journal article·2020-02

Improved visible-light activities of g-C3N4 nanosheets by co-modifying nano-sized SnO2 and Ag for CO2 reduction and 2,4-dichlorophenol degradation

Wajid Ali, Xuliang Zhang, Xinxin Zhang, Sharafat Ali, Lina Zhao, Shabana Shaheen, Liqiang Jing

Publisher page

Abstract

Abstract Graphitic carbon nitride (g-C3N4) usually exhibits weak photocatalytic activity for CO2 reduction and pollutant degradation. Herein, the visible-light activities of g-C3N4 nanosheets are successfully improved by co-modifying SnO2 and Ag, with ∼10-time and ∼8-time improvement respectively for CO2 conversion and 2,4-dichlorophenol (2,4-DCP) degradation as compared to the pure g-C3N4. Mainly based on the transient-state surface photovoltage responses, transient-state photoluminescence spectra and electrochemical analyses, it is confirmed that the improved photoactivities are attributed to the synergistic effect of the prolonged charge lifetime and the provided catalytic function by modifying SnO2 and Ag, respectively. In addition, the synergistic effect is also feasible by replacing Ag with Au. This work will provide an effective strategy for designing high-activity g-C3N4 based photocatalysts.
Source: openaire · Quality: candidate unverified · Source record ↗

Research context

OpenAlex topics: Advanced Photocatalysis Techniques · Perovskite Materials and Applications · Electronic and Structural Properties of Oxides

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

References (54)

Show source-provided references
1. Critical aspects and recent advances in structural engineering of photocatalysts for sunlight-driven photocatalytic reduction of CO210.1002/adfm.201901825 ↗
2. Porous hypercrosslinked polymer-TiO2-graphene composite photocatalysts for visible-light-driven CO2 conversion10.1038/s41467-019-08651-x ↗
3. Catalysts made of earth-abundant elements (Co, Ni, Fe) for water splitting: recent progress and future challenges10.1039/c2ee03250c ↗
4. Tailoring grain boundary chemistry of polymeric carbon nitride for enhanced solar H2 production and CO2 reduction10.1002/anie.201811938 ↗
5. Nature-based catalyst for visible-light-driven photocatalytic CO2 reduction10.1039/C8EE01781F ↗
6. CO2 reduction: from the electrochemical to photochemical approach10.1002/advs.201700194 ↗
7. Synthesis of S-doped porous g-C3N4 by using ionic liquids and subsequently coupled with Au-TiO2 for exceptional cocatalyst-free visible-light catalytic activities10.1016/j.apcatb.2018.06.009 ↗
8. Enhanced photocatalytic activities of commercial P25 TiO2 by trapping holes and transferring electrons for CO2 conversion and 2,4-dichlorophenol degradation10.1016/j.materresbull.2017.04.004 ↗
9. Enhanced photocatalytic CO2 reduction and 2,4-dichlorophenol degradation of TiO2 nanotubes via bi-directionally controlling electrons and holes10.1016/j.chemosphere.2019.03.149 ↗
10. Dimension-matched plasmonic Au/TiO2/BiVO4 nanocomposites as efficient wide-visible-light photocatalysts to convert CO2 and mechanistic insights10.1039/C8TA02889C ↗
11. Tuning product selectivity for aqueous CO2 reduction with a Mn(bipyridine)-pyrene catalyst immobilized on a carbon nanotube electrode10.1021/jacs.7b06269 ↗
12. Noble metal-metal oxide nanohybrids with tailored nanostructures for efficient solar energy conversion, Photocatalysis and Environmental Remediation10.1039/C6EE02265K ↗
13. Phosphorous doped carbon nitride nanobelts for photodegradation of emerging contaminants and hydrogen evolution10.1016/j.apcatb.2019.117931 ↗
14. Non-metal boron modified carbon nitride tube with enhanced visible light-driven photocatalytic performance10.1016/j.materresbull.2018.10.009 ↗
15. Facile preparation of CuO/g-C3N4 with enhanced photocatalytic degradation of salicylic acid10.1016/j.materresbull.2018.04.038 ↗
16. Effective visible-excited charge separation in silicate-bridged ZnO/BiVO4 nanocomposite and its contribution to enhanced photocatalytic activity10.1021/am505651d ↗
17. Photocatalytic conversion of CO2 into renewable hydrocarbon fuels: state-of-the-Art accomplishment, challenges, and prospects10.1002/adma.201400087 ↗
18. Enhanced photocatalytic activity of g-C3N4 for selective CO2 reduction to CH3OH via facile coupling of ZnO: a direct Z-scheme mechanism10.1039/C5TA05503B ↗
19. Surface-halogenation-induced atomic-site activation and local charge separation for superb CO2 photoreduction10.1002/adma.201900546 ↗
20. Metal-free g-C3N4 photocatalysis of organic micropollutants in urban wastewater under visible light10.1016/j.apcatb.2019.02.001 ↗
21. Graphitic carbon nitride nanosheets as highly efficient photocatalysts for phenol degradation under high-power visible LED irradiation10.1016/j.materresbull.2017.12.049 ↗
22. Investigating the role of tunable Nitrogen vacancies in graphitic carbon nitride nanosheets for efficient visible-light-driven H2 evolution and CO2 reduction10.1021/acssuschemeng.7b01477 ↗
23. Graphitic carbon nitride (g-C3N4)-based photocatalysts for artificial photosynthesis and environmental remediation: are we a step closer to achieving sustainability?10.1021/acs.chemrev.6b00075 ↗
24. A new and stable Mo-Mo2C modified g-C3N4 photocatalyst for efficient visible light photocatalytic H2 production10.1016/j.apcatb.2018.10.016 ↗
25. Graphitic carbon nitride polymers toward sustainable photoredox catalysis10.1002/anie.201501788 ↗
26. Enhanced charge separation ability and visible light photocatalytic performance of graphitic carbon nitride by binary S, B co-doping10.1016/j.materresbull.2018.08.021 ↗
27. Carbon nitrides and metal nanoparticles: from controlled synthesis to design principles for improved photocatalysis10.1039/C8CS00479J ↗
28. Facile surfactant assistant synthesis of porous oxygen-doped graphitic carbon nitride nanosheets with enhanced visible light photocatalytic activity10.1016/j.materresbull.2017.02.042 ↗
29. Physical theory of excitons in conducting polymers10.1039/b917724h ↗
30. Semiconducting polymers: the third generation10.1039/b914956m ↗
31. Synthesis of large surface-area g-C3N4 co-modifid with MnOx and Au-TiO2 as efficient visible-light photocatalysts for fuel production
32. Growth of ZnO nanorods on graphitic carbon nitride gCN sheets for the preparation of photocatalysts with high visible‐light activity10.1002/cctc.201801206 ↗
33. Single-atom Pt as co-catalyst for enhanced photocatalytic H2 evolution10.1002/adma.201505281 ↗
34. Single atom (Pd/Pt) supported on graphitic carbon nitride as an efficient photocatalyst for visible-light reduction of carbon dioxide10.1021/jacs.6b02692 ↗
35. Uncovering the key role of the fermi level of the electron mediator in a Z-scheme photocatalyst by detecting the charge transfer process of WO3-metal-gC3N4 (Metal=Cu, Ag, Au)10.1021/acsami.5b10613 ↗
36. Exceptional visible-light activities of g-C3N4 nanosheets dependent on the unexpected synergistic effects of prolonging charge lifetime and catalyzing H2 evolution with H2O10.1016/j.apcatb.2018.05.034 ↗
37. Photocatalytic reduction of CO2 on TiO2 and other semiconductors10.1002/anie.201207199 ↗
38. Sb doped SnO2-decorated porous g-C3N4 nanosheet heterostructures with enhanced photocatalytic activities under visible light irradiation10.1016/j.apcatb.2017.09.041 ↗
39. Boosting up the low catalytic activity of silver for H2 production on Ag/TiO2 photocatalyst: thiocyanate as a selective modifier10.1021/acscatal.5b02376 ↗
40. In situ growth of Pd nanosheets on g-C3N4 nanosheets with well-contacted interface and enhanced catalytic performance for 4-nitrophenol reduction10.1002/smll.201801812 ↗
41. Effect of calcination temperature on the photoactivities of ZnO/SnO2 nanocomposites for the degradation of methyl orange10.1016/j.matchemphys.2018.04.015 ↗
42. Ag nanoparticles decorated WO3/g-C3N4 2D/2D heterostructure with enhanced photocatalytic activity for organic pollutants degradation
43. Phosphorous doped carbon nitride nanobelts for photodegradation of emerging contaminants and hydrogen evolution10.1016/j.apcatb.2019.117931 ↗
44. Watching visible light-driven CO2 reduction on a plasmonic nanoparticle catalyst10.1021/acsnano.8b03617 ↗
45. Microwave-assisted and gram-scale synthesis of ultrathin SnO2 nanosheets with enhanced lithium storage properties10.1021/am507826d ↗
46. Exceptional visible-light-driven cocatalyst-free photocatalytic activity of g-C3N4 by well designed nanocomposites with plasmonic Au and SnO210.1002/aenm.201601190 ↗
47. Silver loaded protonated graphitic carbon nitride (Ag/pg-C3N4) nanosheets for stimulating CO2 reduction to fuels via photocatalytic bi-reforming of methane10.1016/j.apsusc.2019.06.257 ↗
48. n, In situ fabrication of hierarchically porous g-C3N4 and understanding on its enhanced photocatalytic activity based on energy absorption10.1016/j.apcatb.2018.04.082 ↗
49. Long‐lived, visible‐light‐excited charge carriers of TiO2/BiVO4 nanocomposites and their unexpected photoactivity for water splitting10.1002/aenm.201300995 ↗
50. Semiconductor polymeric graphitic carbon nitride photocatalysts: the “holy grail” for the photocatalytic hydrogen evolution reaction under visible light10.1039/C9EE00717B ↗
51. Time-resolved spectroscopic investigation of charge trapping in carbon nitrides photocatalysts for hydrogen generation10.1021/jacs.7b01547 ↗
52. Synthesis of synergetic phosphorus and cyano groups (−C≡N) modified g-C3N4 for enhanced photocatalytic H2 production and CO2 reduction under visible light irradiation10.1016/j.apcatb.2018.03.094 ↗
53. Robust binding between carbon nitride nanosheets and a binuclear ruthenium(II) complex enabling durable, selective CO2 reduction under visible light in aqueous solution10.1002/anie.201701627 ↗
54. Surface co-modification with highly-dispersed Mn & Cu oxides of g-C3N4 nanosheets for efficiently photocatalytic reduction of CO2 to CO and CH410.1016/j.apsusc.2019.06.189 ↗