journal article·2024-01

Biowaste valorization into valuable nanomaterials: Synthesis of green carbon nanodots and anode material for lithium-ion batteries from watermelon seeds

Humza Ashraf, B. Deniz Karahan

Publisher page

Abstract

In this study, a solid biowaste watermelon seed is introduced for the first time as an alternative precursor for the production of fluorescent carbon nanodots and nanostructured activated carbon. Firstly, the seeds are carburized and then activated by using KOH after the ball milling process. The activated carbon is used as anode material in lithium-ion batteries and exhibits ∼360 mAh g − 1 capacity after the 200th cycle, with a coulombic efficiency of 98%. Additionally, carbon dots are fabricated by hydrothermally treating carburized seeds at different conditions. The obtained carbon dots show a remarkable fluorescence effect at 458 nm (when excited at 365 nm) and have the potential to be used in biomedical applications. The results show that by means of proper material selection and process design, low carbon footprint nanomaterials suitable for use in various applications can be synthesized successfully from organic wastes.
Source: openaire · Quality: candidate unverified · Source record ↗

Research context

OpenAlex topics: Carbon and Quantum Dots Applications · Quantum Dots Synthesis And Properties · Graphene and Nanomaterials Applications

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

References (93)

Show source-provided references
1. Multifaceted applications of green carbon dots synthesized from renewable sources10.1016/j.cis.2019.102046 ↗
2. Electrophoretic analysis and purification of fluorescent single-walled carbon nanotube fragments10.1021/ja040082h ↗
3. Quantum-sized carbon dots for bright and colorful photoluminescence10.1021/ja062677d ↗
4. Carbon nanodots in electrochemical sensors and biosensors: a review10.1002/celc.202001229 ↗
5. Carbon Quantum Dots: synthesis, Characterization and Biomedical Applications10.4274/tjps.63497 ↗
6. The potential of nanoparticles in stem cell differentiation and further therapeutic applications
7. Biologically synthesized silver nanoparticles induce neuronal differentiation of SH-SY5Y cells via modulation of reactive oxygen species, phosphatases, and kinase signaling pathways
8. Carbon nanodots featuring efficient fret for real-time monitoring of drug delivery and two-photon imaging10.1002/adma.201303124 ↗
9. Carbon nanodots@zeolitic imidazolate framework-8 nanoparticles for simultaneous pH-responsive drug delivery and fluorescence imaging10.1039/c3ce42506a ↗
10. Facile incorporation of dispersed fluorescent carbon nanodots into mesoporous silica nanosphere for pH-triggered drug delivery and imaging10.1016/j.carbon.2016.07.009 ↗
11. pH-responsive and targeted delivery of curcumin via phenylboronic acid-functionalized ZnO nanoparticles for breast cancer therapy10.1016/j.jare.2019.02.036 ↗
12. One-pot hydrothermal synthesis of highly luminescent nitrogen-doped amphoteric carbon dots for bioimaging from Bombyx mori silk – natural proteins10.1039/c3tb20418a ↗
13. Mg/N double doping strategy to fabricate extremely high luminescent carbon dots for bioimaging10.1039/C3RA43826K ↗
14. Multifunctional carbon dots with high quantum yield for imaging and gene delivery10.1016/j.carbon.2013.10.023 ↗
15. A carbon-based nanocarrier for efficient gene delivery10.4155/tde-2020-0135 ↗
16. Multi-functionalized carbon dots as theranostic nanoagent for gene delivery in lung cancer therapy10.1038/srep21170 ↗
17. White light emitting lanthanide based carbon quantum dots as toxic Cr (VI) and pH sensor10.1016/j.jcis.2019.06.009 ↗
18. Carbon dots production via pyrolysis of sago waste as potential probe for metal ions sensing10.1016/j.jaap.2013.11.001 ↗
19. Photocatalytic H2 evolution on CdS nanoparticles by loading FeSe nanorods as co-catalyst under visible light irradiation10.1016/j.jallcom.2018.09.145 ↗
20. Chemically doped fluorescent carbon and graphene quantum dots for bioimaging, sensor, catalytic and photoelectronic applications10.1039/C5NR07579C ↗
21. Carbon quantum dots: synthesis, properties and applications10.1039/C4TC00988F ↗
22. Bottom-up synthesis of carbon nanoparticles with higher doxorubicin efficacy10.1016/j.jconrel.2017.01.022 ↗
23. Turning date palm fronds into biocompatible mesoporous fluorescent carbon dots10.1038/s41598-018-34349-z ↗
24. Green synthesis of carbon dots with down- and up-conversion fluorescent properties for sensitive detection of hypochlorite with a dual-readout assay10.1039/c3an01003a ↗
25. Facile synthesis of fluorescent carbon dots using watermelon peel as a carbon source10.1016/j.matlet.2011.08.081 ↗
26. Microwave-assisted synthesis of carbon nanodots through an eggshell membrane and their fluorescent application10.1039/c2an36059d ↗
27. Synchronous and rapid preparation of lignin nanoparticles and carbon quantum dots from natural lignocellulose10.1039/C8GC00744F ↗
28. Microwave-assisted and one-step synthesis of PEG passivated fluorescent carbon dots from gelatin as an efficient nanocarrier for methotrexate delivery10.1080/21691401.2018.1562460 ↗
29. Easy synthesis of highly fluorescent carbon dots from albumin and their photoluminescent mechanism and biological imaging applications10.1016/j.msec.2015.09.066 ↗
30. Green synthesis of highly luminescent carbon quantum dots from lemon juice10.1155/2019/2852816 ↗
31. Synthesis of carbon dots from pear juice for fluorescence detection of Cu2+ Ion in Water10.1166/jnn.2018.15356 ↗
32. Green synthesis of ZnO nanoparticles using Solanum nigrum leaf extract and their antibacterial activity10.1016/j.saa.2014.09.105 ↗
33. Photoluminescence of carbon dots and their applications in Hela cell imaging and Fe3+ ion detection10.1007/s10853-017-1178-3 ↗
34. Green preparation of carbon dots with papaya as carbon source for effective fluorescent sensing of Iron (III) and Escherichia coli10.1016/j.bios.2016.04.089 ↗
35. Liu · 2017 · 21 · 61
36. Blue photoluminescent carbon nanodots from limeade10.1016/j.msec.2016.07.075 ↗
37. Simple one-step synthesis of highly luminescent carbon dots from orange juice: application as excellent bio-imaging agents10.1039/c2cc33796g ↗
38. Formation of N, S-codoped fluorescent carbon dots from biomass and their application for the selective detection of mercury and iron ion10.1016/j.saa.2016.10.039 ↗
39. Ricci-Jürgensen · 2020
40. Selective FRET-based sensing of 4-nitrophenol and cell imaging capitalizing on the fluorescent properties of carbon nanodots from apple seeds10.1016/j.snb.2017.11.182 ↗
41. Green preparation of fluorescent carbon dots from lychee seeds and their application for the selective detection of methylene blue and imaging in living cells10.1039/C5TB01073J ↗
42. Fluorescence sensing of cu2+ ion and imaging of fungal cell by ultra-small fluorescent carbon dots derived from acacia concinna seeds10.1016/j.snb.2018.08.149 ↗
43. Synthesis and characterization of mono-disperse carbon quantum dots from fennel seeds: photoluminescence analysis using machine learning10.1038/s41598-019-50397-5 ↗
44. Biogenic approach for fabricating biocompatible carbon dots and their application in colorimetric and fluorometric sensing of lead ion10.1016/j.jclepro.2020.123639 ↗
45. Highly photoluminescent carbon dots derived from linseed and their applications in cellular imaging and sensing10.1039/C8TB00116B ↗
46. Dual sensing of tetracycline and l-Lysine using green synthesized carbon dots from Nigella sativa seeds10.1016/j.dyepig.2020.108640 ↗
47. Nitrogen doped carbon dots derived from natural seeds and their application for electrochemical sensing10.1149/2.0501902jes ↗
48. Label-free carbon dots from black sesame seeds for real-time detection of ammonia vapor via optical electronic nose and density functional theory calculation10.1016/j.colsurfa.2019.04.087 ↗
49. Novel turn-on fluorescent detection of alkaline phosphatase based on green synthesized carbon dots and MnO2 nanosheets10.1016/j.talanta.2016.11.051 ↗
50. Facile and green synthesis of highly fluorescent nitrogen-doped carbon dots from jackfruit seeds and its applications towards the fluorimetric detection of Au3+ ions in aqueous medium and in in vitro multicolor cell imaging10.1039/C9NJ02590A ↗
51. Nutrient composition and physical properties of citron watermelon (Citrullus lanatus var. citroides (L.H. Bailey) Mansf. ex Greb.) seeds are related to seed coat visual appearance10.1016/j.sajb.2022.02.015 ↗
52. Sisal-derived activated carbons for cost-effective lithium–sulfur batteries10.1039/C5RA25850B ↗
53. General and green Strategy toward high performance positive electrode materials for rechargeable Li Ion batteries with crop stalks as the host carbon matrixes10.1021/acssuschemeng.5b00350 ↗
54. Hierarchically porous structured carbon derived from peanut shell as an enhanced high rate anode for lithium ion batteries10.1016/j.apsusc.2019.06.142 ↗
55. Hierarchical porous carbon derived from rice straw for lithium ion batteries with high-rate performance10.1016/j.elecom.2008.10.041 ↗
56. Effect of pyrolysis temperature on carbon obtained from green tea biomass for superior lithium ion battery anodes10.1016/j.cej.2014.06.021 ↗
57. Pyrolytic carbon derived from coffee shells as anode materials for lithium batteries10.1016/j.jpcs.2006.10.007 ↗
58. High-capacity activated carbon anode material for lithium-ion batteries prepared from rice husk by a facile method10.1016/j.diamond.2018.04.019 ↗
59. Loofah-derived carbon as an anode material for potassium ion and lithium ion batteries10.1016/j.electacta.2019.03.165 ↗
60. Alternative lithium-ion battery using biomass-derived carbons as environmentally sustainable anode10.1016/j.jcis.2020.03.092 ↗
61. Potato derived biomass porous carbon as anode for potassium ion batteries10.1016/j.electacta.2018.10.036 ↗
62. Biomorphic carbon derived from corn husk as a promising anode materials for potassium ion battery10.1016/j.electacta.2019.134902 ↗
63. Highly disordered hard carbon derived from skimmed cotton as a high-performance anode material for potassium-ion batteries10.1016/j.jpowsour.2018.06.073 ↗
64. Structural and interface design of hierarchical porous carbon derived from soybeans as anode materials for potassium-ion batteries10.1016/j.jpowsour.2020.228172 ↗
65. High performance potassium-ion battery anode based on biomorphic N-doped carbon derived from walnut septum10.1016/j.jpowsour.2019.01.073 ↗
66. Spontaneous formation of interwoven porous channels in hard-wood-based hard-carbon for high-performance anodes in Potassium-Ion Batteries10.1149/2.1251709jes ↗
67. Superior potassium storage in chitin-derived natural nitrogen-doped carbon nanofibers10.1016/j.carbon.2017.11.064 ↗
68. Insights into pseudographite-structured hard carbon with stabilized performance for high energy K-ion storage10.1016/j.jpowsour.2019.227310 ↗
69. Formation of graphene quantum dots by ball-milling technique using carbon nanocapsules and sodium carbonate
70. Fluorescence turn-off sensing of TNT by polyethylenimine capped carbon quantum dots10.1016/j.saa.2022.120884 ↗
71. Activated Amorphous Carbon with high-porosity derived from camellia pollen grains as anode materials for Lithium/Sodium Ion batteries10.3389/fchem.2018.00366 ↗
72. J.C. Burns, J.L. Krause and D.B. Le, "Introducing symmetric li-ion cells as a tool to study cell degradation mechanisms," vol. 158, no. 12, 2011.10.1149/2.084112jes ↗
73. Hydrothermal carbonization of biomass: a summary and discussion of chemical mechanisms for process engineering10.1002/bbb.198 ↗
74. Effect of water-sludge ratio and reaction time on the hydrothermal carbonization of olive oil mill wastewater treatment: hydrochar characterization10.1016/j.jwpe.2019.100813 ↗
75. Investigating the effect of reaction time on carbon dot formation, structure, and optical properties10.1021/acsomega.9b01798 ↗
76. Egg yolk-derived carbon: achieving excellent fluorescent carbon dots and high performance lithium-ion batteries10.1016/j.jallcom.2018.02.293 ↗
77. A continuously tunable full-color emission nitrogen-doped carbon dots and for ultrasensitive and highly selective detection of ascorbic acid10.3390/nano12040693 ↗
78. Green synthesis of carbon quantum dots from lemon peel waste: applications in sensing and photocatalysis
79. Carbon dots with continuously tunable full-color emission and their application in ratiometric pH sensing10.1021/cm5003669 ↗
80. Ultrafast synthesis of carbon quantum dots from fenugreek seeds using microwave plasma enhanced decomposition: application of C-QDs to grow fluorescent protein crystals10.1038/s41598-020-69264-9 ↗
81. Mesoporous activated carbon from corn stalk core for lithium ion batteries10.1016/j.chemphys.2018.03.027 ↗
82. Nanospace engineering of KOH activated carbon10.1088/0957-4484/23/1/015401 ↗
83. KOH activation of carbon-based materials for energy storage10.1039/c2jm34066f ↗
84. Expanded graphite as superior anode for sodium-ion batteries10.1038/ncomms5033 ↗
85. Oxygen vacancies enhance pseudocapacitive charge storage properties of MoO3−x10.1038/nmat4810 ↗
86. Controllable Interlayer Spacing of Sulfur-Doped Graphitic Carbon Nanosheets for Fast Sodium-Ion Batteries10.1002/smll.201700762 ↗
87. Expanded biomass-derived hard carbon with ultra-stable performance in sodium-ion batteries10.1039/C7TA07951F ↗
88. Preparation of Activated Carbon from Pyrolyzed Rice Husk by Leaching out Ash Content after CO2 Activation10.15376/biores.11.2.3384-3396 ↗
89. Solid waste-derived carbon as anode for high performance lithium-ion batteries10.1016/j.diamond.2019.107517 ↗
90. Hierarchically porous nitrogen-rich carbon derived from wheat straw as an ultra-high-rate anode for lithium ion batteries10.1039/C4TA00501E ↗
91. Recent advances in hard carbon anodes with high initial Coulombic efficiency for sodium-ion batteries
92. Anode materials for lithium-ion batteries: a review10.1016/j.apsadv.2022.100233 ↗
93. Facile preparation of 3D hierarchical porous carbon from lignin for the anode material in lithium ion battery with high rate performance10.1016/j.electacta.2015.08.001 ↗