Supramolecular Assemblies Obtained by Large Counteranion Incorporation in a Well-Oriented Polycationic Copolymer
Source abstract
Abstract
The anodic oxidation of a two bipyridiniums meso-substituted octaethylporphyrin leads to the coating of the working electrode by a cationic polymeric film. Description of the formation and morphological properties of this conducting film are presented along with the electrochemical synthesis of the initial porphyrinic subunit used as monomer for the electropolymerization. We investigated the effects of the counteranion on the morphology of the copolymer 2-poly-Zn where the initial regular arrangement of swollen coils aggregated in the form of "peanuts" all oriented in the same direction was strongly modified in the gain of a new still well oriented supramolecular structure.
Source: openalex_inverted_index · Quality: baseline
Research context
OpenAlex topics: Luminescence and Fluorescent Materials · Supramolecular Self-Assembly in Materials · Molecular Sensors and Ion Detection
SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.
Affiliations
Laboratoire de Chimie Physique, Equipe d'Electrochimie, U.M.R. 8000 au CNRS, Université Paris-Sud 11, Bâtiment 350, F - 91405 Orsay Cedex, Laboratoire d'Electrochimie et de Chimie Physique du Corps Solide, Institut de Chimie, U.M.R. 7177 au CNRS, Université Louis Pasteur, 4 rue Blaise Pascal, F - 67070 Strasbourg Cedex, and Key Laboratory of Molecular Engineering of Polymers, Ministry of Education, Fudan University, Shanghai 200433, PR China
References (16)
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