journal article·2019-05

Copper ferrite synthesis from spent Li-ion batteries for multifunctional application as catalyst in photo Fenton process and as electrochemical pseudocapacitor

A.K.S. Rocha, L.B. Magnago, J.J. Santos, V.M. Leal, A.A.L. Marins, V.C.B. Pegoretti, S.A.D. Ferreira, M.F.F. Lelis, M.B.J.G. Freitas

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Abstract

Abstract In this study, from copper recycled from spent lithium-ion batteries (LiBs) is made the synthesis of cupper ferrite (CuFe2O4-LiB). X-ray diffraction, energy dispersive X-ray spectroscopy and inductively coupled plasma optical emission spectrometry (ICP OES) identified the structure and composition of CuFe2O4-LiB. Scanning electron microscopy and transmission electron microscopy showed agglomerates of nanometric spherical particles. This study investigated the multifunctionality of CuFe2O4-LiB. Photocatalytic properties were analyzed by monitoring the decolorization of methylene blue (MB) in a heterogeneous photo-Fenton process in the presence of solar radiation. Decolorization efficiency was 96.1% in 45 min of reaction. Ion chromatography detected formic and acetic acids as products of MB degradation, and by ICP OES measured lower concentrations of 0.09 mgL−1 and 0.37 mgL−1, respectively for iron and copper ions in the treated solution. CuFe2O4-LiB electrodes showed great reversibility, charge efficiency, and a specific capacitance of 2.4 Fg−1 (10.0 mVs−1), which are favorable characteristics for pseudocapacitors.
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Research context

OpenAlex topics: Advancements in Battery Materials · Supercapacitor Materials and Fabrication · Advanced battery technologies research

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