Use of the Brönsted Equation in the Interpretation of Micellar Effects in Kinetics
Source abstract
Abstract
Micellar and salt effects on the reactions Ru(NH 3 ) 5 (pz) 2+ + S 2 O 8 2- and Ru(NH 3 ) 5 (pz) 2+ + Co(ox) 3 3- have been studied. It is shown that the well-known pseudophase model, an extension of the Olson−Simonson treatment to the micellar case, is equivalent to the Brönsted relation in regard to rationalization of the micellar effects. It is also shown that micellar systems behave as low-concentration/high-ionic-strength systems.
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Research context
OpenAlex topics: Chemical and Physical Properties in Aqueous Solutions · Surfactants and Colloidal Systems · Spectroscopy and Quantum Chemical Studies
SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.
Affiliations
Departamento de Química Física, Universidad de Sevilla, C/Profesor García González s/n, 41012 Sevilla, Spain
Department of Chemistry, University of Leicester, Leicester LE1 7RH, U.K.
References (30)
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