Transport Properties of Comb-Type Grafted and Normal-Type N-Isopropylacrylamide Hydrogel
Source abstract
Abstract
Transport properties of the comb-type grafted and normal-type N -isopropylacrylamide (NIPA) gel are investigated by gel filtration chromatography and a pulsed field gradient NMR technique with known standard probe molecules in terms of molecular weight cutoff and diffusion coefficient in and through the gels, respectively. The incorporation of NIPA grafted chains into NIPA gel makes the effective mesh size smaller and induces the additional friction between the probe molecule and gel network. One may control the maximum mesh size of the NIPA gel and thus the effective diffusivity of a probe molecule within a gel by incorporating grafted chains and by adjusting the temperature.
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Research context
OpenAlex topics: Hydrogels: synthesis, properties, applications · Advanced Polymer Synthesis and Characterization · Polymer Surface Interaction Studies
SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.
Affiliations
Department of Materials Technology, Chiba University, 1-33, Yayoi-cho, Inage-ku, Chiba-shi, Chiba 263-8522, Japan; Department of Physics, Kyushu University, 6-10-1, Hakozaki, Higashi-ku, Fukuoka-shi, Fukuoka 812-8581, Japan; Department of Ophthalmology, Nara Medical University, 840, Shijyo-cho, Kashihara-shi, Nara 634-8522, Japan; Chemical Analysis Center, Chiba University, 1−33, Yayoi-cho, Inage-ku, Chiba-shi, Chiba 263-8522, Japan; Graduate School of Science and Engineering, Kagoshima University,...
References (35)
Show source-provided references
1. Tanaka T. · Phys. Rev. Lett. · 1978 · 40 · 82010.1103/PhysRevLett.40.820 ↗
2. Tanaka T. · Phys. Rev. Lett. · 1980 · 45 · 163610.1103/PhysRevLett.45.1636 ↗
3. Hirokawa Y. · J. Chem. Phys. · 1984 · 81 · 637910.1063/1.447548 ↗
4. Shibayama M. · Adv. Polym. Sci. · 1993 · 109 · 110.1007/3-540-56791-7_1 ↗
5. Kiler J. · Macromolecules · 1990 · 23 · 494410.1021/ma00225a011 ↗
6. Suzuki A. · Nature · 1990 · 346 · 34510.1038/346345a0 ↗
7. Yoshida R. · Nature · 1995 · 374 · 24010.1038/374240a0 ↗
8. Okano, T.; Bae, Y. H.; Kim, S. W. InPulsed and Self-Regulated DrugDelivery System; Kost, J., Ed.; CRC Press: Boca Raton, FL, 1990; p 17.
9. Okano, T.; Yui, N.; Yokoyama, M.; Yoshida, R.Advances in PolymericSystems for Drug Delivery; Gordon & Breach Science Publishers: Yverdon, Switzerland, 1994; p 67.
10. Hoffman A. S. · J. Controlled Release · 1987 · 6 · 29710.1016/0168-3659(87)90083-6 ↗
11. Dusek K. · 1993
12. Okano T. · 2000
13. Yoshida R. · J. Controlled Release · 1994 · 32 · 9710.1016/0168-3659(94)90229-1 ↗
14. Aoki T. · Macromolecules · 1994 · 27 · 94710.1021/ma00082a010 ↗
15. Hoffman A. S. · J. Controlled Release · 1986 · 4 · 21310.1016/0168-3659(86)90005-2 ↗
16. Peppas N. A. · 1987
17. Tanaka T. · J. Chem. Phys. · 1979 · 70 · 121410.1063/1.437602 ↗
18. Kaneko Y. · Macromolecules · 1995 · 28 · 771710.1021/ma00127a018 ↗
19. Kaneko Y. · Polym. Gels Networks · 1998 · 6 · 33310.1016/S0966-7822(98)00022-7 ↗
20. Park T. G. · Biotechnol. Prog. · 1994 · 10 · 8210.1021/bp00025a010 ↗
21. Park T. G. · Appl. Biochem. Biotechnol. · 1988 · 19 · 110.1007/BF02921460 ↗
22. Dong, L. C.; Hoffman, A. S. InReversible Polymeric Gels andRelated Systems; Russo, P., Ed.; ACS Symposium Series 350; American Chemical Society: Washington, DC, 1987; p 236.
23. Holtzscherer C. · Colloids Surf. · 1988 · 29 · 41110.1016/0166-6622(88)80151-3 ↗
24. Candau F. · J. Colloid Interface Sci. · 1984 · 101 · 16710.1016/0021-9797(84)90017-1 ↗
25. Candau F. · Colloid Interface Sci. · 1986 · 104 · 39810.1016/0021-9797(86)90425-X ↗
26. Benoît H. · Pure Appl. Chem. · 1966 · 12 · 54510.1351/pac196612010545 ↗
27. Hecht A. M. · Macromolecules · 1985 · 18 · 216710.1021/ma00153a018 ↗
28. Stejskal E. O. · J. Chem. Phys. · 1965 · 42 · 28810.1063/1.1695690 ↗
29. Matsukawa S. · Macromolecules · 1996 · 29 · 713610.1021/ma960426r ↗
30. Matsukawa S. · Macromolecules · 1997 · 30 · 831010.1021/ma9702408 ↗
31. Matsukawa S. · Macromolecules · 1999 · 32 · 186510.1021/ma980791d ↗
32. Matsukawa S. · Macromolecules · 2001 · 34 · 143010.1021/ma001450e ↗
33. de Gennes P. G. · 1979
34. Langevin D. · Polymer · 1978 · 19 · 87510.1016/0032-3861(78)90191-X ↗
35. Cukier R. I. · Macromolecules · 1984 · 17 · 25210.1021/ma00132a023 ↗