journal article·2017-03

Preparation and photoluminescence characteristics of Li 2 Mg 3 SnO 6 :Mn 4+ deep red phosphor

Renping Cao, Jinlong Zhang, Wudi Wang, Zuofu Hu, Ting Chen, Yuanxiu Ye, Xiaoguang Yu

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Abstract

Abstract Li2Mg3SnO6:Mn4+ deep red phosphor is synthesized by high-temperature solid-state reaction method in air. With excitation 330 and 480 nm, the emission band peaking at ∼670 nm within the range 600–790 nm is observed owing to the 2E → 4A2 transition of Mn4+ ion. Excitation bands peaking at ∼330, 395, and 480 nm in the range of 220–600 nm indicate that Li2Mg3SnO6:Mn4+ phosphor can be effectively excited by (near) ultraviolet and blue light-emitting diode chips. The optimal Mn4+ ion concentration is ∼0.4 mol%. Fluorescence lifetime and quantum efficiency of Li2Mg3SnO6:0.4%Mn4+ phosphor with excitation 330 nm are ∼266.67 μs and 36.3%, respectively. The luminous mechanism is explained by the Tanabe-Sugano energy level diagram of Mn4+ in the octahedron.
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Research context

OpenAlex topics: Luminescence Properties of Advanced Materials · Advanced Photocatalysis Techniques · Microwave Dielectric Ceramics Synthesis

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

References (44)

Show source-provided references
1. Red emitting phosphors of Eu3+ doped Na2Ln2Ti3O10 (Ln=Gd, Y) for white light emitting diodes10.1016/j.jallcom.2015.02.014 ↗
2. Red phosphor Ca2Ge7O16:Eu3+ for potential application in field emission displays and white light-emitting diodes10.1016/j.materresbull.2014.09.091 ↗
3. Synthesis of Eu3+-activated BaMoO4 phosphors and their Judd–Ofelt analysis: applications in lasers and white LEDs10.1016/j.saa.2015.06.045 ↗
4. White luminescence and energy transfer process in Bi3+, Sm3+ co-doped Ca3Al2O6 phosphors10.1016/j.optmat.2014.12.037 ↗
5. Synthesis and luminescence properties of blue-emitting phosphor K2Ca2Si2O7:Ce3+10.1016/j.optmat.2013.11.010 ↗
6. Site-dependent luminescence and thermal stability of Eu2+ doped fluorophosphate toward white LEDs for plant growth10.1021/acsami.6b06102 ↗
7. K2Ln(PO4)(WO4):Tb3+, Eu3+ (Ln=Y, Gd and Lu) phosphors: highly efficient pure red and tunable emission for white light-emitting diodes10.1039/C4TC02406K ↗
8. Rare-earth free self-activated and rare-earth activated Ca2NaZn2V3O12 vanadate phosphors and their color-tunable luminescence properties10.1016/j.jpcs.2013.05.002 ↗
9. Structure, photoluminescence and thermoluminescence study of a composite ZnTa2O6/ZnGa2O4 compound doped with Pr3+10.1016/j.optmat.2016.03.029 ↗
10. Synthesis and photoluminescence properties of novel BiBa2V3O11: A (A=Sm3+ Eu3+) phosphors10.1016/j.optmat.2015.09.030 ↗
11. Rare-earth activated nitride phosphors: synthesis, luminescence and applications10.3390/ma3063777 ↗
12. Narrow-band red-emitting Sr(LiAl3N4):Eu2+ as a next-generation LED-phosphor material10.1038/nmat4012 ↗
13. Synthesis and luminescence properties of novel red-emitting R3P4O13:Bi2+ (R=Sr and Ba) phosphors10.1016/j.jallcom.2015.11.176 ↗
14. Blasse · 1994
15. Chen · 2010
16. Some new aspects of germanate and fluoride phosphors10.1364/JOSA.37.000302 ↗
17. Activator center in magnesium fluorogermanate phosphors10.1063/1.1731262 ↗
18. High efficiency Mn4+ doped Sr2MgAl22O36 red emitting phosphor for white LED10.1149/2.022204jss ↗
19. Orderly-layered tetravalent manganese-doped strontium aluminate Sr4Al14O25:Mn4+: an efficient red phosphor for warm white light-emitting diodes10.1111/jace.12391 ↗
20. Manganese activated luminescence in SrAl12O19 and CaAl12O1910.1149/1.2408274 ↗
21. Synthesis and luminescence properties of CaAl2O4:Mn4+ phosphor10.1016/j.optmat.2014.10.002 ↗
22. Optimized photoluminescence of red phosphor K2TiF6:Mn4+ synthesized at room temperature and its formation mechanism10.1039/C4TC02097A ↗
23. Synthesis of narrow-band red-emitting K2SiF6:Mn4+ phosphors for a deep red monochromatic LED and ultrahigh color quality warm-white LEDs10.1039/C4TC02042A ↗
24. Novel deep red emitting phosphors Ca14Zn6M10O35:Mn4+ (M=Al3+ and Ga3+)10.1246/cl.140227 ↗
25. Comparative analysis of crystal field effects and optical spectroscopy of six-coordinated Mn4+ ion in the Y2Ti2O7 and Y2Sn2O7 pyrochlores10.1016/j.optmat.2011.05.008 ↗
26. The role of tin in Li/Sn/MgO catalysts for the oxidative coupling of methane10.1039/c39920001546 ↗
27. Chaban · Russ. J. Inorg. Chem. (Engl. Transl.) · 1985 · 30 · 1663
28. Revised effective ionic radii and systematic studies of interatomic distances in halides and chalcogenides10.1107/S0567739476001551 ↗
29. Enhancement of the luminescence efficiency of Li2TiO3:Mn4+ red emitting phosphor for white LEDs
30. Synthesis and luminescence properties of novel red phosphors LiRGe2O6:Mn4+ (R=Al or Ga)10.1016/j.jallcom.2015.07.080 ↗
31. Ab initio and crystal field studies of the Mn4+-doped Ba2LaNbO6 double-perovskite10.1016/j.jlumin.2011.09.017 ↗
32. Spectroscopic and crystal field analysis of absorption and photoluminescence properties of red phosphor CaAl12O19:Mn4+ modified by MgO10.1016/j.jallcom.2010.11.117 ↗
33. Chemical trends of Mn4+ emission in solids10.1039/C4TC00031E ↗
34. LiGaTiO4:Mn4+ red phosphor: synthesis, luminescence properties and emission enhancement by Mg2+ and Al3+ ions10.1016/j.ceramint.2016.05.138 ↗
35. Liu · 2005
36. Temperature-dependent photoluminescence properties of deep-red emitting Mn4+-activated magnesium fluorogermanate phosphors10.1016/j.jallcom.2012.11.078 ↗
37. Mn4+–activated red photoluminescence in K2SiF6 phosphor10.1149/1.2993159 ↗
38. Mn4+ doped (NH4)2TiF6 and (NH4)2SiF6 micro-crystal phosphors: synthesis through ion exchange at room temperature and their photoluminescence properties10.1039/C6RA16417J ↗
39. Properties of Mn4+–activated hexafluorotitanate phosphors10.1149/1.3530793 ↗
40. A deep red phosphor Li2MgTiO4:Mn4+ exhibiting abnormal emission: potential application as color converter for warm w-LEDs10.1016/j.cej.2016.06.056 ↗
41. Influence of covalency on the Mn4+2Eg→4A2g emission energy in crystals10.1149/2.0031503jss ↗
42. Highly efficient non-rare-earth red emitting phosphor for warm white light-emitting diodes10.1038/ncomms5312 ↗
43. Luminescence of Mn4+ in the distorted perovskite Gd2MgTiO610.1149/1.1837087 ↗
44. Crystal field studies of the Mn4+ energy levels in the perovskite LaAlO310.1016/j.optmat.2013.03.021 ↗