journal article·2021-01

Nickel sulfide nanoparticle anchored reduced graphene oxide with improved lithium storage properties

Haibo Ren, Junhai Wang, Yaxian Cao, Wei Luo, Yufeng Sun

Publisher page

Abstract

Abstract Reduced graphene oxide@nickel sulfide (NiS) composites are synthesized by a solvothermal method. Uniformly dispersed NiS nanoparticles with a size of 15∼25 nm are embedded to the surface of a three-dimensional (3D) reduced graphene oxide. The favorable 3D-framework with a large amount of pores has been characterized systematically. As a Li-ion battery anode, the reduced graphene oxide@NiS anode keeps a reversible capacity of 1328.7 mAh g-1 at 0.1 A g-1 after 120 cycles. Meanwhile, it shows an enhanced rate capability of 673.6 mAh g-1 at 1.0 A g-1. The enhanced reversible capacity and cycling stability is ascribed to the reduced graphene oxide and its unique 3D porous nanostructure. Furthermore, the existence of C‒S bonds make reduced graphene oxide and nickel sulfide in the composite combine better during the cycling process, and enhance their synergistic effect. Since that, the conductivity, volume-variation and active sites of the composites are greatly improved.
Source: openaire · Quality: candidate unverified · Source record ↗

Research context

OpenAlex topics: Advancements in Battery Materials · Advanced Battery Materials and Technologies · Supercapacitor Materials and Fabrication

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

References (50)

Show source-provided references
1. Progress of enhancing the safety of lithium ion battery from the electrolyte aspect10.1016/j.nanoen.2018.10.035 ↗
2. Crumpled nitrogen-doped graphene-wrapped phosphorus composite as a promising anode for lithium-ion batteries, ACS Appl10.1021/acsami.9b08915 ↗
3. In situ synthesis of three-dimensional nickel oxide nanosheets on reduced graphene oxide with enhanced lithium-ion storage10.1016/j.materresbull.2018.10.043 ↗
4. Enhanced electrochemical performance of Li-Co-BTC ternary metal-organic frameworks as cathode materials for lithium-ion batteries10.1039/C8DT04863K ↗
5. Lithium-ion batteries: outlook on present, future, and hybridized technologies10.1039/C8TA10513H ↗
6. Nanostructured anode materials for lithium-ion batteries: principle, recent progress and future perspectives10.1039/C7TA05283A ↗
7. Well-designed porous graphene flakes for lithium-ion batteries with outstanding rate performance10.1021/acs.langmuir.8b03477 ↗
8. Dual bond enhanced multidimensional constructed composite silicon anode for high-performance lithium ion batteries10.1021/acsnano.9b02129 ↗
9. Nanocomposite of Mo2N quantum dots@MoO3@nitrogen-doped carbon as a high-performance anode for lithium-ion batteries10.1021/acssuschemeng.9b00080 ↗
10. A ZnS nanocrystal/reduced graphene oxide composite anode with enhanced electrochemical performances for lithium-ion batteries10.1039/C6CP06609G ↗
11. Effective combination of FeS2 microspheres and Fe3S4 microcubes with rGO as anode material for high-capacity and long-cycle lithium-ion batteries10.1016/j.jpowsour.2018.06.088 ↗
12. Nickel sulfide cathode for stable charge-discharge rates in lithium rechargeable battery10.1016/j.matchemphys.2019.04.024 ↗
13. Hierarchically assembled 3D nanoflowers and 0D nanoparticles of nickel sulfides on reduced graphene oxide with excellent lithium storage performances10.1016/j.apsusc.2017.12.206 ↗
14. Hierarchical nanostructured NiS/MoS2/C composite hollow spheres for high performance sodium-ion storage performance10.1021/acsami.9b11078 ↗
15. In situ nitrogen-doped helical mesoporous carbonaceous nanotubes for superior-high lithium anodic performance10.1016/j.carbon.2018.01.057 ↗
16. Controlled-size hollow magnesium sulfide nanocrystals anchored on graphene for advanced lithium storage10.1021/acsnano.8b07770 ↗
17. Synthesis of core-shell-like ZnS/C nanocomposite as improved anode material for lithium ion batteries10.1016/j.electacta.2017.01.038 ↗
18. Facile one-pot synthesis of ultrathin NiS nanosheets anchored on graphene and the improved electrochemical Li-storage properties10.1039/c2ra22410k ↗
19. Hierarchical architectured NiS@SiO2 nanoparticles enveloped in graphene sheets as anode material for lithium ion batteries10.1016/j.electacta.2014.12.074 ↗
20. Large-scale synthesis of NiS@N and S co-doped carbon mesoporous tubule as high performance anode for lithium-ion battery10.1016/j.jallcom.2019.02.326 ↗
21. Nickel sulfide anchored carbon nanotubes for all-solid-state lithium batteries with enhanced rate capability and cycling stability10.1039/C8TA03449D ↗
22. One-pot synthesis of core/shell-structured NiS@onion-like carbon nanocapsule as a high-performance anode material for lithium-ion batteries10.1016/j.matlet.2017.03.042 ↗
23. NiS nanorod-assembled nanoflowers grown on graphene: morphology evolution and Li-ion storage applications10.1039/C4TA03440F ↗
24. TiO2-rGO nanocomposite hollow spheres: large scale synthesis and application as an efficient anode material for lithium-ion batteries10.1039/C7TA08164B ↗
25. Three-dimensional porous graphene microsphere for high-performance anode of lithium ion batteries10.1016/j.surfcoat.2018.12.104 ↗
26. Applications of hierarchically structured porous materials from energy storage and conversion, catalysis, photocatalysis, adsorption, separation, and sensing to biomedicine10.1039/C6CS00135A ↗
27. A facile synthesis of sandwich-structured SnS2@reduced graphene oxide with high performance for lithium-ion battery anode10.1016/j.jallcom.2018.06.245 ↗
28. Synthesis of tin(IV) oxide@reduced graphene oxide nanocomposites with superior electrochemical behaviors for lithium-ions batteries10.1016/j.electacta.2018.09.059 ↗
29. Rational design of multi-functional CoS@rGO composite for performance enhanced Li-S cathode10.1016/j.jpowsour.2019.03.015 ↗
30. Three-dimensional sandwich-structured NiMn2O4@reduced graphene oxide nanocomposites for highly reversible Li-ion battery anodes10.1016/j.jpowsour.2018.01.029 ↗
31. Co9S8@MoS2 core-shell nanostructure anchored on reduced graphene oxide with improved electrochemical performance for lithium-ion batteries10.1016/j.apsusc.2018.12.257 ↗
32. NiO/NiS heterostructures: an efficient and stable electrocatalyst for oxygen evolution reaction10.1021/acsaem.9b00317 ↗
33. Controlled synthesis of nickel sulfide/graphene oxide nanocomposite for high-performance supercapacitor10.1016/j.apsusc.2013.06.038 ↗
34. CoS2 hollow spheres: fabrication and their application in lithium-ion batteries10.1021/jp111626a ↗
35. Graphene-wrapped CoS nanoparticles for high-capacity lithium-ion storage10.1021/am3023652 ↗
36. Flexible electrospun carbon nanofiber@NiS core/sheath hybrid membranes as binder-free anodes for highly reversible lithium storage10.1002/admi.201500467 ↗
37. Hexagonal phase NiS octahedrons co-modified by 0D-, 1D-, and 2D carbon materials for high-performance supercapacitor10.1016/j.electacta.2019.04.111 ↗
38. Reduced graphene oxide-induced recrystallization of NiS nanorods to nanosheets and the improved Na-storage properties10.1021/ic402948s ↗
39. A novel strategy for 2D/2D NiS/graphene heterostructures as efficient bifunctional electrocatalysts for overall water splitting10.1016/j.apcatb.2019.05.029 ↗
40. Natural abundance solid-state 33S NMR study of NbS3: applications for battery conversion electrodes10.1039/C9CC06059F ↗
41. Electrochemical performances investigation of NiS/rGO composite as electrode material for supercapacitors10.1016/j.nanoen.2014.02.006 ↗
42. One-step synthesis of nickel sulfide/N-doped graphene composite as anode materials for lithium ion batteries10.1016/j.jelechem.2014.10.035 ↗
43. Highly stable rGO-wrapped Ni3S2 nanobowls: structure fabrication and superior long-life electrochemical performance in LIBs10.1016/j.nanoen.2014.11.022 ↗
44. Synthesis of porous NiS thin films on Ni foam substrate via an electrodeposition route and its application in lithium-ion batteries10.1016/j.jallcom.2013.11.070 ↗
45. Metal-organic framework-derived hollow CoS nanobox for high performance electrochemical energy storage10.1016/j.cej.2018.02.032 ↗
46. Controllable preparation of square nickel chalcogenide (NiS and NiSe2) nanoplates for superior Li/Na ion storage properties10.1021/acsami.6b07300 ↗
47. NiS nanorods as cathode materials for all-solid-state lithium batteries with excellent rate capability and cycling stability
48. Synthesis of hierarchical molybdenum disulfide microplates consisting of numerous crosslinked nanosheets for lithium-ion batteries10.1016/j.jallcom.2018.12.117 ↗
49. CoTe nanorods/rGO composites as a potential anode material for sodium-ion storage10.1016/j.electacta.2019.05.047 ↗
50. One-step solution combustion synthesis of CuO/Cu2O/C anode for long cycle life Li-ion batteries10.1016/j.carbon.2018.10.016 ↗