Decomposition of water by a CaTiO3 photocatalyst under UV light irradiation

Abstract Platinized CaTiO3 powder (band gap 3.5 eV) had a high photocatalytic activity of decomposing water into H2 and O2 under the irradiation of UV light, especially with photon energies above 3.8 eV. The existence of this photocatalytic activity is further supported on electrochemical grounds in that the photoinduced current spectrum measured between a CaTiO3 single crystal and a Pt electrode without applied voltage in water showed a maximum near 4.1 eV. This result indicates that the direct measurement of the spectrum corresponding to the efficiency of water decomposition is an effective method to survey photocatalytic activities of materials.