journal article·2024-02Open access

Enhancing performance of lithium-sulfur batteries through porous carbon network integration in carbonized cotton

Pin-Yu Chen, Chuan-Sheng Cho, Chia-Chen Li

Abstract

A novel material, C porous @CC, has been developed by incorporating a porous conductive network into carbonized cotton (CC). This modification significantly enhances the surface area of the material, increasing it from 29.1 to 163.0 m 2 g −1 . The introduction of the porous network significantly enhances the connection between carbon fibers, resulting in a substantial improvement in electronic conduction, up to 2–3 times greater than bare CC. To evaluate its potential, C porous @CC was utilized as a conductive host for the cathode-active material in lithium-sulfur batteries. The battery utilizing C porous @CC as the cathode host demonstrated a higher initial capacity of 1200 mAh g −1 at 0.2C and exhibited superior rate capability across the range of 0.1C to 1.0C, outperforming the CC-based battery. The factors contributing to the enhanced electrochemical performance of the C porous @CC cell were further elucidated through the utilization of the galvanostatic intermittent titration technique.
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Research context

OpenAlex topics: Advanced Battery Materials and Technologies · Advancements in Battery Materials · Advanced battery technologies research

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References (35)

Show source-provided references
1. Challenges and prospects of lithium–sulfur batteries10.1021/ar300179v ↗
2. Cathode materials for lithium–sulfur batteries: a practical perspective10.1039/C7TA00799J ↗
3. Advances in Li–S batteries10.1039/b925751a ↗
4. Advances in lithium–sulfur batteries: from academic research to commercial viability
5. Recent progress in developing Li2S cathodes for Li–S batteries10.1016/j.ensm.2020.02.010 ↗
6. Construction of an additional hierarchical porous framework in carbon fabric for applications in energy storage10.1021/acs.chemmater.2c00447 ↗
7. Recent advances and applications toward emerging lithium–sulfur batteries: working principles and opportunities10.1002/eem2.12257 ↗
8. Strategies toward high-loading lithium–sulfur battery10.1002/aenm.202000082 ↗
9. Review on recent progress of nanostructured anode materials for Li-ion batteries10.1016/j.jpowsour.2013.11.103 ↗
10. Rational construction of Fe2N@C yolk–shell nanoboxes as multifunctional hosts for ultralong lithium–sulfur batteries10.1021/acsnano.9b06629 ↗
11. Monodispersed FeS2electrocatalyst anchored to nitrogen-doped carbon host for lithium-sulfur batteries10.1002/adfm.202205471 ↗
12. Crystal facet engineering of MXene-derived TiN nanoflakes as efficient bidirectional electrocatalyst for advanced lithium-sulfur batteries10.1002/smll.202202917 ↗
13. Facile synthesis of hierarchical sulfur composites for lithium–sulfur batteries10.1002/celc.201900399 ↗
14. Highly symmetric gigaporous carbon microsphere as conductive host for sulfur to achieve high areal capacity for lithium–sulfur batteries10.1016/j.jpowsour.2020.227818 ↗
15. Recent advances and strategies toward polysulfides shuttle inhibition for high-performance Li–S batteries10.1002/advs.202106004 ↗
16. A nitrogen-doped carbon matrix aiming at inhibiting polysulfide shuttling for lithium–sulfur batteries10.1021/acs.energyfuels.0c01909 ↗
17. Recent progress for concurrent realization of shuttle-inhibition and dendrite-free lithium-sulfur batteries10.1002/adma.202212116 ↗
18. An artificial protective coating toward dendrite-free lithium-metal anodes for lithium–sulfur batteries10.1002/ente.202000348 ↗
19. The dual functions of defect-rich carbon nanotubes as both conductive matrix and efficient mediator for Li–S batteries10.1002/smll.202103535 ↗
20. Nano-carbon-fiber-penetrated sulfur crystals as potential cathode active material for high-performance lithium–sulfur batteries10.1016/j.carbon.2019.12.055 ↗
21. Graphene-based materials for flexible lithium–sulfur batteries10.1021/acsnano.1c03183 ↗
22. Two-dimensional materials for advanced Li–S batteries10.1016/j.ensm.2019.02.001 ↗
23. Carbon cage encapsulating nano-cluster Li2S by ionic liquid polymerization and pyrolysis for high performance Li–S batteries10.1016/j.nanoen.2015.02.021 ↗
24. Three-dimensionally ordered, ultrathin graphitic-carbon frameworks with cage-like mesoporosity for highly stable Li–S batteries10.1007/s12274-017-1454-1 ↗
25. A review of the application of carbon materials for lithium metal batteries10.3390/batteries8110246 ↗
26. Porous hollow carbon@ sulfur composites for high-power lithium–sulfur batteries10.1002/ange.201100637 ↗
27. Porous carbon hosts for lithium–sulfur batteries10.1002/chem.201803153 ↗
28. Status and perspectives of hierarchical porous carbon materials in terms of high-performance lithium–sulfur batteries10.1002/cey2.185 ↗
29. Sulfur-infiltrated porous carbon microspheres with controllable multi-modal pore size distribution for high energy lithium–sulfur batteries10.1039/C3NR04532C ↗
30. Multifunctional mesoporous carbonaceous materials enable the high performance of lithium–sulfur batteries10.1021/acs.langmuir.2c03446 ↗
31. A carbon-cotton cathode with ultrahigh-loading capability for statically and dynamically stable lithium–sulfur batteries10.1021/acsnano.6b06369 ↗
32. Cotton cloth templated in situ encapsulation of sulfur into carbon fibers for lithium–sulfur batteries10.1039/D0CC06643E ↗
33. Towards flexible lithium-sulfur battery from natural cotton textile10.1016/j.electacta.2017.06.069 ↗
34. Least squares galvanostatic intermittent titration technique (LS-GITT) for accurate solid phase diffusivity measurement10.1149/2.084310jes ↗
35. Regulating Li2S deposition by Ostwald ripening in lithium–sulfur batteries10.1021/acsami.1c22025 ↗