Laser ablation: A new technique for the preparation of metal-organic frameworks Cu3(BTC)2(H2O)3
Source abstract
Abstract
Abstract This paper presents a chemical bottom-up synthesis of highly crystalline sub micro structured metal organic framework Cu3(BTC)2(H2O)3 (HKUST-1, BTC=benzene-1,3,5-tricarboxylate) prepared for the first time by a Laser ablation technique in liquid environment. The experiment consists of the ablation of a Cu metal target in a solution of DMF/H2O (1:1) containing benzene 1,3,5, benzene tricarboxilic acid and NaNO3 with a high power second harmonic of a Nd:YAG laser. The X-ray and SEM measurements showed that high crystalline Cu3(BTC)2(H2O)3 with octahedral morphology and dimensions in the range of 200 nm to 2 µm were obtained in a high yield.
Source: openaire · Quality: candidate unverified · Source record ↗
Research context
OpenAlex topics: Laser-Ablation Synthesis of Nanoparticles · Magnetism in coordination complexes · Nanocluster Synthesis and Applications
SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.
References (45)
Show source-provided references
1. Hybrid porous solids: past, present, future10.1039/B618320B ↗
2. Highly efficient separation of carbon dioxide by a metal–organic framework replete with open metal sites10.1073/pnas.0909718106 ↗
3. A pillared-layer coordination polymer network displaying hysteretic sorption: [Cu2(pzdc)2(dpyg)]n (pzdc=Pyrazine-2,3-dicarboxylate; dpyg=1,2-Di(4-pyridyl)glycol)10.1002/1521-3773(20020104)41:1<133::AID-ANIE133>3.0.CO;2-R ↗
4. Metallo-organic molecular sieve for gas separation and purification10.1016/S1387-1811(02)00405-5 ↗
5. Probing the lewis acidity and catalytic activity of the metal–organic framework [Cu3(btc)2] (BTC=Benzene-1,3,5-tricarboxylate)10.1002/chem.200600220 ↗
6. Ionothermal synthesis of the metal-organic framework compound Cu3(BTC)210.1016/S0167-2991(08)80240-6 ↗
7. The ionothermal synthesis of metal organic frameworks, Ln(C9O6H3)((CH3NH)2CO)2, using deep eutectic solvents10.1016/j.solidstatesciences.2009.05.023 ↗
8. Eutectic mixture of choline chloride/urea as a green solvent in synthesis of a coordination polymer: [Zn(O3PCH2CO2)]·NH410.1016/j.inoche.2005.01.025 ↗
9. Versatile structure-directing roles of deep-eutectic solvents and their implication in the generation of porosity and open metal sites for gas storage10.1002/anie.200900134 ↗
10. Ionothermal materials synthesis using unstable deep-eutectic solvents as template-delivery agents10.1002/ange.200600290 ↗
11. Hierarchical porous silica materials with a trimodal pore system using surfactant templates10.1021/ja0470618 ↗
12. Tb3+→Eu3+ energy transfer in mixed-lanthanide-organic frameworks10.1021/jp3054789 ↗
13. A chromium terephthalate-based solid with unusually large pore volumes and surface area10.1126/science.1116275 ↗
14. Ionic liquid as solvent for the synthesis and crystallization of a coordination polymer: (EMI)[Cd(BTC)] (EMI=1-Ethyl-3-methylimidazolium, BTC=1,3,5-Benzenetricarboxylate)10.1021/cg0504197 ↗
15. Ionothermal synthesis of a 3D Zn-BTC metal-organic framework with distorted tetranuclear [Zn4(m4-O)] subunits10.1016/j.inoche.2008.07.001 ↗
16. Zinc(II)–boron(III)-imidazolate framework (ZBIF) with unusual pentagonal channels prepared from deep eutectic solvent10.1039/B920318B ↗
17. Chiral induction in the ionothermal synthesis of a 3-d coordination polymer10.1021/ja070671y ↗
18. Ionothermal synthesis of zeolites, metal-organic frameworks, and inorganic-organic hybrids10.1021/ar700025k ↗
19. Ultrasound in materials chemistry10.1039/jm9960601605 ↗
20. Sonochemical synthesis of amorphous iron10.1038/353414a0 ↗
21. Effect of cavitation conditions on amorphous metal synthesis10.1016/0041-624X(92)90068-W ↗
22. Laser ablation in liquids: applications in the synthesis of nanocrystals10.1016/j.pmatsci.2006.10.016 ↗
23. Nanomaterials via laser ablation/irradiation in liquid: a review10.1002/adfm.201102295 ↗
24. Full physical preparation of size-selected gold nanoparticles in solution: laser ablation and laser-induced size control10.1021/jp020577y ↗
25. Formation of stable platinum nanoparticles by laser ablation in water10.1021/jp021580k ↗
26. Structure and stability of silver nanoparticles in aqueous solution produced by laser ablation10.1021/jp001803b ↗
27. Formation and size control of silver nanoparticles by laser ablation in aqueous solution10.1021/jp001336y ↗
28. Synthesis of silver nanoparticles by laser ablation in pure water10.1007/s00339-004-2841-5 ↗
29. Colloidal stability of gold nanoparticles in 2-propanol under laser irradiation10.1021/jp963107a ↗
30. Stabilization and size control of gold nanoparticles during laser ablation in aqueous cyclodextrins10.1021/ja048678s ↗
31. Nanostructured hydrocerussite compound (Pb3(CO3)2(OH)2) prepared by laser ablation technique in liquid environment10.1016/j.materresbull.2013.08.030 ↗
32. The generation of laser shock waves in a water-confinement regime with 50ns and 150ns XeCl excimer laser pulses10.1088/0022-3727/33/17/308 ↗
33. Experimental determination by PVDF and EMV techniques of shock amplitudes induced by 0.6–3ns laser pulses in a confined regime with water10.1088/0022-3727/33/5/305 ↗
34. Pulsed-laser-induced reactive quenching at liquid-solid interface: aqueous oxidation of iron10.1103/PhysRevLett.58.238 ↗
35. Preparation of nano-crystalline diamonds using pulsed laser induced reactive quenching
36. A chemically functionalizable nanoporous material [Cu3(TMA)2(H2O)3]n10.1126/science.283.5405.1148 ↗
37. Microwave synthesis of hybrid inorganic-organic materials including porous Cu3(BTC)2 from Cu(II)-trimesate mixture10.1016/j.micromeso.2008.10.035 ↗
38. Nitrate-induced photooxidation of trace organic chemicals in water10.1021/es00159a004 ↗
39. Conducting polymer photopolymerization mechanism: the role of nitrate ions (NO3−)10.1016/j.synthmet.2009.09.033 ↗
40. Sonolysis of dimethyl sulfoxide-water mixtures: a spin-trapping study10.1021/j100104a042 ↗
41. Studies on the mechanism of chemical radioprotection by dimethyl sulphoxide10.1080/09553007314551431 ↗
42. Synthesis of metalorganic frameworks (MOFs) with microwave or ultrasound: rapid reaction, phase-selectivity, and size reduction10.1016/j.ccr.2014.10.008 ↗
43. Nanoscaled ceramic powders produced by laser ablation10.1016/S0921-5107(02)00291-X ↗
44. Rapid production of metal-organic frameworks via microwave-assisted solvothermal synthesis10.1021/ja0635231 ↗
45. Laser-induced size reduction of noble metal particles10.1021/jp983503o ↗