journal article·2016-05

Magnetically separable core–shell ZnFe2O4@ZnO nanoparticles for visible light photodegradation of methyl orange

Suresh D. Kulkarni, Sagar Kumbar, Samvit G. Menon, K.S. Choudhari, Santhosh C.

Publisher page

Abstract

Abstract Visible light photodegradation of aqueous methyl orange using magnetically separable core–shell ZnFe2O4@ZnO nanoparticles is reported. A combination of low temperature (190 °C) microwave synthesis and hydrothermal method were used to prepare phase pure material with excellent yield (95%). The magnetic separability, surface area of 41 m2/g and visible light absorption make ZnFe2O4@ZnO nanoparticles a good solar photocatalyst. ZnFe2O4@ZnO displayed greater UV photocatalytic efficiency than ZnO owing to the generation of large number of electron-hole pairs. Visible light photodegradation of MO using ZnFe2O4@ZnO nanoparticles is reported for the first time. Higher first order rate constants under both UV and visible light for core-shell nanoparticles suggested their superiority over its individual oxides. The ZnFe2O4@ZnO showed excellent reusability with high photocatalytic efficiencies suggesting its suitability for solar photocatalytic applications.
Source: openaire · Quality: candidate unverified · Source record ↗

Research context

OpenAlex topics: ZnO doping and properties · Advanced Photocatalysis Techniques · Copper-based nanomaterials and applications

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

References (42)

Show source-provided references
1. Solar photocatalytic degradation of azo dye in aqueous suspension assisted by fresnel lens10.1155/2012/303586 ↗
2. Photocatalytic degradation of monoazo and diazo dyes in wastewater on nanometer-sized TiO2
3. A general review on advanced oxidation processes for waste water treatment
4. Effects of solvent diols on the synthesis of ZnFe2O4 particles and their use as heterogeneous photo-Fenton catalysts10.3390/ma7096281 ↗
5. Secondary effluents treatment with ozone
6. Photo catalytic degradation of two commercial dyes in aqueous phase using photo catalyst TiO2
7. Graphene oxide: an efficient and reusable carbocatalyst for aza-Michael addition of amines to activated alkenes10.1039/c1cc15230k ↗
8. Synthesis, structure and photocatalytic activity of nano TiO2 and nano Ti1−xMxO2−δ (M=Cu Fe, Pt, Pd, V, W, Ce, Zr)10.1007/BF03010452 ↗
9. Synthesis, characterization and photocatalytic activities of Ag-N-codoped ZnO nanoparticles for degradation of methyl red
10. Initial studies of photocatalytic discolouration of methyl orange by using ZnO nanostructures
11. A TiO2 immobilized Ru (ii) polyazine complex: a visible-light active photoredox catalyst for oxidative cyanation of tertiary amines10.1039/c3ta14783e ↗
12. Role of particle size in visible light photocatalysis of congo red using TiO2·[ZnFe2O4]x nanocomposites10.1007/s12034-009-0074-0 ↗
13. Synthesis of ZnO nanostructures and their photocatalytic activity
14. Fundamentals of zinc oxide as a semiconductor10.1088/0034-4885/72/12/126501 ↗
15. Size dependency of nanocrystalline TiO2 on its optical property and photocatalytic reactivity exemplified by 2-chlorophenol10.1016/j.apcatb.2006.07.018 ↗
16. Synthesis and properties of (Yb, N)-TiO2 photocatalyst for degradation of methylene blue (MB) under visible light irradiation10.1016/j.materresbull.2015.04.060 ↗
17. Nanosized zinc peroxide (ZnO2): a novel inorganic oxidant for the oxidation of aromatic alcohols to carbonyl compounds10.1039/C3QI00092C ↗
18. Synthesis, optical, and photocatalytic properties of a new visible-light-active ZnFe2O4–TiO2 nanocomposite material10.1007/s11051-012-0937-y ↗
19. BOD5 removal from tannery wastewater over ZnO–ZnFe2O4 composite photocatalyst supported on activated carbon10.5897/JCEMS2013.0165 ↗
20. Enhanced photocatalytic degradation of methylene blue using/MWCNT composite synthesized by hydrothermal method, Indian
21. Preparation and characterization of magnetic core–shell ZnFe2O4@ZnO nanoparticles and their application for the photodegradation of methylene blue10.1016/j.cej.2012.11.109 ↗
22. Preparation and magnetic properties of ZnFe2O4 nanotubes
23. Controlled inversion and surface disorder in zinc ferrite nanocrystallites and their effects on magnetic properties10.1039/C4RA12961J ↗
24. ZnFe2O4: rapid and sub-100C synthesis and anneal-tuned magnetic properties10.1039/C1JM14874E ↗
25. Synthesis of zinc ferrite and its photocatalytic application under visible light10.3938/jkps.54.204 ↗
26. Cation distribution in ZnFe2O4 fine particles studied by neutron powder diffraction10.1016/0038-1098(92)90412-3 ↗
27. Magnetization of sol–gel prepared zinc ferrite nanoparticles: effects of inversion and particle size10.1016/j.ssc.2006.03.023 ↗
28. Chemistry of nanocrystalline oxide materials: combustion synthesis, properties and applications
29. One-pot solvothermal synthesis of ZnFe2O4 nanospheres/graphene composites with improved lithium-storage performance10.1016/j.materresbull.2015.01.057 ↗
30. Microwave-hydrothermal versus conventional hydrothermal preparation of Ni-and Zn-ferrite powders10.1016/S0925-8388(01)01375-5 ↗
31. Microwave-induced polyol-process synthesis of MIIFe2O4 (M=Mn, Co) nanoparticles and magnetic property10.1016/j.matchemphys.2007.09.022 ↗
32. Synthesis of ZnO nanoparticles by hydrothermal method
33. Synthesis and characterization of cupric oxide (CuO) nanoparticles and their application for the removal of dyes10.5897/AJB2013.13058 ↗
34. Infrared and magnetic study of nanophase zinc ferrite
35. Nalwa · 1999
36. Preparation, infrared spectroscopy, and phase stability of nanosized iron silicide powders10.1016/S0025-5408(99)00222-6 ↗
37. Structural, magnetic and electronic structure properties of Co doped ZnO nanoparticles10.1016/j.materresbull.2015.02.020 ↗
38. The impact of nano-milling on porous ZnO prepared from layered zinc hydroxide nitrate and zinc hydroxide carbonate10.1016/j.materresbull.2014.09.061 ↗
39. Preparation of ZnO nanoparticles by solvothermal process
40. Optical absorption red and blue shifts in ZnFe2O4 nanoparticles10.1016/j.mseb.2008.10.032 ↗
41. Nanocrystalline zinc ferrite photocatalysts formed using the colloid mill and hydrothermal technique10.1016/j.cej.2009.08.008 ↗
42. Photocatalytic degradation of an azo dye acid red 27, in aqueous solution using nano ZnO