Hydrogen desorption and absorption properties of Pd and MgO or nano-sized Ni-added MgH2+LiBH4 composites

Abstract In order to increase the hydrogen storage capacity of Mg-based materials, LiBH 4 with a higher hydrogen storage capacity of 18.4 wt% was added to MgH 2 . Pd and MgO or nano-sized Ni were added to improve the desorption rate and decrease the desorption temperature of MgH 2 and LiBH 4 composite. Composite powders with compositions of 69.7 wt% MgH 2 + 30.3 wt% LiBH 4 , 84 wt% MgH 2 + 15 wt% LiBH 4 + 1 wt% Pd, 79 wt% MgH 2 + 15 wt% LiBH 4 + 1 wt% Pd + 5 wt% MgO, and 79 wt% MgH 2 + 15 wt% LiBH 4 + 1 wt% Pd + 5 wt% Ni were prepared by planetary ball milling under hydrogen. The absorption and desorption properties of the samples were then examined. Among these samples, 79 wt% MgH 2 + 15 wt% LiBH 4 + 1 wt% Pd + 5 wt% Ni showed the highest desorption rate and the largest released hydrogen quantity, releasing 4.70 wt% H for 50 min, and 5.70 wt% H for 300 min. Among these samples, 84 wt% MgH 2 + 15 wt% LiBH 4 + 1 wt% Pd showed the highest absorption rate and the largest absorbed hydrogen quantity, absorbing 5.3 wt% H for about 25 min, and absorbing hydrogen even after 550 min, in particular. 84 wt% MgH 2 + 15 wt% LiBH 4 + 1 wt% Pd exhibited a relatively high desorption rate.