journal article·2019-11

Clinoptilolite modified with TiO2 for simultaneous elimination of two herbicides; 2,4-D and MCPA by UV and sunlight-assisted photocatalytic degradation

Zohreh Mehrabadi, Hossein Faghihian

Publisher page

Abstract

Abstract In this work, a photocatalyst prepared by titanium dioxide doped on clinoptilolite nanoparticles was used for simultaneous degradation of 2,4-dichlorophenoxyacetic acid (2,4-D), and 2-methyl-4-chlorophenoxyacetic acid (MCPA) mixture under ultraviolet and sunlight irradiations. The results indicated that by immobilization of titanium dioxide on clinoptilolite surface, the efficiency of photocatalyst by sunlight irradiation was significantly increased. This was in agreements with the results obtained by diffuse reflectance spectroscopy and photoluminescence analysis which respectively indicated that photocatalyst band gap shifted to the visible region and recombination of electron-hole was significantly reduced. To optimize the degradation efficiency, the effects of various experimental variables and different scavengers were studied. The degradation efficiency was estimated by determination of total organic carbon, and the degradation products were detected by HPLC technique.
Source: openaire · Quality: candidate unverified · Source record ↗

Research context

OpenAlex topics: Advanced oxidation water treatment · TiO2 Photocatalysis and Solar Cells · Advanced Photocatalysis Techniques

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

References (73)

Show source-provided references
1. Heavy metal ion removal of wastewater by zeolite-imidazolate frameworks10.1016/j.seppur.2017.11.068 ↗
2. Progress on the photocatalytic reduction removal of chromium contamination10.1002/tcr.201800153 ↗
3. Optimization of epoxypinane synthesis by silicotungstic acid supported on SBA-15 catalyst using response surface methodology10.1166/sam.2019.3473 ↗
4. Preparation and characterization of mesoporous CuO/ZSM-5 catalysts for automotive exhaust purification10.1166/sam.2019.3559 ↗
5. Component determination and their formation of PM2.510.1166/sam.2019.3526 ↗
6. Intracellular polymer substances induced conductive polyaniline for improved methane production from anaerobic wastewater treatmen10.1021/acssuschemeng.8b05847 ↗
7. Solvothermal synthesis, characterization and photocatalytic property of zirconium dioxide doped titanium dioxide spinous hollow microspheres with sunflower pollen as bio-templates
8. Supporting information for superhydrophobic/superoleophilic polycarbonate/carbon nanotubes porous monolith for selective oil adsorption from water10.1021/acssuschemeng.8b01637 ↗
9. Graphene oxide based dopamine mussel-like cross-linked polyethylene imine nanocomposite coating with enhanced hexavalent uranium adsorption10.1039/C9TA04562G ↗
10. Highly efficient uranium adsorption by salicylaldoxime/polydopamine graphene oxide nanocomposites10.1039/C8TA09486A ↗
11. Hexavalent chromium removal over magnetic carbon nanoadsorbent: synergistic effect of fluorine and nitrogen Co-doping10.1039/C8TA02861C ↗
12. Triple layered core–shell ZVI@carbon@polyaniline composite enhanced electron utilization in Cr(VI) reduction10.1039/C8TA03066A ↗
13. On-line monitoring of the photocatalytic degradation of 2,4-D and dicamba using a solid-phase extraction-multisyringe flow injection system10.1016/j.jenvman.2013.08.007 ↗
14. Simultaneous catalytic degradation of 2,4-D and MCPA herbicides using sulfate radical-based heterogeneous oxidation over persulfate activated by natural hematite (α-Fe2O3/PS)10.1016/j.jpcs.2018.02.009 ↗
15. Influence of 2,4-D and MCPA herbicides on uptake and translocation of heavy metals in wheat (Triticum aestivum L.)10.1016/j.envpol.2016.10.072 ↗
16. Study of the degradation of the herbicides 2,4-D and MCPA at different depths in contaminated agricultural soil10.1021/es0107226 ↗
17. Adsorption isotherm and kinetic modeling of 2,4-D pesticide on activated carbon derived from date stones10.1016/j.jhazmat.2008.06.069 ↗
18. Kinetic and equilibrium studies of simultaneous adsorption of monochlorophenols and chlorophenoxy herbicides on activated carbon10.1080/19443994.2013.780984 ↗
19. Oxidation of MCPA and 2,4-D by UV radiation, ozone, and the combinations UV/H2O2 and O3/H2O210.1081/PFC-120035925 ↗
20. Experimental and modeling study on adsorption of cationic methylene blue dye onto mesoporous biochars prepared from agrowaste10.1080/19443994.2016.1163736 ↗
21. Biodegradation of the herbicide 2,4-dichlorophenoxyacetic acid (2,4-D) in sequencing batch reactors10.1016/S0043-1354(98)00259-0 ↗
22. Analysis and modeling of the continuous electro-oxidation process for organic matter removal in urnan wastewater treatment10.1021/ie303021v ↗
23. Application of membrane processes for distillery wastewater purification-a review10.1080/19443994.2012.749178 ↗
24. Evaluation of the performance of adsorption and coagulation processes for the maximum removal of reactive dyes10.1016/j.dyepig.2005.03.008 ↗
25. Removal of 2-chlorophenol from water by adsorption combined with TiO2 photocatalysis10.1016/S0926-3373(02)00101-7 ↗
26. Removal of an anionic dye by adsorption/precipitation processes using alkaline white mud10.1016/j.jhazmat.2007.04.037 ↗
27. Sonochemical degradation of perfluorooctanesulfonate in aqueous film-forming foams10.1021/es902444r ↗
28. Treatment of hospital wastewater effluent by nanofiltration and reverse osmosis10.2166/wst.2010.119 ↗
29. Photodegradation of chlorpyrifos in water by UV/H2O2 treatment: toxicity evaluation10.2166/wst.2013.493 ↗
30. Ozonation of wastewater by dielectric barrier discharge and its impact on the elimination of fecal bacteria and inorganic micropollutants
31. Detoxification of diclofenac - a comparison between oxidative and reductive degradation processes10.1016/S0920-5861(99)00102-9 ↗
32. Comparative photocatalytic performance of TiO2 supported on clinoptilolite and TiO2/Salicylaldehyde-NH2-MIL-101(Cr) for degradation of pharmaceutical pollutant atenolol under UV and visible irradiations10.1016/j.jphotochem.2017.12.042 ↗
33. Synergistic effect of artificial enzyme and 2D nano-structured Bi2WO6 for eco-friendly and efficient biomimetic photocatalysis
34. Rational design of graphic carbon nitride copolymers by molecular doping for visible-light-driven degradation of aqueous sulfamethazine and hydrogen
35. BiOX (X=Cl, Br, I) photocatalytic nanomaterials: applications for fuels and environmental management10.1016/j.cis.2018.03.004 ↗
36. Construction of iodine vacancy-rich BiOI/Ag@AgI Z-scheme heterojunction photocatalysts for visible-light-driven tetracycline degradation: transformation pathways and mechanism insight
37. Boron nitride quantum dots decorated ultrathin porous g-C3N4: intensified exciton dissociation and charge transfer for promoting visible-light-driven molecular oxygen activation
38. An overview of nanostructural tungsten oxides and their nanocomposites for photoelectrochemical water splitting
39. Synthesis and characterization of ZnNiIn layered double hydroxides derived mixed metal oxides with highly efficient photoelectrocatalytic activities10.1021/acs.iecr.8b04829 ↗
40. Microwave solvothermal carboxymethyl chitosan templated synthesis of TiO2/ZrO2 composites toward enhanced photocatalytic degradation of Rhodamine B10.1016/j.jcis.2019.01.069 ↗
41. Enhanced photocatalytic activity of B, N-Codoped TiO2 by a new molten nitrate process10.1166/jnn.2019.15745 ↗
42. Microwave hydrothermal synthesis of In2O3-ZnO nanocomposites and their enhanced photoelectrochemical properties10.1149/2.0071905jes ↗
43. Solvothermal synthesis, characterization and photocatalytic property of zirconium dioxide doped titanium dioxide spinous hollow microspheres with sunflower pollen as bio-templates10.1016/j.jcis.2018.05.091 ↗
44. Synthesis, characterization and photocatalytic activity of mixed-metal oxides derived from NiCoFe ternary layered double hydroxides10.1039/C8DT01045E ↗
45. Elimination of highly consumed herbicide; 2,4-ichlorophenoxyacetic acid from aqueous solution by TiO2 impregnated clinoptilolite, study of degradation pathway10.1016/j.saa.2018.06.047 ↗
46. Versatility of heterogeneous photocatalysis: synthetic methodologies epitomizing the role of silica support in TiO2 based mixed oxides10.1155/2014/617405 ↗
47. Heterogeneous photodecolorization of mixture of methylene blue and bromophenol blue using CuO-nano-clinoptilolite10.1016/j.jiec.2013.07.027 ↗
48. Removal of zirconium from aqueous solution by modified clinoptilolite10.1016/j.jhazmat.2010.01.044 ↗
49. Effects of annealing treatment on microstructure and photocatalytic performance of nanostructured TiO2 coatings through flame spraying with liquid feedstocks10.1116/1.1788679 ↗
50. Optical, magnetic and photocatalytic activity studies of Li, Mg and Sr doped and undoped zinc oxide nanoparticles10.1166/jnn.2018.15442 ↗
51. Optical properties and electronic structure of amorphous germanium10.1002/pssb.19660150224 ↗
52. Ein Beitrag Zur Optik der farbanstriche
53. Comprehensive study on enhanced photocatalytic activity of heterojunction ZnS-NiS/ zeolite nanoparticles: experimental design based on response surface methodology (RSM), impedance spectroscopy and GC-MASS studies10.1016/j.jcis.2016.11.105 ↗
54. Sunlight-assisted decomposition of cephalexin by novel synthesized NiS-PPY-Fe3O4 nanophotocatalyst10.1016/j.jphotochem.2017.02.003 ↗
55. Luminescence from zinc oxide nanostructures and polymers and their hybrid devices10.3390/ma3042643 ↗
56. AgI/Ag heterojunction nanowires: facile electrochemical synthesis, photoluminescence, and enhanced ionic conductivity10.1002/adfm.200600590 ↗
57. Enhanced visible light photodegradation of pharmaceutical pollutant, warfarin by nano-sized SnTe, effect of supporting, catalyst dose, and scavengers10.1016/j.etap.2017.12.013 ↗
58. Novel g-C3N4/Ag2SO4 nanocomposites: fast microwave-assisted preparation and enhanced photocatalytic performance towards degradation of organic pollutants under visible light10.1016/j.jcis.2016.08.002 ↗
59. Hyperconjugation10.1002/wcms.6 ↗
60. McMurry · 2008
61. Application of a novel nanocomposite for desulfurization of a typical organo sulfur compound
62. Heterogeneous photodecolorization of mixture of methylene blue and bromophenol blue using CuO-nano-clinoptilolite10.1016/j.jiec.2013.07.027 ↗
63. Energy and exergy analyses of various typical solar energy applications: a comprehensive review10.1016/j.rser.2017.07.003 ↗
64. Solar energy: potential and future prospects10.1016/j.rser.2017.09.094 ↗
65. Photocatalytic degradation of paraquat herbicide in the presence TiO2 nanostructure thin films under visible and sun light irradiation using continuous flow photoreactor10.1016/j.solener.2015.07.010 ↗
66. Nanoparticles of zinc sulfide doped with manganese, nickel and copper as nanophotocatalyst in the degradation of organic dyes10.1016/j.jhazmat.2008.05.128 ↗
67. Photodecolorization of eriochrome black T using NiS-P zeolite as a heterogeneous catalyst10.1016/j.jhazmat.2009.11.077 ↗
68. Solar photodecolorization of methylene blue by CuO/X zeolite as a heterogeneous catalyst10.1016/j.apcata.2010.08.042 ↗
69. Effect of operational parameters on photodegradation of methylene blue on ZnS nanoparticles prepared in presence of an ionic liquid as a highly efficient photocatalyst10.1007/BF03254294 ↗
70. Bicarbonate activation of hydrogen peroxide: a new emerging technology for wastewater treatment10.1016/S1872-2067(15)61100-7 ↗
71. Application of TiO2–zeolite as photocatalyst for photodegradation of some organic pollutants
72. Enhancement in the photocatalytic activity of Ag loaded N-doped TiO2 nanocomposite under sunlight10.1007/s12034-011-0124-2 ↗
73. Critical Review of Rate Constants for reactions of hydrated electrons, hydrogen atoms and hydroxyl radicals (OH/O−) in aqueous solution