Oppositely-charged coordination cages form a type I porous ionic liquid with two pore sizes
Source abstract
Abstract
Here we introduce a new type of porous liquid that combines two coordination cages in a single salt. This material is prepared through the ion metathesis of two oppositely-charged cages: one charged +20, and the other with a -16 charge. This ionic liquid has higher porosity than previously reported systems, because both of its components are hollow cages. The enhanced porosity holds promise for improving performance in chemical separations or storage, reflecting the guest-binding selectivity of the two cages, and the applications accessible due to its liquid nature.
Source: openalex_inverted_index · Quality: candidate unverified · Source record ↗
Research context
OpenAlex topics: Ionic liquids properties and applications · Supramolecular Chemistry and Complexes · Dielectric materials and actuators
SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.
Affiliations
Yusuf Hamied Department of Chemistry, University of Cambridge, CB2 1EW Cambridge, UK
Area Science Park, 34149 Basovizza, Italy
CNR-IMEM Institute, Parco Area delle Scienze 37/A, 43124 Parma, Italy
Department of Chemical and Pharmaceutical Sciences, University of Trieste, 34127 Trieste, Italy
INSTM, University of Trieste, 34127 Trieste, Italy
Funding
European Research Council · NextGenerationEU · Engineering and Physical Sciences Research Council
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