journal article·2019-04

Novel I-doped Bi12O17Cl2 photocatalysts with enhanced photocatalytic activity for contaminants removal

Minna Guo, Heng He, Jing Cao, Haili Lin, Shifu Chen

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Abstract

Abstract Novel I-doped Bi12O17Cl2 photocatalysts have been synthesized using a facile chemical precipitation method and characterized by XRD , XPS , SEM, BET and UV–vis DRS etc. The corresponding results indicate that I − ions enter into the crystal lattices of Bi 12O17Cl2 and replace partial Cl− ions. In addition, the doped I− ions form an impurity level over valence band and extend the visible light absorption ranges of Bi12O17Cl2. I-doped Bi12O17Cl2 exhibits much superior visible-light (λ > 420 nm) photocatalytic activity to that of the pure Bi12O17Cl2 in the methyl orange (MO) and phenol degradation, because a little amount of I− ions can boost the photocharges separation efficiency, which is ensured by photoluminescence spectra, transient photocurrent responses and electrochemical impedance spectra. It is expected that this work opens a new potential pathway to improve the photocatalytic activity of non-stoichiometric ratios bismuth oxyhalide via ions doping strategy.
Source: openaire · Quality: candidate unverified · Source record ↗

Research context

OpenAlex topics: Advanced Photocatalysis Techniques · Covalent Organic Framework Applications · Perovskite Materials and Applications

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

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