Defects, microstructure and properties in additive manufacturing of TiAl alloys: Formation mechanisms, influencing factors and improvement strategies
Source abstract
Abstract
TiAl alloys are pivotal for aero-engine applications due to exceptional high-temperature properties, yet their inherent brittleness challenges traditional manufacturing. Additive manufacturing (AM) techniques, including electron beam melting (EBM), laser-based methods (LAM), and directed energy deposition-arc (DED-arc), offer innovative pathways to overcome these limitations. This review systematically analyses defects (cracking and Al loss) formation mechanisms of AM-fabricated TiAl alloys. EBM, with high preheating, effectively suppresses cracking but exacerbates Al loss under vacuum, while LAM minimizes Al evaporation yet suffers from thermal stress-induced cracks. DED-arc balances cost-efficiency and density but faces compositional inhomogeneity. Subsequently, we discuss microstructural characteristics, evolution mechanisms, and property features and failure mechanisms, including tensile strength, fracture toughness, creep, fatigue, oxidation, and wear resistance. Regulation strategies, such as process optimization, alloying and heat treatment, are also analysed systematically to address defects and enhance performance. Additionally, the current research status of AM-fabricated TiAl-based bimetallic structures is scrutinized, revealing challenges in interface bonding and properties enhancement. Finally, we outline future research directions, emphasizing the need for standardized AM processes, advanced alloying designs, and multi-energy field coupling techniques to achieve large-scale, crack-free TiAl components with superior mechanical properties. This review serves as a valuable reference for advancing high-quality AM of TiAl alloys.
Source: openalex_inverted_index · Quality: baseline
Research context
OpenAlex topics: Intermetallics and Advanced Alloy Properties · MXene and MAX Phase Materials · Energetic Materials and Combustion
SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.
References (100+)
Show source-provided references
1. Introduction
2. Microstructure and mechanical properties of consolidated gamma titanium aluminides10.1179/174329007X186471 ↗
3. Advances in optimisation of mechanical properties in cast TiAl alloys10.1016/j.intermet.2004.12.002 ↗
4. Progress in the understanding of gamma titanium aluminides10.1007/BF03221103 ↗
5. Intermetallic titanium aluminides in aerospace applications – processing, microstructure and properties10.1080/09603409.2016.1163792 ↗
6. Titanium aluminides10.1016/B978-0-85709-346-2.00004-2 ↗
7. Novel design concepts for gamma-base titanium aluminide alloys10.1016/S0966-9795(00)00036-4 ↗
8. Electron beam melting of Ti–48Al–2Cr–2Nb alloy: microstructure and mechanical properties investigation10.1016/j.intermet.2010.11.017 ↗
9. Manufacturing technology for gamma-TiAl alloy in current and future applications10.1007/s12598-011-0288-3 ↗
10. History and development of γ-TiAl alloys and the effect of alloying elements on their phase transformations10.1016/j.jallcom.2022.164811 ↗
11. Blackburn · 1982
12. The effects of Cr additions to binary TiAl-base alloys10.1007/BF02851355 ↗
13. Phase transformations and microstructures10.1002/9783527636204.ch4 ↗
14. Processing 4th generation titanium aluminides via electron beam based additive manufacturing – characterization of microstructure and mechanical properties10.1016/j.mtla.2020.100902 ↗
15. Titanium aluminum alloys modified by chromium and niobium and method of preparation
16. Kim · 1995
17. Advances in gammalloy materials–processes–application technology: successes, dilemmas, and future10.1007/s11837-018-2747-x ↗
18. Enhancing the high-temperature mechanical property and microstructure stability in Ti-4822 matrix composites via Ti/Al transition layer10.1016/j.ceramint.2024.02.079 ↗
19. Reinforcement of TiAl alloy by evenly distributed micron-/nano-Y2O3 particles10.1016/j.matchar.2023.113316 ↗
20. High-temperature oxidation resistance of (Al2O3–Y2O3)/(Y2O3-stabilized ZrO2) laminated coating on 8Nb–TiAl alloy prepared by a novel spray pyrolysis10.1016/j.corsci.2013.08.029 ↗
21. In situ tailoring of precipitation behavior and improving mechanical properties of (Ti2AlC+Y2O3) reinforced TiAl alloy produced by directed energy deposition10.1016/j.msea.2024.146937 ↗
22. Hierarchically heterogeneous strategy for Ti2AlC/TiAl composite with superior mechanical properties10.1016/j.compositesb.2024.111259 ↗
23. Synchronous manipulation of heterointerfaces and atomic hybrids in bimetallic MAX phase composites for advanced electromagnetic wave absorption10.1016/j.compositesb.2023.111148 ↗
24. Fabrication and mechanical properties of Ti2AlN/TiAl composite with continuous network structure10.1016/S1003-6326(23)66194-1 ↗
25. Appel · 2011
26. Design of novel β‐solidifying TiAl alloys with adjustable β/B2‐phase fraction and excellent hot‐workability10.1002/adem.200800164 ↗
27. Microstructure and mechanical properties of a high Nb-TiAl alloy fabricated by electron beam melting10.1016/j.matdes.2018.09.044 ↗
28. Grain refinement of TiAl-based alloys: the role of TiB2 crystallography and growth10.1016/j.actamat.2010.08.040 ↗
29. Effect of boron concentration on phase transformation texture in as-solidified Ti44Al8NbxB10.1016/j.scriptamat.2012.03.023 ↗
30. Habel · 2016 · 1223
31. Titanium aluminides for aerospace and automotive applications processed by electron beam melting: contribution of politecnico di torino10.1016/j.mprp.2016.02.058 ↗
32. Bewlay · 2013 · 49
33. Additive manufacturing of titanium aluminides10.1016/B978-0-12-814062-8.00013-3 ↗
34. TiAl alloys in commercial aircraft engines10.1080/09603409.2016.1183068 ↗
35. Recent progress in the development of gamma titanium aluminide alloys10.1002/1527-2648(200011)2:11<699::AID-ADEM699>3.0.CO;2-J ↗
36. Ordered intermetallic alloys, part III: Gamma titanium aluminides10.1007/BF03220745 ↗
37. Additive manufacturing of TiAl-based alloys
38. Additive manufacturing of gamma titanium aluminide alloys: a review10.1007/s10853-022-06896-4 ↗
39. Titanium aluminides processing by additive manufacturing – a review10.1007/s00170-022-08728-w ↗
40. The prospects for additive manufacturing of bulk TiAl alloy10.1080/09603409.2016.1171510 ↗
41. Achieving material diversity in wire arc additive manufacturing: leaping from alloys to composites via wire innovation10.1016/j.ijmachtools.2023.104103 ↗
42. Cormier · 2005
43. Freeform fabrication of titanium aluminide via electron beam melting using prealloyed and blended powders10.1155/2007/34737 ↗
44. Revealing mechanisms underlying powder reusability of Ti-48Al-2Cr-2Nb intermetallic in electron beam powder bed fusion process
45. Anisotropy of microstructure and tensile properties of Ti–48Al–2Cr–2Nb fabricated by electron beam melting10.1016/j.jallcom.2020.154684 ↗
46. Selective electron beam melting of Ti–48Al–2Nb–2Cr: microstructure and aluminium loss10.1016/j.intermet.2014.01.004 ↗
47. Electron beam melting of a β-solidifying intermetallic titanium aluminide alloy10.1002/adem.201900800 ↗
48. Characterization of in-situ alloyed and additively manufactured titanium aluminides10.1007/s11663-014-0144-6 ↗
49. Fabrication of γ-TiAl intermetallic alloy using the twin-wire plasma arc additive manufacturing process: microstructure evolution and mechanical properties10.1016/j.msea.2021.141056 ↗
50. Wire arc additive manufacturing of titanium aluminide alloys using two-wire TOP-TIG welding: processing, microstructures, and mechanical properties
51. Solidification behavior and microstructure of Ti-(37−52) at% Al alloys synthesized in situ via dual-wire electron beam freeform fabrication
52. Achieving equiaxed and lamellar TiAl alloys via cold-cathode electron beam additive manufacturing with dual-wire synergistic control10.1016/j.jmrt.2024.12.131 ↗
53. Twin-wire directed energy deposition-arc of Ti–48Al–2Cr–2Nb alloy: feasibility, microstructure, and tensile property investigation10.1016/j.msea.2022.143566 ↗
54. Modification of microstructure and mechanical properties for twin-wire directed energy deposition-arc fabricated Ti–48Al–2Cr–2Nb alloys via current regulation10.1016/j.msea.2024.146147 ↗
55. Study on crack generation of Ti-Al Alloy deposited by plasma arc welding arc10.1007/s11665-022-07351-w ↗
56. The mechanism of element inhomogeneity in TW-DED-arc fabricated γ-TiAl alloy10.1007/s40194-024-01697-6 ↗
57. Interplay of process, microstructure, and mechanical performance in electron beam-powder bed fusion of Ti48Al2Nb2Cr
58. Laser metal deposition of titanium aluminide composites
59. Intermetallic alloys based on gamma titanium aluminide10.1007/BF03220267 ↗
60. Machinability of titanium aluminides: a review
61. Mechanical properties of TiAl fabricated by electron beam melting — a review10.1007/s41230-021-1093-8 ↗
62. Advances in gamma titanium aluminides and their manufacturing techniques10.1016/j.paerosci.2012.04.001 ↗
63. Research progress on powder bed fusion additive manufacturing of TiAl-based alloy10.1007/s00170-024-13843-x ↗
64. The influence of alloying on the α2/(α2+ γ)/γ phase boundaries in TiAl based systems10.1016/S1359-6454(99)00415-2 ↗
65. Development of protective coatings for high-temperature metallic materials10.2514/1.9191 ↗
66. Oxidation protection of gamma-titanium aluminide using glass–ceramic coatings10.1016/j.surfcoat.2008.12.029 ↗
67. Phase equilibria and transformations in intermediate titanium aluminum alloys10.1016/0956-7151(93)90069-5 ↗
68. Crystallography and phase transformation mechanisms in TiAl-based alloys–a synthesis10.1016/j.intermet.2009.05.013 ↗
69. Alloy design concepts for refined gamma titanium aluminide based alloys10.1016/j.intermet.2006.05.003 ↗
70. Microstructure and properties of a beta-solidifying TiAl-based alloy with different refiners10.1007/s12598-015-0634-y ↗
71. Microstructure of cast γ-TiAl based alloy solidified from β phase region10.1016/S1003-6326(11)60702-4 ↗
72. Metadynamic recrystallization behaviour of β-solidified TiAl alloy during post-annealing after hot deformation10.1016/j.intermet.2019.106679 ↗
73. Microstructural evolution and dynamic recrystallization behaviour of β-γ TiAl-based alloy during hot compression10.1002/adem.201600546 ↗
74. Effect of Al content on phase transformation of rapidly solidified binary Ti-Al alloys10.3740/MRSK.2017.27.1.8 ↗
75. Influence of cooling rate on microstructure formation during rapid solidification of binary TiAl alloys10.1016/j.jallcom.2015.03.016 ↗
76. Effect of cooling rate and Y element on the microstructure of rapidly solidified TiAl alloys10.1016/j.jallcom.2010.02.054 ↗
77. Microstructures and tensile properties of massively transformed and aged Ti46Al8Nb and Ti46Al8Ta alloys10.1016/j.intermet.2008.09.006 ↗
78. Microstructure refinement via martensitic transformation in TiAl alloys10.1016/j.jallcom.2018.01.216 ↗
79. Microstructural refinement in cast TiAl alloys by solid state transformations10.1016/j.scriptamat.2004.12.021 ↗
80. A mixture of massive and feathery microstructures of Ti48Al2Cr2Nb alloy by high undercooled solidification10.1016/j.matchar.2014.09.016 ↗
81. Effect of heat treatment on microstructures and mechanical properties in a full lamellar PM TiAl alloy10.1590/S1516-14392012005000059 ↗
82. Effect of solidification parameters on microstructural characteristics and mechanical properties of directionally solidified binary TiAl alloy10.1016/j.jallcom.2015.05.160 ↗
83. Phase equilibria in the Ti–Al binary system10.1016/S1359-6454(00)00118-X ↗
84. Evolution of the microstructure and nanohardness of Ti–48at.%Al alloy solidified under high pressure10.1016/j.matdes.2011.08.030 ↗
85. Effects of Nb and Al on the microstructures and mechanical properties of high Nb containing TiAl base alloys10.1016/S0966-9795(02)00037-7 ↗
86. Research progress on additive manufacturing of TiAl-based alloys10.3901/JME.2021.08.115 ↗
87. Hall–Petch relation and boundary strengthening10.1016/j.scriptamat.2004.06.002 ↗
88. Development of TiAl alloys with excellent mechanical properties and oxidation resistance10.1016/j.matdes.2013.08.083 ↗
89. Effects of test orientation on fracture and fatigue crack growth behaviour of third generation as-cast Ti–48Al–2Nb–2Cr10.1016/j.intermet.2014.10.005 ↗
90. Effect of lamellar orientation on the strength and operating deformation mechanisms of fully lamellar TiAl alloys determined by micropillar compression10.1016/j.actamat.2016.10.034 ↗
91. Refining grain size of a TiAl alloy by cyclic heat treatment through discontinuous coarsening10.1016/S0966-9795(02)00126-7 ↗
92. Effect of cooling rate on the grain refinement of TiAl-based alloys by rapid heat treatment10.1016/S0167-577X(00)00167-1 ↗
93. Continuous-cooling-transformation (CCT) behaviors and fine-grained nearly lamellar (FGNL) microstructure formation in a cast Ti-48Al-4Nb-2Cr Alloy10.1007/s11661-020-05934-7 ↗
94. Phase transformation and microstructural evolution in Ti-44Al-4Nb-4Zr alloy during heat treatment10.1007/BF02586153 ↗
95. Effect of multi-stage heat treatment on mechanical properties and microstructure transformation of Ti–48Al–2Cr–2Nb alloy10.1016/j.msea.2021.141321 ↗
96. Experimental study of the effects of heat treatment on microstructure and grain size of a gamma TiAl alloy10.1016/S0966-9795(03)00028-1 ↗
97. Effects of lamellae spacing and colony size on the fracture resistance of a fully-lamellar TiAl alloy10.1016/0956-7151(94)00278-P ↗
98. Cracking behaviour of Ti-48Al-2Cr-2Nb alloy in powder bed fusion electron beam melting process10.1016/j.jmatprotec.2023.118104 ↗
99. Characterisation of titanium aluminide components manufactured by laser metal deposition10.1016/j.intermet.2017.11.013 ↗
100. From crack-prone to crack-free: eliminating cracks in additively manufactured Ti-48Al-2Cr-2Nb alloy by adjusting phase composition10.1016/j.matdes.2023.112025 ↗