journal article·2013-11

The influence of auxiliary codopants on persistent phosphor Sr2P2O7:Eu2+,R3+ (R=Y, La, Ce, Gd, Tb and Lu)

Guifang Ju, Yihua Hu, Li Chen, Xiaojuan Wang, Zhongfei Mu

Materials Research Bulletin· Volume 48· Issue 11
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Abstract

Abstract We investigate the persistent luminescence in europium-doped strontium pyrophosphate upon codoping with auxiliary rare earth ions. The persistent phosphors are synthesized via solid-state reaction method under flowing N2 + H2. Under UV irradiation, broadband emission persistent luminescence located at 420 nm is observed in all of these phosphors at room temperature. The effects of auxiliary rare earth ions on Sr2P2O7:Eu2+ are discussed according to the decay curves and thermoluminescence spectra. Sr2P2O7:Eu2+,Lu3+ shows the best performance, while and La3+ and Ce3+ codoped samples are the weakest. The influence of auxiliary codopants is discussed in terms of ionic potential and ionic radius. We derive an empirical formula based on the experimental results.
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Research context

OpenAlex topics: Luminescence Properties of Advanced Materials · Radiation Detection and Scintillator Technologies · Luminescence and Fluorescent Materials

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