journal article·2003-05

Opportunity of metallic interconnects for solid oxide fuel cells: a status on contact resistance

W.Z. Zhu, S.C. Deevi

Materials Research Bulletin· Volume 38· Issue 6
Publisher page

Abstract

The status and opportunity of metallic interconnects for an anode-supported solid oxide fuel cell stack is reviewed with special emphasis on the variation of contact resistance of currently developed interconnects at operating temperatures, as well as the prevailing approaches to reduce contact resistance. It appears that without a coating, current metallic interconnects are not suitable for practical applications at 800 °C since they may cause drastic performance degradation of the stack within its expected service lifetime. Some guidelines in designing new metallic interconnects with both excellent oxidation resistance and reasonably low contact resistance in SOFC environments are set forth.
Source: openaire · Quality: candidate unverified · Source record ↗

Research context

OpenAlex topics: Advancements in Solid Oxide Fuel Cells · Electronic and Structural Properties of Oxides · Semiconductor materials and devices

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

References (30)

Show source-provided references
1. H. Kabs, U. Stimming, D. Stovers, Advances in the anode supported planar SOFC technology, in: U. Stimming, S.C. Singhal, H. Tagawa, W. Lehnert (Eds.), Proceedings of the Fifth International Symposium on Solid Oxide Fuel Cells (SOFC V), Aachen, Germany, 2–5 June 1997, pp. 160–170.
2. K. Foger, R. Donelson, R. Ratnaraj, Demonstration of anode supported cell technology in Kw class stack, in: S.C. Singhal, M. Dokiya (Eds.), Proceedings of the Sixth International Symposium on Solid Oxide Fuel Cells (SOFC VI), Honolulu, Hawaii, 17–22 October 1999, pp. 95–100.10.1149/199919.0095PV ↗
3. L.G.J. deHaart, I.C. Vinke, A. Janke, H. Ringel, F. Tietz, New developments in stack technology for anode substrate based SOFC, in: H. Yokokawa, S.C. Singhal (Eds.), Proceedings of the Seventh International Symposium on Solid Oxide Fuel Cells (SOFC VII), Tsukuba, Ibaraki, Japan, 3–8 June 2001, pp. 111–119.10.1149/200116.0111PV ↗
4. I. Yasuda, Y. Baba, T. Ogiwara, H. Yakabe, Y. Matsuzaki, Development of anode-supported SOFC for reduced temperature operation, in: H. Yokokawa, S.C. Singhal (Eds.), Proceedings of the Seventh International Symposium on Solid Oxide Fuel Cells (SOFC VII), Tsukuba, Ibaraki, Japan, 3–8 June 2001, pp. 131–139.10.1149/200116.0131PV ↗
5. Kim · J. Electrochem. Soc. · 1999 · 146 · 6910.1149/1.1391566 ↗
6. W.Z. Zhu, S.C. Deevi, Oxidation behavior of some potential metallic interconnects for solid oxide fuel cell, J. Mater. Sci. (in press).
7. Gonzalez-Carrasco · Intermetallics · 1999 · 7 · 6910.1016/S0966-9795(98)00012-0 ↗
8. P.Y. Hou, K. Huang, W.T. Bakker, Promises and problems with metallic interconnects for reduced temperature solid oxide fuel cells, in: S.C. Singhal, M. Dokiya (Eds.), Proceedings of the Sixth International Symposium on Solid Oxide Fuel Cells (SOFC VI), Honolulu, Hawaii, 17–22 October 1999, pp. 737–748.10.1149/199919.0737PV ↗
9. G.V. Samsonovin, in: Turton, T.I. Turton (Trans.), The Oxide Handbook, Plenum Press, New York, 1973, p. 125.10.1007/978-1-4615-9597-7 ↗
10. Tiffee · Ber. Bunsenges Phys. Chem. · 1990 · 949 · 97810.1002/bbpc.19900940919 ↗
11. W. Glatz, E. Batawi, M. Janousek, W. Kraussler, R. Zach, G. Zobl. A new low cost mass production route for metallic SOFC-interconnectors, in: S.C. Singhal, M. Dokiya (Eds.), Proceedings of the Sixth International Symposium on Solid Oxide Fuel Cells (SOFC VI), Honolulu, Hawaii, 17–22 October 1999, pp. 783–790.10.1149/199919.0783PV ↗
12. W.J. Qudakkers, H. Greiner, W. Kock, Metals and alloys for high temperature SOFC applications, in: U. Bossel (Ed.), Proceedings of the First European Solid Oxide Fuel Cell Forum, vol. 1, 3–7 October 1994, Lucerne, Switzerland, pp. 525–535.
13. P. Kofstad, High temperature oxidation of chromium and chromium-forming alloys, in: B. Thorstensen (Ed.), Proceedings of Second European Solid Oxide Fuel Cell Forum, vol. 2, 6–10 May 1996, Oslo, Norway, pp. 479–490.
14. B.E. Liebert, Electrical characterization of a chromium alloy interconnect materials, in: S.C. Singhal, M. Dokiya (Eds.), Proceedings of the Sixth International Symposium on Solid Oxide Fuel Cells (SOFC VI), Honolulu, Hawaii, 17–22 October 1999, pp. 722–730.10.1149/199919.0722PV ↗
15. Brylewski · Solid State Ionics · 2001 · 143 · 13110.1016/S0167-2738(01)00863-3 ↗
16. Linderoth · J. Mater. Sci. · 1996 · 31 · 507710.1007/BF00355908 ↗
17. Quadakkers · Solid State Ionics · 1996 · 91 · 5510.1016/S0167-2738(96)00425-0 ↗
18. Huang · Solid State Ionics · 2000 · 129 · 23710.1016/S0167-2738(99)00329-X ↗
19. M.D. Vazquez-Navarro, J. McAleese, J.A. Kilner, Candidate interconnect materials: oxidation study of a Ni-based superalloy in pure oxygen at 800 °C, in: S.C. Singhal, M. Dokiya (Eds.), Proceedings of the Sixth International Symposium on Solid Oxide Fuel Cells (SOFC VI), Honolulu, Hawaii, 17–22 October 1999, pp. 749–758.10.1149/199919.0749PV ↗
20. A.V. Virkar, J.W. Kim, Planar solid oxide fuel cell stack with metallic foil interconnect, US Pat. 6106967.
21. England · J. Electrochem. Soc. · 1999 · 146 · 319610.1149/1.1392454 ↗
22. England · J. Electrochem. Soc. · 2001 · 148 · A33010.1149/1.1354611 ↗
23. A.V. Virkar, D.M. England, Solid oxide fuel cell interconnector, US Pat. 6053231.
24. N. Oishi, Y. Yamazaki, The effects of rare earth element coatings on oxidation of alloys in SOFC operating atmospheres, in: S.C. Singhal, M. Dokiya (Eds.), Proceedings of the Sixth International Symposium on Solid Oxide Fuel Cells (SOFC VI), Honolulu, Hawaii, 17–22 October 1999, pp. 759–773.10.1149/199919.0759PV ↗
25. Badwal · Solid State Ionics · 1997 · 99 · 29710.1016/S0167-2738(97)00247-6 ↗
26. Matsuzaki · Solid State Ionics · 2000 · 132 · 27110.1016/S0167-2738(00)00654-8 ↗
27. E. Batawi, A. Plas, W. Straub, K. Honegger, R. Diethelm, New cost-effective ceramic oxide phases used as protective coatings for chromium-based interconnects, in: S.C. Singhal, M. Dokiya (Eds.), Proceedings of the Sixth International Symposium on Solid Oxide Fuel Cells (SOFC VI), Honolulu, Hawaii, 17–22 October 1999, pp. 767–773.10.1149/199919.0767PV ↗
28. E. Batawi, W. Glatz, W. Kraussler, M. Janousek, Oxidation resistance and performance in stack tests of near-net-shaped chromium-based interconnects, in: S.C. Singhal, M. Dokiya (Eds.), Proceedings of the Sixth International Symposium on Solid Oxide Fuel Cells (SOFC VI), Honolulu, Hawaii, 17–22 October 1999, pp. 731–736.10.1149/199919.0731PV ↗
29. K. Honegger, A. Plas, R. Diethelm, W. Glatz, Evaluation of ferritic steel interconnects for SOFC stacks, in: H. Yokokawa, S.C. Singhal (Eds.), Proceedings of the Seventh International Symposium on Solid Oxide Fuel Cells (SOFC VII), Tsukuba, Ibaraki, Japan, 3–8 June 2001, pp. 803–810.10.1149/200116.0803PV ↗
30. Y. Yoo, M. Daugo, The effect of protective layers formed by electrophoretic deposition on oxidation and performance of metallic interconnects, in: H. Yokokawa, S.C. Singhal (Eds.), Proceedings of the Seventh International Symposium on Solid Oxide Fuel Cells (SOFC VII), Tsukuba, Ibaraki, Japan, 3–8 June 2001, pp. 837–846.10.1149/200116.0837PV ↗