New multilayer π-stacked polymers derived from 1,4-Diethynylbenzene: Design, synthesis and property study
Source abstract
Abstract
A series of multilayer polymers (1A–1E) was synthesized by Sonogashira coupling reaction between 1,4-diethynylbenzene and various 1,8-substituted aromatic derivatives. Photophysical and thermal characterizations demonstrated their electronic transitions, aggregation-induced emission (AIE) behaviors, and enhanced thermal stability compared with many conventional polymeric materials. These findings can also suggest that subtle changes in substituent structure affect the UV–Vis, photoluminescence, and thermal properties of the synthesized polymers.
Source: openaire · Quality: candidate unverified · Source record ↗
Research context
OpenAlex topics: Synthesis and properties of polymers · Synthesis and Properties of Aromatic Compounds · Nonlinear Optical Materials Research
SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.
References (17)
Show source-provided references
1. Modeling-driven materials by design for conjugated polymers: insights into optoelectronic, conformational, and thermomechanical properties10.1039/D4CC03217A ↗
2. [2.2] paracyclophane-layered polymers end-capped with fluorescence quenchers10.1021/ma9000644 ↗
3. New blue light emitting cyanopyridine based conjugated polymers: from molecular engineering to PLED applications10.1016/j.jphotochem.2019.04.012 ↗
4. New cyanopyridine based conjugated polymers carrying auxiliary electron donors: from molecular design to blue emissive PLEDs10.1016/j.dyepig.2019.108046 ↗
5. Synthesis of π-stacked polymers on the basis of [2.2] paracyclophane10.1246/bcsj.82.1070 ↗
6. Multilayer 3D chiral folding polymers and their asymmetric catalytic assembly10.34133/2022/9847949 ↗
7. The synthesis and property study of NH-ac-anchored multilayer 3D polymers10.3390/molecules30091981 ↗
8. Synthesis and characterization of multilayer 3D chiral polymers with enhanced optical properties10.3390/molecules30071567 ↗
9. Design, synthesis, and analysis of multi-layered 3D fluorescent polymers derived from anthracene and naphthalene structural units10.1039/D5RA08369A ↗
10. Synthesis and characterization of new aryl-oxycarbonyl methyl methacrylate monomers and their polymers10.1016/S1381-5148(03)00052-X ↗
11. Monomer reactivity ratios of the 2-(3-mesityl-3-methylcyclobutyl)-2-hydroxyethyl methacrylate and styrene system from 1H NMR10.1002/pola.10255 ↗
12. Copolymerization and monomer reactivity ratios of 2-(3-mesityl-3-methylcyclobutyl)-2-hydroxyethyl methacrylate with acrylonitrile10.1016/S0014-3057(99)00039-7 ↗
13. Manipulating p-π resonance through methoxy group engineering in covalent organic frameworks for an efficient photocatalytic hydrogen evolution10.1002/ange.202420217 ↗
14. Theoretical study on the torsional potential of alkyl, donor, and acceptor substituted bithiophene: the hidden role of noncovalent interaction and backbone conjugation10.1039/C4CP05379F ↗
15. Exploring chiral and achiral properties of novel multilayer 3D polymers: synthesis and characterization10.1039/D5RA00233H ↗
16. Efficiency boost in non-doped blue organic light-emitting diodes: harnessing aggregation-induced emission–a comprehensive review10.1039/D3TC03449F ↗
17. Effects of side chain on high temperature operation stability of conjugated polymers10.1021/acsapm.9b00999 ↗