51. CuFe2o4 magnetic nanoparticles: a simple and efficient catalyst for the reduction of nitrophenol10.1016/j.cej.2013.02.009 ↗
52. 4-nitrophenol reduction catalysed by au-ag bimetallic nanoparticles supported on ldh: homogeneous vs. heterogeneous catalysis10.1016/j.clay.2017.10.015 ↗
53. Morphology-dependent interfacial interactions of fe2o3 with ag nanoparticles for determining the catalytic reduction of p-nitrophenol10.1016/j.jes.2020.02.001 ↗
54. Monodispersed feni2 alloy nanostructures: solvothermal synthesis, magnetic properties and size-dependent catalytic activity10.1039/c2ce25457c ↗
55. Microbial synthesis of bimetallic PdPt nanoparticles for catalytic reduction of 4-nitrophenol10.1007/s11356-016-8276-7 ↗
56. Cuag and auag bimetallic nanoparticles for catalytic and heat transfer applications10.1007/s10098-021-02120-0 ↗
57. Predicting chemical hazard across taxa through machine learning10.1016/j.envint.2022.107184 ↗
58. Quantitative structure–property relationship of the photoelectrochemical oxidation of phenolic pollutants at modified nanoporous titanium oxide using supervised machine learning10.1039/D0CP01518K ↗
59. Machine learning algorithms to predict the catalytic reduction performance of eco-toxic nitrophenols and azo dyes contaminants (invited article)10.1016/j.aej.2023.04.007 ↗
60. Fast synthesis of nanoporous cu/ag bimetallic triangular nanoprisms via galvanic replacement for efficient 4-nitrophenol reduction10.1039/D3NR05968E ↗
61. Preparation and characterization of ag–pd bimetallic nano-catalysts in thermosensitive microgel nano-reactor10.1039/C8RA02563K ↗
62. Free energy change of aggregation of nanoparticles10.1021/jp804966c ↗
63. Electricity out of electronic trash: triboelectric nanogenerators from discarded smartphone displays for biomechanical energy harvesting10.1016/j.wasman.2024.02.009 ↗
64. Pulsed laser deposited and sulfurized Cu2ZnSnS4 thin film for efficient solar cell10.1016/j.solmat.2021.111383 ↗
65. Pyroelectric nanogenerators (PyNGs) in converting thermal energy into electrical energy: fundamentals and current status10.1016/j.nanoen.2021.105888 ↗