journal article·2013-06

Memory effect of hydrotalcites and its impact on cyanoethylation reaction

F. Teodorescu, A.-M. Pălăduţă, O.D. Pavel

Materials Research Bulletin· Volume 48· Issue 6
Publisher page

Abstract

Abstract The aim of this work is to study the changes of hydrotalcites structure when is subjected to gradual multiple calcination/hydration treatments in the presence of water or alkaline solution with the same composition like in co-precipitation step and then to analyze its influence on the catalytic activity in the cyanoethylation reaction between ethanol and acrylonitrile with the main product being beta-ethoxypropionitrile according to these treatment. The samples were characterized by elemental analysis, XRD, DRIFT, CO2-TPD.
Source: openaire · Quality: candidate unverified · Source record ↗

Research context

OpenAlex topics: Layered Double Hydroxides Synthesis and Applications · Mesoporous Materials and Catalysis · Inorganic Chemistry and Materials

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

References (26)

Show source-provided references
1. Cavani · Catal. Today · 1991 · 11 · 17310.1016/0920-5861(91)80068-K ↗
2. Tichit · Appl. Clay Sci. · 1998 · 13 · 40110.1016/S0169-1317(98)00035-0 ↗
3. Gill · Catal. Rev. · 2000 · 42 · 14510.1081/CR-100100261 ↗
4. Sels · Catal. Rev. · 2001 · 43 · 44310.1081/CR-120001809 ↗
5. Kabashima · Catal. Today · 1998 · 44 · 27710.1016/S0920-5861(98)00200-4 ↗
6. Ono · J. Catal. · 2003 · 216 · 40610.1016/S0021-9517(02)00120-3 ↗
7. Dumitriu · Appl. Catal. A: Gen. · 1999 · 178 · 14510.1016/S0926-860X(98)00282-8 ↗
8. Costantino · J. Mol. Catal. A: Chem. · 2003 · 195 · 24510.1016/S1381-1169(02)00580-0 ↗
9. Vaccari · Appl. Clay Sci. · 1999 · 14 · 16110.1016/S0169-1317(98)00058-1 ↗
10. Marchi · Appl. Clay Sci. · 1998 · 13 · 3510.1016/S0169-1317(98)00011-8 ↗
11. Takehira · J. Catal. · 2005 · 231 · 9210.1016/j.jcat.2005.01.025 ↗
12. Pavel · Catal. Comm. · 2008 · 9 · 197410.1016/j.catcom.2008.03.027 ↗
13. Pavel · Catal. Comm. · 2011 · 12 · 84510.1016/j.catcom.2011.02.005 ↗
14. Prinetto · Catal. Today · 2000 · 55 · 10310.1016/S0920-5861(99)00230-8 ↗
15. Chaphekar · Appl. Catal. A: Gen. · 2003 · 242 · 1110.1016/S0926-860X(02)00491-X ↗
16. Kumbhar · Chem. Commun. · 1998 · 10 · 109110.1039/a801872c ↗
17. Jyothi · J. Mol. Catal. A: Chem. · 2000 · 157 · 19310.1016/S1381-1169(99)00439-2 ↗
18. Corma · J. Catal. · 1994 · 148 · 20510.1006/jcat.1994.1202 ↗
19. Corma · Appl. Catal. A: Gen. · 1993 · 105 · 27110.1016/0926-860X(93)80252-L ↗
20. Gazzano · J. Phys. Chem. B · 1997 · 101 · 451410.1021/jp963761q ↗
21. Prabhakaran · Mater. Res. Bull. · 2009 · 44 · 61310.1016/j.materresbull.2008.06.029 ↗
22. Mosayebi · Mater. Res. Bull. · 2012 · 47 · 215410.1016/j.materresbull.2012.06.010 ↗
23. Frost · Vib. Spectrosc. · 1998 · 16 · 17310.1016/S0924-2031(98)00014-9 ↗
24. Diez · J. Catal. · 2003 · 215 · 22010.1016/S0021-9517(03)00010-1 ↗
25. Corma · J. Catal. · 1992 · 134 · 5810.1016/0021-9517(92)90209-Z ↗
26. Di Cosimo · J. Catal. · 1998 · 178 · 49910.1006/jcat.1998.2161 ↗