Preparation of LiFePO4 with inverse opal structure and its satisfactory electrochemical properties

Phase pure, well-crystallized and homogeneous LiFePO{sub 4} powder with inverse opal structure was obtained by calcining the precursors of Li{sup +}, Fe{sup 2+} and PO{sub 4} {sup 3-} in the presence of organic template of poly(styrene-methyl methacrylate-acrylic acid) latex micro-spheres under nitrogen atmosphere. The resultant products were characterized by X-ray powder diffraction (XRD), scanning electron microscopy (SEM), X-ray photoelectron spectroscopy (XPS), chemical titration, Fourier transform infrared (FTIR) and Land 2001A electrochemical measurement system. Results indicated that after the decomposition of organic template, inverse opal structure and conductive carbon were left in the resultant products. With the large specific surface area resulting from inverse opal structure and with the conductive carbon, the products delivered satisfactory capacity and superior rate capability at room temperature, i.e., over 100 mAh/g at the high current density of 5.9C.