journal article·2018-07

Blue photons excited highly chromatic red light emitting K3La(PO4)2:Pr3+ phosphors for white light emitting diodes

A.K. Bedyal, D.D. Ramteke, Vinay Kumar, H.C. Swart

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Abstract

Abstract Highly chromatic blue photons excited red emitting K3La(PO4)2:Pr3+ (0–1.8 mol%) phosphors were synthesized by solution combustion method. The resulted phosphors showed peanut like morphology and had a monoclinic phase with space group P21/m. The photoluminescence studies disclosed that the phosphor emits red light due to the 1D2 → 3H4 and 1D2 → 3H5 transition of the Pr3+ ions under blue photons excitation. The optimal concentration for the Pr3+ ions were optimized to be 1.2 mol% after which concentration quenching occurred. Dipole-dipole interaction among the dopant ions was found to be responsible for the concentration quenching. X-ray photoelectron spectroscopy results depicted that Pr was present in the (+3) valance state in the phosphor. The photometric results suggest that the phosphor with a high color purity ∼ 97.8% and enough quantum yield ∼27% could be an eventual choice as the red component for white light emitting diodes.
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Research context

OpenAlex topics: Luminescence Properties of Advanced Materials · Radiation Detection and Scintillator Technologies · Gas Sensing Nanomaterials and Sensors

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

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