Synthesis, characterization and magnetic properties of NiS1+x nanocrystals from [bis(salicylidene)nickel(II)] as new precursor

Abstract [Bis(salicylidene)nickel(II)] was used as a precursor to prepare nickel sulfides nanoparticles of average size 20 nm by a chemical process in oleylamine. The products were characterized by X-ray diffraction (XRD), scanning electron microscope (SEM), transmission electron microscope (TEM), X-ray photoelectron spectroscopy (XPS), ultraviolet–visible spectroscopy (UV–vis) and photoluminescence (PL) spectroscopy. Magnetization measurement indicates that both of the α-NiS and Ni 3 S 4 nanoparticles show pramagnetism due to the size effect.