Hydrothermal synthesis and electrical properties of NaNbO3

Abstract Triangular prism-like of crystalline rhombohedral sodium niobate (r-NaNbO 3 ) were prepared from Nb 2 O 5 in the presence of NaOH via a hydrothermal method at 180 °C for 6 h. Techniques X-ray diffraction, scanning electron microscopy, Fourier transform infrared, Raman and impedance spectroscopy have been used to characterize the structure, morphology, composition and electrical properties of the material. Electrical conductivity measurements showed that the as synthesized r-NaNbO 3 triangular prism has a conductivity value which goes from 5.5 × 10 −6 Ω −1 cm −1 at 280 °C to 7.61 × 10 −4 Ω −1 cm −1 at 780 °C. The Arrhenius diagram is not linear; it presents four regions of conductivity. The corresponding activation energies are, respectively, in the order of 0.893, 0.507, 0.819 and 0.105 eV, deduced from the Arrhenius relation.