Effects of element addition on liquid phase separation of Bi-Ga immiscible alloy: Characterization by electrical resistivity and coordination tendency
Source abstract
Abstract
Abstract The application of immiscible alloys is limited by their macrosegregation caused by liquid phase separation upon solidification. So liquid phase separation tendency is the primary factor should be concerned in the design of an immiscible alloy. In present work, the effects of tin and indium additions on liquid phase separation of Bi33.3Ga66.7 (at.%) immiscible alloy were studied by electrical resistivity measurement. It is observed that the liquid phase separation tendency of Bi33.3Ga66.7 alloy is weakened by tin but enhanced by indium addition within a minor quantity. Based on thermodynamic calculations, the effects of element additions on liquid phase separation of immiscible alloy were understood in the viewpoint of coordination tendency between elements: liquid phase separation tendency of immiscible alloy is weakened by the element addition which presents homo-coordination tendency with both the constituent elements of the immiscible alloy in liquid state; liquid phase separation tendency is enhanced by the element addition which presents hetero-coordination tendency with one of the constituent elements of the immiscible alloy but homo-coordination tendency with the other in liquid state.
Source: openaire · Quality: candidate unverified · Source record ↗
Research context
OpenAlex topics: Thermodynamic and Structural Properties of Metals and Alloys · Metallurgical and Alloy Processes · Solidification and crystal growth phenomena
SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.
References (27)
Show source-provided references
1. Liquid Immiscible Alloys10.1016/0927-796X(95)00180-8 ↗
2. Effect of TiC particles on the liquid–liquid decomposition of Al–Pb alloys10.1016/j.matdes.2015.11.090 ↗
3. Microstructural development during transient directional solidification of hypermonotectic Al–Bi alloys10.1016/j.matdes.2010.05.046 ↗
4. High-efficiency control of phase separation in Al-based immiscible alloys by TiC particles10.1016/j.jallcom.2015.03.194 ↗
5. Dendritic growth in undercooled Ni–25 wt.%Pb alloy melts10.1016/j.matdes.2005.08.010 ↗
6. Microstructure–wear behavior correlation on a directionally solidified Al–In monotectic alloy10.1016/j.triboint.2013.05.009 ↗
7. Controlling droplet distribution using thermoelectric magnetic forces during bulk solidification processing of a Zn–6wt.% Bi immiscible alloy10.1016/j.matdes.2016.03.078 ↗
8. Effect of a transverse magnetic field on solidification structure in directionally solidified Sn-Pb hypoeutectic alloys10.1016/j.jcrysgro.2014.06.031 ↗
9. Characteristics of liquid-liquid immiscibility in Al-Bi-Cu, Al-Bi-Si, and Al-Bi-Sn monotectic alloys
10. Effect of Y and Ni addition on liquid immiscibility in Cu-Zr-Ag ternary alloys10.1016/j.jallcom.2013.12.087 ↗
11. Effect of the magnetism of manganese on the resistivity of liquid manganese–zinc alloys10.1016/j.jnoncrysol.2007.05.055 ↗
12. The electrical resistivity of liquid Pb-Bi alloy10.1142/S0217984906009037 ↗
13. Experimental investigation and thermodynamic calculation of the Bi-Ga-Sn phase equilibria10.1016/j.jpcs.2009.07.010 ↗
14. Thermodynamic calculations and characterization of the Bi-Ga-In ternary alloys10.1016/j.jallcom.2015.12.233 ↗
15. Thermodynamic properties of some gallium-based binary alloys10.1016/j.physb.2008.01.026 ↗
16. Short range order and concentration fluctuations in regular and compound forming molten alloys10.1080/00319108208080752 ↗
17. Short-range order and concentration fluctuations in binary molten alloys10.1139/p87-038 ↗
18. Structural aspects of the electrical resistivity of binary alloys10.1103/PhysRevB.2.3004 ↗
19. Demixing tendencies in some Sn-based liquid alloys10.1016/S0925-8388(99)00232-7 ↗
20. Predel · 2006
21. Correlation between bulk and surface phenomena in Ga-(Bi,In) and In-Bi liquid alloys10.1142/S0217979201007178 ↗
22. Thermodynamic properties and phase equilibria of Sn-Bi-Zn ternary alloys10.1016/j.matchemphys.2008.05.034 ↗
23. Thermodynamic investigation of viscosity in Cu–Bi and Bi–Zn liquid alloys10.1016/S0925-8388(97)00547-1 ↗
24. Thermodynamics and surface properties of liquid Bi-In alloys10.1016/j.calphad.2008.09.002 ↗
25. Thermodynamic properties of liquid Al-Si and Al-Cu alloys10.1023/A:1022285010138 ↗
26. Thermodynamics of liquid and undercooled liquid Al–Ni–Si alloys10.1016/S0925-8388(00)00696-4 ↗
27. Resistance–temperature relation and atom cluster estimation of In–Bi system melts10.1016/j.matchemphys.2012.01.096 ↗