journal article·2020-10

Growth of α-MoO3 Golf Ball Architectures with Interlocking Loops for Selective Probing of Trimethylamine at Room Temperature

Parthasarathy Srinivasan, John Bosco Balaguru Rayappan

Publisher page

Abstract

Abstract We report TMA sensing characteristics of MoO3 thin films deposited using spray pyrolysis technique by varying the substrate temperatures from 523 to 623 K in steps of 50 K. An intermediate molybdenum composite was formed at 523 K, whereas it gets transformed to orthorhombic MoO3 at higher temperatures with golf ball-like morphology surrounded by interlocking loops. These thin films were highly selective and sensitive towards TMA vapor at room temperature. Also, the influence of grain boundary resistance and inter-granular activation energy of deposited thin films on TMA sensing properties has been investigated and reported. In particular, the film deposited at 623 K showed a minimum grain boundary resistance of 8.52 MΩ among other samples resulted in the maximum response of 27 towards 100 ppm of TMA at room temperature with the response and recovery times of 248 and 70 s respectively.
Source: openaire · Quality: candidate unverified · Source record ↗

Research context

OpenAlex topics: Gas Sensing Nanomaterials and Sensors · Transition Metal Oxide Nanomaterials · Analytical Chemistry and Sensors

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

References (63)

Show source-provided references
1. Ultrafast response and recovery of single crystalline α-Fe2O3 nanorhombohedrons for trimethylamine sensing applications10.1016/j.matlet.2017.08.120 ↗
2. Ultraselective and ultrasensitive detection of trimethylamine using MoO3 nanoplates prepared by ultrasonic spray pyrolysis10.1016/j.snb.2014.01.021 ↗
3. High sensitivity and good selectivity of ultralong MoO3 nanobelts for trimethylamine gas10.1016/j.snb.2015.12.005 ↗
4. Ultrafast response and recovery trimethylamine sensor based on α-Fe2O3 snowflake-like hierarchical architectures10.1016/j.jallcom.2017.05.227 ↗
5. Trimethylamine sensing properties of sensors based on MoO3 microrods10.1016/j.snb.2010.05.049 ↗
6. Triethylamine gas sensor based on ZnO nanorods prepared by a simple solution route10.1016/j.snb.2009.06.033 ↗
7. Trimethylamine gas sensor based on Cr3+ doped ZnO nanorods/nanoparticles prepared via solvothermal method10.1016/j.matchemphys.2011.09.069 ↗
8. Ultrasensitive detection of trimethylamine using Rh-doped SnO2 hollow spheres prepared by ultrasonic spray pyrolysis10.1016/j.snb.2014.10.001 ↗
9. Trimethylamine sensors with enhanced anti-humidity ability fabricated from La0.7Sr0.3FeO3 coated In2O3–SnO2 composite nanofibers10.1016/j.snb.2014.06.082 ↗
10. Branch-like hierarchical heterostructure (α-Fe2O3/TiO2): a novel sensing material for trimethylamine gas sensor10.1021/am402532v ↗
11. Selective trimethylamine sensors using Cr2O3-decorated SnO2 nanowires10.1016/j.snb.2014.07.084 ↗
12. Highly selective and sensitive detection of trimethylamine using WO3 hollow spheres prepared by ultrasonic spray pyrolysis10.1016/j.snb.2012.10.044 ↗
13. Nanostructured α-MoO3 thin film as a highly selective TMA sensor10.1016/j.bios.2013.09.057 ↗
14. Facile synthesis and enhanced trimethylamine sensing performances of W-doped MoO3 nanobelts10.1016/j.mssp.2017.04.002 ↗
15. Template-assisted synthesis of hierarchical MoO3 microboxes and their high gas-sensing performance10.1016/j.snb.2017.04.137 ↗
16. α-MoO3 nanocrystals of controlled size on a glass substrate10.1016/j.materresbull.2008.06.034 ↗
17. Thermal oxidation synthesis hollow MoO3 microspheres and their applications in lithium storage and gas-sensing10.1016/j.materresbull.2013.02.050 ↗
18. Room temperature chemiresistive gas sensors: challenges and strategies---a mini review10.1007/s10854-019-02025-1 ↗
19. Electrospun tailored ZnO nanostructures-role of chloride ions10.1039/C5RA15697A ↗
20. Monomer: Design of ZnO Nanostructures (Nanobush and Nanowire) and Their Room-Temperature Ethanol Vapor Sensing Signatures10.1021/acsami.7b11561 ↗
21. Role of substrate temperature on MoO3 thin films by the JNS pyrolysis technique for P–N junction diode application10.1016/j.mssp.2015.12.009 ↗
22. Effect of the substrate temperature on the physical properties of molybdenum tri-oxide thin films obtained through the spray pyrolysis technique10.1016/j.matchar.2012.11.002 ↗
23. A highly selective room temperature ammonia sensor using spray deposited zinc oxide thin film10.1016/j.snb.2013.03.132 ↗
24. Nanostructured Cerium-doped ZnO thin film – A breath sensor10.1016/j.ceramint.2016.08.156 ↗
25. Room temperature ammonia sensing properties of ZnO thin films grown by spray pyrolysis: Effect of Mg doping10.1016/j.jallcom.2016.07.050 ↗
26. Racetrack Effect on the Dissimilar Sensing Response of ZnO Thin Film—An Anisotropy of Isotropy10.1021/acsami.6b05133 ↗
27. Growth of Eshelby twisted ZnO nanowires through nanoflakes & nanoflowers: A room temperature ammonia sensor10.1016/j.snb.2018.09.003 ↗
28. Investigations on Room Temperature Dual Sensitization of ZnO Nanostructures Towards Fish Quality Biomarkers
29. Highly crystalline {010} facet grown α-MoO3 nanobelts for resistive sensing of n-butanol vapor at room temperature10.1007/s00604-019-3905-8 ↗
30. Improved sensing response of photo activated ZnO thin film for hydrogen peroxide detection10.1016/j.jcis.2016.07.066 ↗
31. Nanostructured flower like V2O5 thin films and its room temperature sensing characteristics10.1016/j.ceramint.2014.10.023 ↗
32. Physical investigations on MoO3 sprayed thin film for selective sensitivity applications10.1016/j.ceramint.2014.05.062 ↗
33. Alteration of architecture of MoO 3 nanostructures on arbitrary substrates: growth kinetics, spectroscopic and gas sensing properties10.1039/C4NR04529G ↗
34. Synthesis and field emission of MoO3 nanoflowers by a microwave hydrothermal route10.1016/j.jallcom.2009.03.007 ↗
35. Hydrothermally Synthesized h-MoO3 and α-MoO3 Nanocrystals: New Findings on Crystal-Structure-Dependent Charge Transport10.1021/acs.cgd.5b01571 ↗
36. Strong influence of substrate temperature on the growth of nanocrystalline MoO3 thin films10.1016/j.physleta.2009.08.058 ↗
37. Substrate temperature influenced structural, electrical and optical properties of dc magnetron sputtered MoO3 films10.1016/j.apsusc.2009.11.086 ↗
38. Influence of precursor solution volume on the properties of spray deposited α-MoO3 thin films10.1016/j.ceramint.2013.11.022 ↗
39. Systematic synthesis and analysis of change in morphology, electronic structure and photoluminescence properties of pyrazine intercalated MoO3 hybrid nanostructures10.1039/c0ce00303d ↗
40. Investigation of oxygen vacavcy and Interstitial oxygen defects in ZnO films by photoluminescence ad X-ray photoelectron spectroscopy
41. Facial synthesis of hexagonal metal oxide nanoparticles for low temperature ammonia gas sensing applications10.1039/C4RA12747A ↗
42. Impedance spectroscopy on WO3 gas sensor10.1016/j.snb.2004.09.022 ↗
43. Grain boundaries dependent hydrogen sensitivity in MAO-TiO2 thin films sensors10.1016/j.snb.2010.05.014 ↗
44. New approaches for improving semiconductor gas sensors10.1016/0925-4005(91)80213-4 ↗
45. Grain size effects on gas sensitivity of porous SnO2-based elements10.1016/0925-4005(91)80207-Z ↗
46. Electrical barriers in the ZnO varistor grain boundaries
47. Eff ;ects of activation energy on transient response of semiconductor gas sensor10.1002/ecj.11475 ↗
48. Thickness dependency of sol-gel derived ZnO thin films on gas sensing behaviors10.1016/j.tsf.2010.08.005 ↗
49. Monomer: Design of ZnO Nanostructures (Nanobush and Nanowire) and Their Room-Temperature Ethanol Vapor Sensing Signatures10.1021/acsami.7b11561 ↗
50. Room temperature ethanol sensing properties of ZnO nanorods prepared using an electrospinning technique10.1039/C7TC03771F ↗
51. Synthesis and characterization of α-MoO3 microspheres packed with nanoflakes10.1088/0022-3727/47/6/065305 ↗
52. Novel and facile synthesis of randomly interconnected ZnO nanoplatelets using spray pyrolysis and their room temperature sensing characteristics10.1016/j.snb.2014.02.101 ↗
53. A highly selective and wide range ammonia sensor - Nanostructured ZnO:Co thin film10.1016/j.mseb.2014.10.007 ↗
54. W. Göpel\textdagger, Fundamental and practical aspects in the design of nanoscaled SnO2 gas sensors: a status report, Fresenius
55. Conduction Model of Metal Oxide Gas Sensors10.1023/A:1014405811371 ↗
56. The effect of oxygen stoichiometry on the humidity sensing characteristics of bismuth iron molybdate10.1016/S0925-4005(00)00395-6 ↗
57. Nanostructured mixed ZnO and CdO thin film for selective ethanol sensing10.1016/j.matlet.2012.03.009 ↗
58. Influence of precursor concentration on structural, morphological and electrical properties of spray deposited ZnO thin films10.1002/crat.201000672 ↗
59. Nanostructured ZnO thin film for hydrogen peroxide sensing10.1016/j.physe.2011.06.015 ↗
60. Branch-like hierarchical heterostructure (α-Fe2O3/TiO2): A novel sensing material for trimethylamine gas sensor10.1021/am402532v ↗
61. Hexagonal ZnO nanorings: synthesis{,} formation mechanism and trimethylamine sensing properties10.1039/C5RA14793J ↗
62. In2O3-functionalized MoO3 heterostructure nanobelts with improved gas-sensing performance10.1039/C6RA07292E ↗
63. Fabrication of SnO2-ZnO nanocomposite sensor for selective sensing of trimethylamine and the freshness of fishes10.1016/j.snb.2008.05.015 ↗