Redox active cobalt based bi-linker metal organic frameworks derived from 5-sulfoisopthalic acid and 4,4-bipyridine for supercapacitor
Source abstract
Abstract
In this research study, we have synthesized, characterized and extensively compared the electrochemical characteristics of two materials derived from 5-sulphoisophtalic acid, 4,4-bipyridine and cobalt metal using sonochemical method. Cobalt-bipyridine complex with 5-SIP in lattice structure (RG-41) showed predominant capacitive behavior whereas Co-SIP-Bpy MOF (RG-42) exhibited significant pseudocapacitive attributes due to the presence of coordination linkage responsible for the electron transfer. Due to the effective electrochemical properties of RG-42, we implemented it practically by fabricating a hybrid device with outstanding electrochemical features, demonstrating impressive 92 % cyclic stability with energy density and power density of 51.41 Wh/kg and 800 W/kg at 1 A/g, respectively. Dunn's method was employed to obtain capacitive-diffusive contributions for both half-electrochemical cells as well as hybrid device. These results underscored the potential of RG-42 as a competitive electrode material for future energy storage applications.
Source: openaire · Quality: candidate unverified · Source record ↗
Research context
OpenAlex topics: Metal-Organic Frameworks: Synthesis and Applications · Supercapacitor Materials and Fabrication · Chemical Synthesis and Reactions
SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.
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