Silver nanoparticles: Large scale solvothermal synthesis and optical properties

Abstract Silver nanoparticles have been successfully synthesized by a simple and modified solvothermal method at large scale using ethanol as the refluxing solvent and NaBH4 as reducing agent. The nanopowder was investigated by means of X-ray diffraction (XRD), transmission electron microscopy (TEM), dynamic light scattering (DLS), UV–visible and BET surface area studies. XRD studies reveal the monophasic nature of these highly crystalline silver nanoparticles. Transmission electron microscopic studies show the monodisperse and highly uniform nanoparticles of silver of the particle size of 5 nm, however, the size is found to be 7 nm using dynamic light scattering which is in good agreement with the TEM and X-ray line broadening studies. The surface area was found to be 34.5 m2/g. UV–visible studies show the absorption band at ∼425 nm due to surface plasmon resonance. The percentage yield of silver nanoparticles was found to be as high as 98.5%.