journal article·2016-12

Synthesis of tin oxide/graphene (SnO 2 /G) nanocomposite and its electrochemical properties for supercapacitor applications

V. Velmurugan, U. Srinivasarao, R. Ramachandran, M. Saranya, Andrews Nirmala Grace

Publisher page

Abstract

Abstract Tin oxide/graphene (SnO2/G) nanocomposites were prepared by a simple wet chemical route and the as prepared nanocomposites were characterized by X-ray diffraction (XRD), High Resolution Transmission Electron Microscopy (HRTEM) and Fourier transform infrared spectra (FTIR). The characterized results showed the tetragonal structure of SnO2 nanostructures on uniform distribution on graphene sheets with a particle size of ∼50 nm. The reduction of graphene oxide to graphene during SnO2/G synthesis was confirmed from FTIR analysis. HRTEM analysis showed that the individual SnO2 nanoparticles deposited on graphene sheets. The electrochemical performances of SnO2/G nanocomposites towards supercapacitors were studied in 6M KOH electrolyte. A maximum specific capacitance of 818.6 F/g was obtained for SnO2/G-a composite at 5 mV/s scan rate suggesting that the presence of graphene matrix in SnO2 nanoparticles have enhanced the electrochemical behaviour of SnO2. The galvanostatic charge/discharge studies confirmed the good cyclic stability of the composite electrode. These excellent electrochemical properties suggested that the SnO2/G nanocomposites could be used for high energy density supercapacitor electrode materials.
Source: openaire · Quality: candidate unverified · Source record ↗

Research context

OpenAlex topics: Supercapacitor Materials and Fabrication · Graphene and Nanomaterials Applications · Graphene research and applications

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

References (42)

Show source-provided references
1. Graphene and nanostructured MnO2 composite electrodes for supercapacitors10.1016/j.carbon.2011.02.068 ↗
2. High capacity and excellent cycling stability of single-walled carbon nanotube/SnO2 core-shell structures as Li-insertion materials10.1063/1.2937839 ↗
3. All-solid-supercapacitor based on polyaniline and sulfonated polymers10.1016/j.synthmet.2006.06.017 ↗
4. One-pot polyelectrolyte assisted hydrothermal synthesis of RuO2-reduced graphene oxide nanocomposite10.1016/j.electacta.2013.02.034 ↗
5. A reduced graphene oxide/Co3O4 composite for supercapacitor electrode10.1016/j.jpowsour.2012.10.064 ↗
6. Synthesis of NiO nanospheres with ultrasonic method for supercapacitors10.1016/j.mssp.2013.09.002 ↗
7. Rapid microwave-assisted synthesis of graphene nanosheet/Co3O4 composite for supercapacitors10.1016/j.electacta.2010.06.081 ↗
8. Solvothermal synthesis of SnO2/graphene nanocomposites for supercapacitor application10.1016/j.ceramint.2013.01.102 ↗
9. Gas sensing mechanism and properties of Ce-doped SnO2 sensors for volatile organic compounds10.1016/j.mssp.2012.02.015 ↗
10. Synthesis and characterization of co-doped TiO2 thin films on glass-ceramic
11. Gram-scale synthesis of graphene-mesoporous SnO2 composite as anode for lithium-ion batteries10.1016/j.electacta.2014.11.100 ↗
12. Graphene-based materials as supercapacitor electrodes10.1039/c000417k ↗
13. Specific surface area of carbon nanotubes and bundles of carbon nanotubes10.1016/S0008-6223(00)00155-X ↗
14. Graphene-based composite materials10.1038/nature04969 ↗
15. Synergistic effects from graphene and carbon nanotubes enable flexible and robust electrodes for high-performance supercapacitors10.1021/nl301804c ↗
16. One-step synthesis of graphene/SnO2 nanocomposites and its application in electrochemical supercapacitors10.1088/0957-4484/20/45/455602 ↗
17. Microwave-assisted one-pot synthesis of metal/metal oxide nanoparticles on graphene and their electrochemical applications10.1016/j.electacta.2011.01.016 ↗
18. Synthesis of graphene platelets by chemical and electrochemical route10.1016/j.materresbull.2013.05.085 ↗
19. Controlled fabrication of SnO2 arrays of well-aligned nanotubes and nanowires10.1039/c0nr00279h ↗
20. Graphene-metal particle nanocomposites10.1021/jp807989b ↗
21. A template-free facile approach for the synthesis of CuS–rGO nanocomposites towards enhanced photocatalytic reduction of organic contaminants and textile effluents10.1039/C4RA09029B ↗
22. Dispersing carbon nanotubes with graphene oxide in water and synergistic effects between graphene derivatives10.1002/chem.201001771 ↗
23. Temperature dependence of graphene oxide reduced by hydrazine hydrate10.1088/0957-4484/22/5/055705 ↗
24. One-step in situball milling synthesis of polymer-functionalized graphene nanocomposites10.1039/c1jm10819k ↗
25. Mechanical property and structure of covalent functionalised graphene/epoxy nanocomposites
26. Co9S8 nanoflakes on graphene (Co9S8/G) nanocomposites for high performance supercapacitors10.1039/C4RA01515K ↗
27. Hydrothermal synthesis and pseudocapacitance properties of α-MnO2 hollow spheres and hollow urchins10.1021/jp076730b ↗
28. Mesoporous amorphous MnO2 as electrode material for supercapacitor10.1007/s10008-006-0246-4 ↗
29. Fabrication of polypyrrole/graphene oxide nanocomposites by liquid/liquid interfacial polymerization and evaluation of their optical, electrical and electrochemical properties10.1016/j.polymer.2011.12.054 ↗
30. One-pot synthesis of ZnO/reduced graphene oxide nanocomposite for supercapacitor applications10.1016/j.mssp.2014.11.037 ↗
31. Facile synthesis of graphene-wrapped honeycomb MnO2 nanospheres and their application in supercapacitors10.1021/am3000165 ↗
32. Coating single walled carbon nanotube with SnO2 and its electrochemical properties10.1016/j.powtec.2012.03.012 ↗
33. Hollow SnO2 microspheres and their carbon-coated composites for supercapacitors10.1016/j.colsurfa.2013.12.028 ↗
34. Synthesis of polyaniline/SnO2 nanocomposite and its improved electrochemical performance10.1016/j.materresbull.2014.08.022 ↗
35. Preparation of graphene nanosheets/SnO2 composites by pre-reduction followed by in-situ reduction and their electrochemical performances10.1016/j.matchemphys.2013.02.052 ↗
36. Rajendran Ramachandran, Murugan Saranya, Pratap Kollu, Bala PC Raghupathy, Soon Kwan Jeong, Andrews Nirmala Grace, Solvothermal synthesis of Zinc sulfide decorated Graphene (ZnS/G) nanocomposites for novel Supercapacitor electrodes, Electrochimica Acta, 2015,178, 647–657.10.1016/j.electacta.2015.08.010 ↗
37. Facile synthesis of polyaniline/TiO2/graphene oxide composite for high performance supercapacitors10.1016/j.solidstatesciences.2012.03.020 ↗
38. Supercapacitors based on graphene–polyaniline derivative nanocomposite electrode materials10.1016/j.electacta.2013.01.039 ↗
39. Co3S4 hollow nanospheres grown on graphene as advanced electrode materials for supercapacitors10.1039/c2jm34714h ↗
40. High-rate electrochemical capacitors from highly graphitic carbon–tipped manganese oxide/mesoporous carbon/manganese oxide hybrid nanowires10.1039/c1ee01032h ↗
41. Supercapacitor devices based on graphene materials10.1021/jp902214f ↗
42. Synthesis of graphene oxide/polypyrrole nanowire composites for supercapacitors10.1016/j.matlet.2012.03.013 ↗