journal article·2016-08

Electrochemical and anticorrosion behaviors of hybrid functionalized graphite nano-platelets/tripolyphosphate in epoxy-coated carbon steel

Somayeh Mohammadi, Homeira Shariatpanahi, Faramarz Afshar Taromi, Jaber Neshati

Publisher page

Abstract

Abstract Functionalized graphite nano-platelets (FGNP) were combined with tripolyphosphate (TPP) to gain a hybrid nano-particle (FGNP-TPP) with homogenous dispersion in epoxy, resulting in an excellent anti-corrosion coating for carbon steel substrate. Characterization analyses of the hybrid nano-particle were performed by FT-IR, SEM, XRD and TEM. TPP was linked to FGNP nano-particles by hydrogen bondings. Different epoxy coatings formulated with 1 wt.% of FGNP, FGNP-TPP and TPP were evaluated. Electrochemical investigations, salt spray and pull-off tests showed that the hybrid nano-particle can provide long-term corrosion protection compared to FGNP and TPP due to synergistic effect between FGNP as an accelerator and TPP as a corrosion inhibitor to produce a uniform and stable iron-phosphate passive film with high surface coverage.
Source: openaire · Quality: candidate unverified · Source record ↗

Research context

OpenAlex topics: Corrosion Behavior and Inhibition · Lubricants and Their Additives · Electrodeposition and Electroless Coatings

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

References (43)

Show source-provided references
1. A review on the mechanical and electrical properties of graphite and modified graphite reinforced polymer composites10.1016/j.progpolymsci.2010.11.003 ↗
2. Recent advances in graphene based polymer composites10.1016/j.progpolymsci.2010.07.005 ↗
3. Graphene-based polymer nanocomposites10.1016/j.polymer.2010.11.042 ↗
4. Processing of nanographene platelets (NGPs) and NGP nanocomposites: a review10.1007/s10853-008-2755-2 ↗
5. Review on polymer/graphite nanoplatelet nanocomposites10.1007/s10853-011-5572-y ↗
6. Interfacial, fire retardancy, and thermal stability evaluation of graphite oxide (GO)-phenolic composites with different GO particle sizes10.1016/j.compositesb.2013.04.063 ↗
7. Room-temperature cured hydrophobic epoxy/graphene composites as corrosion inhibitor for cold-rolled steel10.1016/j.carbon.2013.08.052 ↗
8. The production of a corrosion resistant graphene reinforced composite coating on copper by electrophoretic deposition10.1016/j.carbon.2013.04.063 ↗
9. Exploring graphene as a corrosion protection barrier10.1016/j.corsci.2011.12.003 ↗
10. Preparation and corrosion behavior of Ni and Ni–graphene composite coatings10.1016/j.materresbull.2012.12.064 ↗
11. Electrochemical and anticorrosion behavior of functionalized graphite nanoplatelets epoxy coating10.1016/j.jiec.2014.01.011 ↗
12. Phosphate ions as corrosion inhibitors for reinforcement steel in chloride-rich environments10.1016/j.electacta.2013.03.180 ↗
13. Long-term anticorrosion behaviour of polyaniline on mild steel10.1016/j.corsci.2006.11.007 ↗
14. Effect of phosphate based inhibitor on the threshold chloride to initiate steel corrosion in saturated hydroxide solution10.1016/j.conbuildmat.2013.08.054 ↗
15. Corrosion protection of mild steel by polypyrrole phosphate composite coating10.1016/j.porgcoat.2007.07.029 ↗
16. Anticorrosive polyurethane paints with nano- and microsized phosphates10.1016/j.porgcoat.2011.12.003 ↗
17. Three generations of inorganic phosphates in solvent and water-borne paints: a synergism case10.1016/j.apsusc.2005.02.096 ↗
18. Calcium tripolyphosphate: an anticorrosive pigment for paint10.1007/BF02698398 ↗
19. The role of a zinc phosphate pigment in the corrosion of scratched epoxy-coated steel10.1016/j.corsci.2008.11.015 ↗
20. Performance of anticorrosive coatings containing tripolyphosphates in aggressive environments10.1021/ie071544d ↗
21. Sodium tripolyphosphate (STPP) as a novel corrosion inhibitor for mild steel in 1M HCl
22. Evaluation of sodium hexametaphosphate as scale and corrosion inhibitor in cooling water using electrochemical techniques10.1016/j.desal.2012.11.017 ↗
23. Some tripolyphosphates as corrosion inhibitors for mild steel in 3% NaCl solution
24. The mechanism of inhibition by zinc phosphate in an epoxy coating10.1016/j.corsci.2012.11.025 ↗
25. Optimization of fabrication parameters to produce chitosan-tripolyphosphate nanoparticles for delivery of tea catechins10.1021/jf801111c ↗
26. Physico-chemical studies of MgNa3P3O10·12H2O
27. Intercalation compounds of trimethylphosphate in graphitic oxide10.1007/BF00665484 ↗
28. Polarization resistance method for determination of instantaneous corrosion rates10.5006/1.3280536 ↗
29. Synergistic effect on corrosion inhibiton efficiency of ginger affinale extract in controlling corrosion of mild steel in acid medium10.5012/jkcs.2013.57.6.672 ↗
30. Corrosion protection of carbon steel by an epoxy resin containing organically modified clay10.1016/j.surfcoat.2007.02.009 ↗
31. An electrochemical impedance spectroscopy study of the corrosion behaviour of PVD coated steels in 0.5N NaCl aqueous solution: part I. Establishment of equivalent circuits for EIS data modelling10.1016/S0010-938X(02)00213-5 ↗
32. Substitution of the constant phase element by Warburg impedance for protective coatings10.1016/j.corsci.2006.06.027 ↗
33. Poly(3-octylthiophene) and polystyrene blends thermally treated as coatings for corrosion protection of stainless steel 30410.1007/s10008-009-0969-0 ↗
34. Corrosion performance of polypyrrole coating applied to low carbon steel by an electrochemical process10.1016/S0013-4686(00)00519-3 ↗
35. A corrosion protective film formed on a carbon steel by an organic phosphonate10.1016/S0010-938X(97)00086-3 ↗
36. Electrochemical examining behavior of epoxy coating incorporating zinc-free phosphate-based anticorrosion pigment10.1016/j.porgcoat.2012.09.026 ↗
37. Studying the effects of micro and nano sized ZnO particles on the corrosion resistance and deterioration behavior of an epoxy-polyamide coating on hot-dip galvanized steel10.1016/j.porgcoat.2011.03.026 ↗
38. The effects of zinc aluminum phosphate (ZPA) and zinc aluminum polyphosphate (ZAPP) mixtures on corrosion inhibition performance of epoxy/polyamide coating10.1016/j.jiec.2012.11.027 ↗
39. Studying the corrosion protection properties of an epoxy coatingcontaining different mixtures of strontium aluminum polyphosphate (SAPP) and zinc aluminum phosphate (ZPA) pigments10.1016/j.porgcoat.2013.09.003 ↗
40. Cathodic disbondment of epoxy coating with zinc aluminum polyphosphate as a modified zinc phosphate anticorrosion pigment10.1016/j.porgcoat.2010.08.001 ↗
41. An electrochemical study of the delamination of polymer coatings on galvanized steel10.1016/j.corsci.2004.08.017 ↗
42. The effect of deposition temperature on the surface coverage and morphology of iron-phosphate coatings on low carbon steel10.1016/j.apsusc.2011.07.122 ↗
43. Studies on the electrochemical reduction of oxygen catalyzed by reduced graphene sheets in neutral media10.1016/j.jpowsour.2010.07.087 ↗