journal article·2018-07

TiO2 nanotubes grown on Ti substrates with different microstructure

Hanna Sopha, Karel Tesar, Petr Knotek, Ales Jäger, Ludek Hromadko, Jan M. Macak

Publisher page

Abstract

Abstract Four Ti substrates with various microstructures were investigated for the anodic growth of TiO2 nanotube layers: nanocrystalline and single-crystalline ingots as well as microcrystalline thick Ti sheets and microcrystalline thin Ti foils. All substrates were anodized in a conventional ethylene glycol based electrolyte under identical conditions. The resulting TiO2 nanotube layers were compared in dimensions and the consumption of Ti required for their growth. Unexpectedly, the results showed that on all substrates nanotube layers with a similar thickness and nanotube diameter, as well as a similar degree of ordering and after annealing the same crystallographic orientation of anatase were received, regardless the microstructures. However, the nanotube layers grown on a Ti sheet revealed a slightly higher thickness compared to the other substrates which were assigned to slower field-assisted dissolution rates due to different impurities found in this substrate compared to other ones.
Source: openaire · Quality: candidate unverified · Source record ↗

Research context

OpenAlex topics: Anodic Oxide Films and Nanostructures · TiO2 Photocatalysis and Solar Cells · Electrocatalysts for Energy Conversion

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

References (42)

Show source-provided references
1. Oxide morphology and adhesive bonding on titanium surfaces10.1007/BF02396935 ↗
2. TiO2 nanotubes: Self-organized electrochemical formation, properties and applications10.1016/j.cossms.2007.08.004 ↗
3. TiO2 nanotubes, nanochannels and mesosponge: Self-organized formation and applications10.1016/j.nantod.2013.04.010 ↗
4. One-dimensional titanium dioxide nanomaterials: nanotubes10.1021/cr500061m ↗
5. TiO2 nanotubes: Tailoring the geometry in H3PO4/HF electrolytes10.1016/j.elecom.2006.05.030 ↗
6. Mechanistic aspects and growth of large diameter self-organized TiO2 nanotubes10.1016/j.jelechem.2008.01.005 ↗
7. Titanium oxide nanotubes prepared in phosphate electrolytes10.1016/j.elecom.2005.03.007 ↗
8. Towards ideal self-ordering of TiO2 nanotubes10.1002/pssr.200701148 ↗
9. Highly ordered nanoporous TiO2 and its photocatalytic properties10.1016/j.elecom.2007.10.014 ↗
10. Anodization fabrication of highly ordered TiO2 nanotubes10.1021/jp903037f ↗
11. Anodization of nanoimprinted titanium: a comparison with formation of porous alumina10.1016/j.electacta.2004.02.015 ↗
12. Effects of titania nanotube distance and arrangement during focused ion beam guided anodization10.1039/c1jm11083g ↗
13. Ideally ordered porous TiO2 prepared by anodization of pretextured Ti by nanoimprinting process10.1016/j.elecom.2014.11.013 ↗
14. Long-range hexagonal arrangement of TiO2 nanotubes by soft lithography-guided anodization10.1016/j.electacta.2016.04.016 ↗
15. Ideally hexagonally ordered TiO2 nanotube arrays
16. Ordered metal nanohole arrays made by a two-step replication of honeycomb structures of anodic alumina10.1126/science.268.5216.1466 ↗
17. Highly ordered nanochannel-array architecture in anodic alumina10.1063/1.120128 ↗
18. Donachie · 2007
19. Self-organized anodic TiO2 nanotube layers: Influence of the Ti substrate on nanotube growth and dimensions10.1016/j.electacta.2015.12.121 ↗
20. Polishing effect on anodic titania nanotube formation10.1016/j.electacta.2011.04.098 ↗
21. Microstructure of polycrystalline Ti and its microelectrochemical properties by means of electron-backscattering diffraction (EBSD)10.1016/S0013-4686(01)00572-2 ↗
22. Tailoring TiO2 nanotube growth during anodic oxidation by crystallographic orientation of Ti10.1016/j.scriptamat.2009.01.043 ↗
23. TiO2 nanotubes: Interdependence of substrate grain orientation and growth characteristics10.1021/jp209418n ↗
24. TiO2 nanotubes: Interdependence of substrate grain orientation and growth rate10.1021/am507181p ↗
25. Influence of the Ti microstructure on anodic self-organized TiO2 nanotube layers produced in ethylene glycol electrolytes10.1016/j.apsusc.2016.03.012 ↗
26. Formation of anodic TiO2 nanotube arrays with bimodal pore size distribution10.1016/j.elecom.2013.03.007 ↗
27. Effect of nanostructured titanium on anodization growth of self-organized TiO2 nanotubes
28. Effects of substrate microstructure on the formation of oriented oxide nanotube arrays on Ti and Ti alloys10.1016/j.apsusc.2013.08.041 ↗
29. Achieving homogeneous anodic TiO2 nanotube layers through grain refinement of the titanium substrate10.1016/j.matdes.2016.07.144 ↗
30. The influence of surface roughness and high pressure torsion on the growth of anodic titania nanotubes on pure titanium10.1016/j.apsusc.2016.07.036 ↗
31. Microstructure and anisotropy of the mechanical properties in commercially pure titanium after equal channel angular pressing with back pressure at room temperature10.1016/j.msea.2015.07.038 ↗
32. Effect of the electrolyte age and potential changes on the morphology of TiO2 nanotubes10.1016/j.jelechem.2015.11.002 ↗
33. AFM imaging and analysis of local mechanical properties for detection of surface pattern of functional groups10.1016/j.msec.2013.01.006 ↗
34. Photo-expansion in Ge-As-S amorphous film monitored by digital holographic microscopy and atomic force microscopy
35. Mechanistic aspects of the self-organization process for oxide nanotube formation on valve metals10.1149/1.2749091 ↗
36. Polishing effect on anodic titania nanotube formation10.1016/j.electacta.2011.04.098 ↗
37. Self-organized porous and tubular oxide layers on Ti Al alloys10.1016/j.elecom.2007.07.013 ↗
38. Transition from nanopores to nanotubes: Self-ordered anodic oxide structures on titanium-aluminides10.1021/cm8004024 ↗
39. Investigation of anodic TiO2 nanotube composition with high spatial resolution AES and ToF SIMS10.1016/j.apsusc.2017.10.132 ↗
40. Anodic growth of self-organized anodic TiO2 nanotubes in viscous electrolytes10.1016/j.electacta.2006.07.021 ↗
41. Influence of anodization parameters on the expansion factor of TiO2 nanotubes10.1016/j.electacta.2012.12.094 ↗
42. Highly ordered nanoporous TiO2 and its photocatalytic properties10.1016/j.elecom.2007.10.014 ↗