Protonic conduction in Ca2+-doped La2M2O7 (M=Ce, Zr) with its application to ammonia synthesis electrochemically

Complex oxides La{sub 1.95}Ca{sub 0.05}M{sub 2}O{sub 7-{delta}} (M = Ce, Zr) were prepared by sol-gel method and characterized by thermal analysis (TG-DTA), X-ray diffraction (XRD). On the sintered complex oxides as solid electrolyte, the conductivity was measured in various atmospheres, and ammonia was synthesized from nitrogen and hydrogen at atmospheric pressure in the solid states proton conducting cell reactor by electrochemical methods. The rates of ammonia formation were up to 2.0 x 10{sup -9} mol s{sup -1} cm{sup -2} for La{sub 1.95}Ca{sub 0.05}Zr{sub 2}O{sub 7-{delta}} and 1.3 x 10{sup -9} mol s{sup -1} cm{sup -2} for La{sub 1.95}Ca{sub 0.05}Ce{sub 2}O{sub 7-{delta}}, respectively, at 520 deg. C.