Role of the fuel stoichiometry and post-treatment temperature on the spinel inversion and magnetic properties of NiFe2O4 nanoparticles produced by solution combustion synthesis
Source abstract
Abstract
Abstract Soft-magnetic nickel ferrite (NiFe2O4) nanoparticles were synthesized via solution combustion synthesis (SCS). The influence of the fuel concentration and the post-treatment temperature on the structural and magnetic properties of the samples were studied. The samples produced in a fuel-short regime presented the purest NiFe2O4 nanoparticles, with an average diameter of 32 nm. Spinel inversion degree, composition, crystallite size, and surface area were evaluated regarding their influence on the magnetic behavior of the nanoparticles. Interestingly, the magnetic properties of pure NiFe2O4 samples remained unaffected even after heat-treated above 900 °C. This result is promising for industrial applications that require magnetic stability over temperature changes. NiFe2O4 presented a critical size of 40 nm for single-domain to multi-domain transition. Below 40 nm, the discharge of Ni and α-Fe2O3 from the NiFe2O4 structure is the main factor influencing the magnetism. Pure NiFe2O4 samples treated at different temperatures presented a similar spinel inversion and consequently similar coercivities, approximately 170 Oe.
Source: openaire · Quality: candidate unverified · Source record ↗
Research context
OpenAlex topics: Magnetic Properties and Synthesis of Ferrites · Advancements in Battery Materials · Iron oxide chemistry and applications
SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.
References (71)
Show source-provided references
1. Magnetic nickel ferrite nanoparticles: green synthesis by Urtica and therapeutic effect of frequency magnetic field on creating cytotoxic response in neural cell lines10.1016/j.colsurfb.2018.08.049 ↗
2. Room temperature giant positive junction magnetoresistance of NiFe2O4/n-Si heterojunction for spintronics application10.1016/j.physb.2014.04.002 ↗
3. Microwave assisted combustion synthesis and characterization of nickel ferrite nanoplatelets10.1016/j.moem.2016.10.003 ↗
4. Microwave absorbing properties of NiFe2O4 nanosheets synthesized via a simple surfactant-assisted solution route10.1590/1980-5373-MR-2015-0581 ↗
5. Catalytic studies of NiFe2O4 nanoparticles prepared by conventional and microwave combustion method10.1016/j.matchemphys.2018.09.012 ↗
6. Octahedral NiFe2O4 for high-performance gas sensor with low working temperature10.1016/j.ceramint.2017.11.008 ↗
7. NiFe2O4 nanoparticles/MWCNTs nanohybrid as anode material for lithium-ion battery10.1016/j.ceramint.2019.01.160 ↗
8. Kharat · 2017 · 050122
9. Magnetic attributes of NiFe2O4 nanoparticles: influence of dysprosium ions (Dy3+) substitution10.3390/nano9060820 ↗
10. Combustion synthesis of nickel ferrite powders: effect of NaClO4 content on their characteristics and magnetic properties10.1016/j.cap.2019.02.006 ↗
11. Synthesis of NiFe2O4 nanoparticles for energy and environment applications10.1088/2053-1591/aaacde ↗
12. Influence of morphology and crystallinity on field emission properties of NiFe2O4 nanoparticles grown by high-temperature vapor phase condensation route10.1088/2053-1591/2/9/095001 ↗
13. Structural investigation and electronic properties of the nickel ferrite NiFe2O4 : a periodic density functional theory approach10.1088/0953-8984/19/34/346219 ↗
14. Synthesis and electrophoretic deposition of magnetic nickel ferrite nanoparticles10.1007/s10853-006-0393-0 ↗
15. Preparation and characterization of nickel ferrite nanoparticles via Co-precipitation method10.1590/1980-5373-mr-2016-0533 ↗
16. Parametric optimization of NiFe2O4 nanoparticles synthesized by mechanical alloying
17. CO response characteristics of NiFe2O4 sensing material at elevated temperature10.1149/2.0581912jes ↗
18. Preparation and properties of nickel ferrite (NiFe2O 4) nanoparticles via sol-gel auto-combustion method10.1016/j.materresbull.2011.09.010 ↗
19. Synthesis and characterization of nickel ferrite magnetic nanoparticles10.1016/j.materresbull.2011.09.009 ↗
20. Magnetic and gas sensing property of nanosized NiFe2O4 powders synthesized by pulsed wire discharge10.1007/s11051-005-5427-z ↗
21. The effect of Ni/Fe ratio on the physical properties of NiFe2O4 nanocomposites10.1088/2053-1591/ab201c ↗
22. Magnetic behavior of nanocrystalline nickel ferrite synthesized by the reverse micelle technique10.1016/j.jmmm.2003.11.015 ↗
23. Naidu · 2017 · 417
24. Mass synthesis of nanocrystalline spinel ferrites by a polymer-pyrolysis route10.1016/j.msec.2006.07.026 ↗
25. Mechanochemical synthesis of TiO2/NiFe2O4 magnetic catalysts for operation under RF field10.1016/j.mseb.2014.12.011 ↗
26. Structural, electrical and dielectric properties of spinel nickel ferrite prepared by soft mechanochemical synthesis10.1016/j.materresbull.2013.07.012 ↗
27. Rapid synthesis of nanocrystalline NiFe2O4 and CoFe2O4 powders by a microwave-assisted combustion method10.1007/s10948-012-1972-8 ↗
28. Structural and magnetic properties of nanocrystalline nickel ferrite (NiFe2O4) synthesized in sol-gel and combustion routes10.1016/j.solidstatesciences.2018.10.008 ↗
29. Nanocrystalline nickel ferrite thick film as an efficient gas sensor at room temperature10.1016/j.snb.2007.11.003 ↗
30. Low temperature processing of NiZn ferrite by citrate precursor method and study of properties10.1179/026708300101508324 ↗
31. Correlating size and composition-dependent effects with magnetic, Mössbauer, and pair distribution function measurements in a family of catalytically active ferrite nanoparticles10.1021/acs.chemmater.5b00767 ↗
32. Structural, optical and magnetic properties of porous α-Fe2o3 nanostructures prepared by rapid combustion method10.1166/jnn.2013.7402 ↗
33. A novel synthesis and characterization studies of magnetic Co3O4 nanoparticles10.1166/jnn.2015.9776 ↗
34. Influence of order-disorder effects on the magnetic and optical properties of NiFe 2 O 4 nanoparticles10.1016/j.ceramint.2018.06.190 ↗
35. Combustion synthesis of ZnFe Cr O4 nanocrystallites for ceramic digital decoration10.1016/j.matchemphys.2020.122695 ↗
36. Photocatalytic performances of BiFeO 3 powders synthesized by solution combustion method: the role of mixed fuels10.1016/j.matchemphys.2019.02.059 ↗
37. In situ preparation of oxide-based supported catalysts by solution combustion synthesis10.1021/jp054486n ↗
38. Influence of the fuel composition and the Fuel/Oxidizer ratio on the combustion solution synthesis of MgFe2O4 catalyst nanoparticles
39. 3D CNT macrostructure synthesis catalyzed by MgFe2O4nanoparticles—a study of surface area and spinel inversion influence10.1016/j.apsusc.2017.06.020 ↗
40. Applied catalysis a : general Fundamentals, properties and applications of solid catalysts prepared by solution combustion synthesis (SCS)10.1016/j.apcata.2012.11.024 ↗
41. A new approach to thermochemical calculations of condensed fuel-oxidizer mixtures10.1016/0010-2180(81)90111-5 ↗
42. Role of fuel and fuel-to-oxidizer ratio in combustion synthesis of nano-crystalline nickel oxide powders10.1016/j.ceramint.2015.08.037 ↗
43. Sol-gel synthesis of substoichiometric cobalt ferrite (CoFe2O4) spinels: Influence of additives on their stoichiometry and magnetic properties10.1016/j.ceramint.2018.04.026 ↗
44. Numerical investigation of pulverized coal jet flame characteristics under different oxy-fuel conditions10.1016/j.ijheatmasstransfer.2012.11.070 ↗
45. Sol-gel NiFe 2 O 4 nanoparticles: effect of the silica coating10.1063/1.4720079 ↗
46. Varma · 2016
47. Photocatalytic degradation of methyl orange dye by NiFe2O4 nanoparticles under visible irradiation: effect of varying the synthesis temperature10.1007/s10854-018-8693-0 ↗
48. Nanostructured cobalt oxides (Co3O4 and CoO) and metallic Co powders synthesized by the solution combustion method10.1016/j.materresbull.2010.03.001 ↗
49. Effect of glycine on one-step solution combustion synthesis of magnetite nanoparticles10.1016/j.jallcom.2017.05.187 ↗
50. Effect of the thermal treatment on the magnetic and structural properties of cobalt ferrite particles10.1016/j.ceramint.2016.06.120 ↗
51. Subsurface cation vacancy stabilization of the magnetite (001) surface
52. Solution combustion synthesis of metal nanopowders: nickel-Reaction pathways10.1002/aic.12416 ↗
53. Effect of heat treatment on microstructure and mechanical properties of cold sprayed Ti coatings with relatively large powder particles10.1007/s11998-008-9133-5 ↗
54. Raman study of NiFe2O4 nanoparticles, bulk and films: effect of laser power10.1002/jrs.2791 ↗
55. Raman Spectra and vibrational analysis of BaFe 12 O 19 hexagonal ferrite10.1006/jssc.1997.7737 ↗
56. Use of Raman micro-spectroscopy in the characterization of MIIFe2O4 (M = Fe, Zn) electric double layer ferrofluids10.1002/(SICI)1097-4555(200003)31:3<185::AID-JRS511>3.0.CO;2-B ↗
57. NiFe2O4 nanoparticles formed in situ in silica matrix by mechanical activation10.1063/1.1462853 ↗
58. Domain size correlated magnetic properties and electrical impedance of size dependent nickel ferrite nanoparticles10.1063/1.4906101 ↗
59. A structural and magnetic investigation of the inversion degree in spinel NiFe2O4, ZnFe2O4 and Ni0.5Zn0.5Fe2O4 ferrites prepared by Soft mechanochemical synthesis
60. The power of databases: the RRUFF project
61. Ceylan · 2008 · 857
62. Facile synthesis of nanocrystalline spinel NiFe2O4 via a novel soft chemistry route10.1016/j.matlet.2007.01.111 ↗
63. Cullity · 2008
64. Effect of dysprosium substitution on magnetic and structural properties of NiFe2O4 nanoparticles10.1016/j.jre.2018.10.009 ↗
65. Mössbauer study of several ferrimagnetic spinels10.1103/PhysRev.187.747 ↗
66. Effect of bimetallic (Ca, Mg) substitution on magneto-optical properties of NiFe2O4 nanoparticles10.1016/j.ceramint.2018.12.072 ↗
67. PLS-regression: A basic tool of chemometrics10.1016/S0169-7439(01)00155-1 ↗
68. CNT sponges with outstanding absorption capacity and electrical properties: impact of the CVD parameters on the product structure10.1016/j.ceramint.2019.04.072 ↗
69. Ecofriendly synthesis of MWCNTs by electric arc in aqueous medium: comparative study of 6B pencil and mineral graphite10.1111/ijac.13565 ↗
70. Partial least squares structural equation modeling (PLS-SEM)10.1108/EBR-10-2013-0128 ↗
71. Correlation between particle size/domain structure and magnetic properties of highly crystalline Fe 3 O 4 nanoparticles