journal article·2014-12

Facile synthesis of Ag–Cu 2 O composites with enhanced photocatalytic activity

Jianbo Yang, Zhen Li, Caixin Zhao, Yang Wang, Xueqin Liu

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Abstract

Abstract Silver–cuprous oxide (Ag–Cu 2 O) microcomposites are successfully prepared by a facile low-cost solution method. The obtained materials were characterized by X-ray diffraction (XRD), energy-dispersive X-ray spectroscopy (EDX), field emission scanning electron microscopy (FESEM), ultraviolet–visible (UV–vis) spectroscopy, X-ray photoelectron spectroscopy (XPS). Experiments demonstrated that the formation of Ag–Cu 2 O microcomposites was significantly influenced by the concentration of AgNO 3 , and with increasing the concentration of AgNO 3 , the optical absorption of the composites becomes strong. The photocatalytic activity of the prepared Ag–Cu 2 O composites was determined by measuring the degradation of methyl orange solution under visible light, to find out its potential application in waste water treatment. The results reveal that the photocurrent of the composite is about 4 times higher than that of pure Cu 2 O and the visible light photocatalytic activity of the composite is enhanced greatly on degradation of methyl orange. The reason for improvement in photocatalytic activity of the Ag–Cu 2 O composites was also discussed.
Source: openaire · Quality: candidate unverified · Source record ↗

Research context

OpenAlex topics: Copper-based nanomaterials and applications · Advanced Photocatalysis Techniques · ZnO doping and properties

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

References (36)

Show source-provided references
1. One-dimensional shape-controlled preparation of porous Cu2O nano-whiskers by using CTAB as a template10.1016/j.jssc.2004.10.025 ↗
2. One-pot synthesis of octahedral Cu2O nanocages by a catalytic solution route10.1002/adma.200501128 ↗
3. Electrical, structural and optical characterization of copper oxide thin films as a function of post annealing temperature10.1002/pssa.200881797 ↗
4. Synthesis and characterization of Cu2O nanowires by a novel reduction route10.1002/1521-4095(20020104)14:1<67::AID-ADMA67>3.0.CO;2-Z ↗
5. Nano-sized copper tungstate thin films as positive electrodes for rechargeable Li batteries10.1016/j.electacta.2008.01.014 ↗
6. Gram-scale synthesis of Cu2O nanocubes and subsequent oxidation to CuO hollow nanostructures for lithium-ion battery anode materials10.1002/adma.200800596 ↗
7. Nearly monodisperse Cu2O and CuO nanospheres: preparation and applications for sensitive gas sensors10.1021/cm052256f ↗
8. One-pot synthesis and hierarchical assembly of hollow Cu2O microspheres with nanocrystals-composed porous multishell and their gas-sensing properties10.1002/adfm.200601146 ↗
9. Self-assembled Cu2O flowerlike architecture: polyol synthesis, photocatalytic activity and stability under simulated solar light10.1016/j.materresbull.2010.04.009 ↗
10. H2 evolution from a photoelectrochemical cell with n-Cu2O photoelectrode under visible light irradiation10.1016/S0927-0248(00)00416-5 ↗
11. Water photoreduction with Cu2O quantum dots on TiO2 nano-particles10.1016/j.jphotochem.2004.10.018 ↗
12. A highly efficient Ag-ZnO photocatalyst: synthesis, properties, and mechanism10.1021/jp802729a ↗
13. One-pot synthesis of Ag/ZnO self-assembled 3D hollow microspheres with enhanced photocatalytic performance10.1021/jp803654k ↗
14. Towards a highly efficient simulated sunlight driven photocatalyst: a case of heterostructured ZnO/ZnS hybrid structure10.1039/c3dt51712h ↗
15. Photocatalytic degradation of organic dyes with hierarchical Ag2O/ZnO heterostructures10.1166/sam.2013.1597 ↗
16. Surface-enhanced Raman scattering-active Au/TiO2 films prepared by electrochemical and photochemical methods10.1016/j.materresbull.2012.10.040 ↗
17. Facet-dependent and Au nanocrystal-enhanced electrical and photocatalytic properties of Au-Cu2O core-shell heterostructures10.1021/ja109182y ↗
18. Controlled growth of ZnO nanorods on textured silicon wafer and the application for highly effective and recyclable SERS substrate by decorating Ag nanoparticles10.1016/j.materresbull.2014.02.027 ↗
19. In situ Fenton reagent generated from TiO2/Cu2O composite film: a new way to utilize TiO2 under visible light irradiation10.1021/es070345i ↗
20. Moudler · 1992
21. Interfacial hydrothermal synthesis of Cu@Cu2O core-shell microspheres with enhanced visible-light-driven photocatalytic activity10.1021/jp9083647 ↗
22. Morphological evolution of Cu2O nanocrystals in an acid solution: stability of different crystal planes10.1021/la104475s ↗
23. Facile electrochemical synthesis of hexagonal Cu2O nanotube arrays and their application10.1021/ic1017664 ↗
24. A hierarchically ordered TiO2 hemispherical particle array with hexagonal-non-close-packed tops: synthesis and stable superhydrophilicity without UV irradiation10.1002/smll.200800428 ↗
25. Fabrications of hollow nanocubes of Cu2O and Cu via reductive self-assembly of CuO nanocrystals10.1021/la060439q ↗
26. Characterizing well-ordered CuO nanofibrils synthesized through gas–solid reactions10.1063/1.1690114 ↗
27. Copper nanoparticles grown under hydrogen: study of the surface oxide10.1016/j.apsusc.2010.12.082 ↗
28. Crystal plane-dependent compositional and structural evolution of uniform Cu2O nanocrystals in aqueous ammonia solutions10.1021/jp206966f ↗
29. Hexagonal-close-packed, hierarchical amorphous TiO2 nanocolumn arrays: transferability, enhanced photocatalytic activity, and superamphiphilicity without UV irradiation10.1021/ja805077q ↗
30. Electrostatic assembly of Cu2O nanoparticles on DNA templates10.1016/j.apsusc.2005.03.212 ↗
31. Cu2O as a photocatalyst for overall water splitting under visible light irradiation10.1039/a707440i ↗
32. Highly efficient visible light plasmonic photocatalyst Ag@ Ag (Br, I)10.1002/chem.200903361 ↗
33. The absolute energy positions of conduction and valence bands of selected semiconducting minerals10.2138/am-2000-0416 ↗
34. Nanoclusters of semiconductors and metals: colloidal nano‐particles of semiconductors and metals: electronic structure and processes10.1002/bbpc.19971011103 ↗
35. Ag/ZnO heterostructure nanocrystals: synthesis, characterization, and photocatalysis10.1021/ic700688f ↗
36. One-pot synthesis of Ag/ZnO self-assembled 3D hollow microspheres with enhanced photocatalytic performance10.1021/jp803654k ↗