journal article·2015-04

Controllable preparation, characterization and performance of Cu2O thin film and photocatalytic degradation of methylene blue using response surface methodology

Xiaojiao Yu, Linzhu Huang, Yuchen Wei, Jian Zhang, Zhuozhuo Zhao, Wenqin Dai, Binghua Yao

Publisher page

Abstract

Abstract Cu2O thin film is prepared using the electrodeposition approach. XRD, XPS, SEM, PL and UV–vis are used to characterize the thin film microstructure, morphology and optical properties. Response surface methodology is employed to optimize the main influences of photocatalytic degradation, the quadratic multinomial mathematical model is also established. Photocatalytic degradation process of methylene blue is studied as well. The results indicate that the prepared Cu2O thin film is of high-purity with the preferential orientation of (1 1 1). R2 is 0.9888 in the established quadratic model, which is of better fitness and higher significance. The optimal degradation conditions are obtained. Under this condition, degradation rate of methylene blue can reach over 98.2% in 3 h. The methylene blue molecules can be decomposed completely. Recycling results reveal that more than 94.2% of methylene blue can be decomposed within 7 cycles, which could still reach 81.8% after 11 cycles.
Source: openaire · Quality: candidate unverified · Source record ↗

Research context

OpenAlex topics: Copper-based nanomaterials and applications · ZnO doping and properties · Electronic and Structural Properties of Oxides

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

References (31)

Show source-provided references
1. On the engineering part of solar hydrogen production from water splitting: photoreactor design10.1016/j.ces.2013.08.039 ↗
2. Facile synthesis of Cu2O nanocube/polycarbazole composites and their high visible-light photocatalytic properties10.1016/j.jssc.2011.03.055 ↗
3. Review of preparation and optoelectronic characteristics of Cu2O-based solar cells with nanostructure10.1016/j.mssp.2012.12.028 ↗
4. Facile preparation and size-dependent photocatalytic activity of Cu2O nanocrystals modified titania for hydrogen evolution10.1016/j.ijhydene.2012.10.064 ↗
5. Degradation of some typical pharmaceuticals and personal care products with copper-plating iron doped Cu2O under visible light irradiation10.1016/S1001-0742(11)60847-4 ↗
6. Preparation of ZnO/Cu2O compound photocatalyst and application in treating organic dyes10.1016/j.jhazmat.2009.11.106 ↗
7. Preparation and characterization of Cu2O–ZnO immobilized on diatomite for photocatalytic treatment of red water produced from manufacturing of TNT10.1016/j.cej.2011.03.048 ↗
8. Cuprous oxide created on sepiolite: preparation, characterization, and photocatalytic activity in treatment of red water from 2,4,6-trinitrotoluene manufacturing10.1016/j.jhazmat.2011.12.053 ↗
9. Mesoporous Cu2O submicro-spheres, facile synthesis and the selective adsorption properties10.1016/j.cej.2012.01.064 ↗
10. Morphology evolutions and optical properties of Cu2O films by an electrochemical deposition on flexible substrate10.1016/j.apsusc.2011.11.070 ↗
11. Stress-induced growth of well-aligned Cu2O nanowire arrays and their photovoltaic effect10.1016/j.scriptamat.2011.09.041 ↗
12. Time-dependent hydrothermal synthesis and self-evolution mechanism of Cu2O microcrystals10.1016/j.matchar.2012.06.007 ↗
13. Effects of supporting electrolyte on galvanic deposition of Cu2O crystals10.1016/j.electacta.2011.05.051 ↗
14. Electrodeposition of mesoporous bilayers of polyaniline supported Cu2O semiconductor films from lyotropic liquid crystalline phase10.1016/j.ces.2012.06.029 ↗
15. Preparationtion and formation mechanism of smooth and uniform Cu2O thin films by electrodeposition method10.1016/j.surfcoat.2012.11.051 ↗
16. Structural properties of RF-magnetron sputtered Cu2O thin films10.1016/j.tsf.2011.07.066 ↗
17. Electrodeposited cuprous oxide on indium tin oxide for solar applications10.1016/S0927-0248(01)00112-X ↗
18. Morphology-controlled electrodeposition of Cu2O microcrystalline particle films for application in photocatalysis under sunlight10.1016/j.materresbull.2012.08.067 ↗
19. Electrochemical synthesis of hierarchical Cu2O stars with enhanced photoelectrochemical properties10.1016/j.electacta.2011.10.106 ↗
20. Shape controlled synthesis and characterization of Cu2O nanostructures assisted by composite surfactants system10.1016/j.matchemphys.2011.04.042 ↗
21. Application of response surface methodology (RSM) for optimisation of COD NH3-N and 2,4-DCP removal from recycled paper wastewater in a pilot-scalegranular activated carbon sequencing batch biofilm reactor (GAC-SBBR)10.1016/j.jenvman.2013.02.016 ↗
22. Optimization of the coagulation-flocculation process for pulp mill wastewater treatment using a combination of uniform design and response surface methodology10.1016/j.watres.2011.08.023 ↗
23. Surface modified bacterial biosorbent with poly(allylamine hydrochloride): development using response surface methodology and use for recovery of hexachloroplatinate(IV) from aqueous solution10.1016/j.watres.2010.07.034 ↗
24. Process modeling and analysis of palm oil mill effluent treatment in an up-flow anaerobic sludge fixed film bioreactor using response surface methodology (RSM)10.1016/j.watres.2006.07.005 ↗
25. Response surface methodology (RSM) analysis of photoinduced decoloration of toludine blue10.1016/j.cej.2007.03.007 ↗
26. Synergy effect over electrodeposited submicron Cu2O films in photocatalytic degradation of methylene blue10.1016/j.apsusc.2012.01.122 ↗
27. Shape evolution and size-controllable synthesis of Cu2O octahedra and their morphology-dependent photocatalytic properties10.1021/jp061934y ↗
28. Shape evolution of Cu2O nanostructures via kinetic and thermodynamic controlled growth10.1021/jp061835k ↗
29. Relationships between photoluminescence performance and photocatalytic activity of ZnO and TiO2 nanoparticles
30. Electrochemical treatment of simulated textile wastewater with industrial components and Levafix Blue CA reactive dye: optimization through response surface methodology10.1016/j.jhazmat.2007.06.010 ↗
31. Modelling, analysis and optimization of adsorption parameters for H3PO4 activated rubber wood sawdust using response surface methodology (RSM)10.1016/j.colsurfb.2008.12.007 ↗