journal article·2017-11

Nucleation and growth of hexagonal CaAl 2 Si 2 O 8 crystals in CaO–Al 2 O 3 –SiO 2 glass

Kei Maeda, Atsuo Yasumori

Materials Letters· Volume 206
Publisher page

Abstract

Abstract Hexagonal CaAl 2 Si 2 O 8 was precipitated inside of 25CaO–20Al 2 O 3 –55SiO 2 (wt%) glass by heat treatment at 1050 °C with MoO 3 and carbon as nucleating agents. Transmission electron microscopy revealed that metallic molybdenum particles with sizes of ∼200 nm precipitated in the glass and served as heterogeneous nucleation sites for plane-like hexagonal CaAl 2 Si 2 O 8 crystals with widths greater than 10 μm and thicknesses of ∼1 μm. The thickness direction was the c -axis of hexagonal CaAl 2 Si 2 O 8 .
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Research context

OpenAlex topics: Glass properties and applications · Luminescence Properties of Advanced Materials · Advanced ceramic materials synthesis

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References (12)

Show source-provided references
1. Höland · 2012
2. 2. 2. 6 SiO2-Al2O3-CaO (Wollastonite), in: Glass-Ceramic Technology, second ed., Wiley, 2012, pp. 114–116.
3. Chapter 7, Slagsitall, in: Z. Strnad (Ed.), Glass-Ceramic Materials, Elsevier, 1986, pp. 230–234.
4. 2. 2. 9 SiO2-Al2O3-CaO (Slag Sital), in: Glass-Ceramic Technology, second ed., Wiley, 2012, pp. 123–126.
5. Deer · 2001
6. The crystal structure of hexagonal CaAl2Si2O810.1107/S0365110X59001396 ↗
7. High temperature solvent growth of anorthite on the join CaAl2Si2O8–SiO210.1007/BF00371307 ↗
8. Nucleation, growth and stability of CaAl2Si2O8 polymorphs10.1007/BF00202227 ↗
9. Hexagonal CaAl2Si2O8 in a high temperature solution; metastable crystallization and transformation to anorthite10.2465/minerj.17.257 ↗
10. Mineral Data Publishing, Mineralogical Society of America, 2001.
11. Dmisteinbergite CaAl2Si2O8 (hexagonal) – a new mineral
12. Toughening of CaO–Al2O3–SiO2 glass by dmisteinbergite precipitation10.1016/j.matlet.2016.05.123 ↗