Luminescence and temperature sensing abilities of zincate phosphors co-doped bismuth Bi3+ and lanthanide Eu3+/Sm3+
Source abstract
Abstract
Abstract We proposed the FIR method-based optical materials involving dual luminescent centers of Bi3+ and lanthanide (Ln): Eu3+/Sm3+. Resulted from the f-f characteristic transition of Eu3+, the tunable color region changing from cyan to jacinth with the augment of Eu3+/Bi3+ ratio exists . Owing to Bi3+ being susceptive to crystal surroundings, and asymmetric crystal sites of Sm3+ in the host, phenomena respectively involving redshift and energy level splitting occur. In addition, benefiting from the unshielded 3d orbitals, the thermal quenching of Bi3+ ion occurs through energy-level crossing relaxation (ELCR), while the heating quenching of Ln3+ ions takes place due to the shielded 4f orbitals via multi-phonon deexcitation (MPD). Considering the symmetric crystal environment, stronger sensitivity compared with Sm3+ ion to the outer environment due to its smaller value of thermal activation energy and the weaker crystal field than CAZO:Bi3+,Sm3+, a more excellent temperature sensing sensitivity is excepted by applying Eu3+ as the temperature-detecting signal.
Source: openaire · Quality: candidate unverified · Source record ↗
Research context
OpenAlex topics: Luminescence Properties of Advanced Materials · Perovskite Materials and Applications · Radiation Detection and Scintillator Technologies
SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.
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