journal article·2023Open access

Composite formation of covalent organic framework crystals and sugar alcohols for exploring a new class of heat-storage materials

Yoichi Murakami, Shoma Mitsui, Shiori Nakagawa, Xiaohan Wang, Hiroki Fujisawa, Meguya Ryu, Junko Morikawa

Materials Horizons· Volume 10· Issue 11

Abstract

We impregnated the sugar alcohols (SAs) erythritol and mannitol (Man) in >0.1 mm single crystals of a covalent organic framework, COF-300, to propose new solid-state heat storing materials. The fusion-freezing cycles of the Man-COF composite occur in a narrow range of 130-155 °C without large or random supercooling, which has been a crucial problem of SAs, indicating the significance of this materials concept. The Man-COF composite displayed two endothermic and two exothermic features in the heating/cooling cycles. We measured the heat transmission properties in detail, based on which we discuss and suggest a postulate on the phase change behaviour of Man in the pores of the COF.
Source: openalex_inverted_index · Quality: candidate unverified · Source record ↗

Research context

OpenAlex topics: Covalent Organic Framework Applications · Metal-Organic Frameworks: Synthesis and Applications · Membrane Separation and Gas Transport

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

Affiliations

Laboratory for Zero-Carbon Energy, Institute of Innovative Research, Tokyo Institute of Technology, 2-12-1 Ookayama, Meguro-ku, Tokyo 152-8550, Japan

Department of Mechanical Engineering, School of Engineering, Tokyo Institute of Technology, 2-12-1 Ookayama, Meguro-ku, Tokyo 152-8552, Japan

Department of Transdisciplinary Science and Engineering, School of Environment and Society, Tokyo Institute of Technology, 2-12-1 Ookayama, Meguro-ku, Tokyo 152-8552, Japan

PRESTO, JST, 4-1-8 Honcho, Kawaguchi, Saitama 332-0012, Japan

Department of Organic and Polymeric Materials, School of Materials and Chemical Technology, Tokyo Institute of Technology, 2-12-1, Ookayama, Meguro-ku, Tokyo 152-8550, Japan

National Metrology Institute of Japan, National Institute of Advanced Industrial Science and Technology (AIST), 1-1-1 Umezono, Tsukuba, Ibaraki, 305-8563, Japan

CRESTO, JST, 4-1-8 Honcho, Kawaguchi, Saitama 332-0012, Japan

Funding

Japan Science and Technology Agency · Japan Society for the Promotion of Science

References (39)

Show source-provided references
1. Tomassetti · J. Energy Storage · 2022 · 55 · 10545610.1016/j.est.2022.105456 ↗
2. del Barrio · Sol. Energy Mater. Sol. Cells · 2017 · 159 · 56010.1016/j.solmat.2016.10.009 ↗
3. Papapetrou · Appl. Therm. Eng. · 2018 · 138 · 20710.1016/j.applthermaleng.2018.04.043 ↗
4. Garofalo · Energy Technol. · 2020 · 8 · 200041310.1002/ente.202000413 ↗
5. Solé · Sol. Energy Mater. Sol. Cells · 2014 · 126 · 12510.1016/j.solmat.2014.03.020 ↗
6. Pitkinen · Thermochim. Acta · 1993 · 214 · 15710.1016/0040-6031(93)80051-B ↗
7. Barreneche · Sol. Energy · 2013 · 94 · 34410.1016/j.solener.2013.05.023 ↗
8. Luna · Appl. Sci. · 2021 · 11 · 544810.3390/app11125448 ↗
9. Shamseddine · Renewable Sustainable Energy Rev. · 2022 · 158 · 11217210.1016/j.rser.2022.112172 ↗
10. Mojiri · Sol. Energy Mater. Sol. Cells · 2018 · 176 · 15010.1016/j.solmat.2017.11.028 ↗
11. Bayón · AIMS Energy · 2017 · 5 · 40410.3934/energy.2017.3.404 ↗
12. Neumann · Thermochim. Acta · 2018 · 660 · 13410.1016/j.tca.2017.12.026 ↗
13. Neumann · Sol. Energy Mater. Sol. Cells · 2019 · 200 · 10991310.1016/j.solmat.2019.109913 ↗
14. Nomura · Mater. Chem. Phys. · 2009 · 115 · 84610.1016/j.matchemphys.2009.02.045 ↗
15. Sagara · Mater. Chem. Phys. · 2014 · 146 · 25310.1016/j.matchemphys.2014.03.009 ↗
16. Xu · Sol. Energy Mater. Sol. Cells · 2016 · 155 · 14110.1016/j.solmat.2016.06.003 ↗
17. He · Sol. Energy Mater. Sol. Cells · 2020 · 209 · 11047310.1016/j.solmat.2020.110473 ↗
18. Hackl · J. Mater. Chem. A · 2020 · 8 · 2379510.1039/D0TA05019A ↗
19. El-Kaderi · Science · 2017 · 316 · 26810.1126/science.1139915 ↗
20. Diercks · Science · 2017 · 355 · 92310.1126/science.aal1585 ↗
21. Chen · Angew. Chem., Int. Ed. · 2020 · 59 · 505010.1002/anie.201904291 ↗
22. Ma · Science · 2018 · 361 · 4810.1126/science.aat7679 ↗
23. Chen · J. Am. Chem. Soc. · 2019 · 141 · 329810.1021/jacs.8b13691 ↗
24. Wang · Chem. Commun. · 2021 · 57 · 665610.1039/D1CC01857D ↗
25. Zhang · Angew. Chem., Int. Ed. · 2023 · 62 · e20221456910.1002/anie.202214569 ↗
26. Nakano · J. Phys. Chem. C · 2015 · 119 · 476910.1021/jp510048g ↗
27. Burger · J. Pharm. Sci. · 2000 · 89 · 45710.1002/(SICI)1520-6017(200004)89:4<457::AID-JPS3>3.0.CO;2-G ↗
28. Raemy · J. Therm. Anal. · 1983 · 28 · 9510.1007/BF02105282 ↗
29. Maruyama · AIP Conf. Proc. · 2004 · 708 · 67510.1063/1.1764256 ↗
30. Suzuki · Nano Lett. · 2015 · 15 · 198710.1021/nl504855z ↗
31. Grigoriadis · ACS Nano · 2011 · 5 · 920810.1021/nn203448c ↗
32. Fronczek · Acta Crystallogr., Sect. C: Cryst. Struct. Commun. · 2003 · 59 · o56710.1107/S0108270103018961 ↗
33. Hashimoto · Thermochim. Acta · 1997 · 304 · 15110.1016/S0040-6031(97)00026-9 ↗
34. Orie · Thermochim. Acta · 2012 · 532 · 14810.1016/j.tca.2011.08.017 ↗
35. Ryu · Appl. Phys. Lett. · 2021 · 119 · 25190210.1063/5.0055707 ↗
36. ISO 22007-3:2008. URL: https://www.iso.org/standard/41063.html
37. dos Santos · Polym. Test. · 2005 · 24 · 62810.1016/j.polymertesting.2005.03.007 ↗
38. Zamengo · Appl. Therm. Eng. · 2017 · 117 · 37610.1016/j.applthermaleng.2017.02.040 ↗
39. Agarwal · J. Therm. Anal. Calorim. · 2018 · 134 · 118310.1007/s10973-018-7468-4 ↗