Hydrothermal fabrication of copper sulfide nanocones and nanobelts

Abstract Novel copper sulfide nanocones and nanobelts have been hydrothermally fabricated at 140 °C for 24 h with acrylamide and sodium dodecyl benzene sulfonate (SDBS) as surfactants, respectively. X-ray diffraction (XRD) pattern indicates that the as-prepared samples are the pure hexagonal phase CuS. XPS spectra show that the ratio of Cu/S is about 1:1.084. The morphology was characterized by scanning electron microscopy (SEM) and field emission scanning electron microscopy (FE-SEM) techniques. Transmission electron microscopy (TEM) and high-resolution transmission electron microscopy (HRTEM) images reveal that nanocones and nanobelts grow along the [110] axis. The surfactant is found to be critical to the morphologies of the products. The possible formation mechanism is also discussed.