journal article·2022-09-27

Enhanced Tetracycline Adsorption of MoS2 via Defect Introduction Under Microwave Irradiation

Cheng Xie, Lei Xu, Ruiqi Gang, Libo Zhang, Qianjun Ye, Zhangbiao Xu

Langmuir· Volume 38· Issue 38
Publisher page

Abstract

Defect engineering is a promising method for improving the performance of MoS2 in various fields. In this study, sulfur-defect-enriched MoS2 (SD-MoS2) nanosheets were fabricated via a facile microwave-hydrothermal strategy in 10 min for tetracycline (TC) adsorption applications. The introduction of sulfur defects in MoS2 induced more exposed unsaturated sulfur atoms at the edge, enhancing the interaction between the adsorbent and antibiotic and improving the adsorption activity of the antibiotic. Density functional theory calculations further revealed that sulfur defects in MoS2 could alter the electronic structure and exhibited low TC adsorption energy of −2.09 eV. This work provides a new method for fabricating MoS2 nanosheets and other transition metal dichalcogenide-based adsorbents with enhanced antibiotic removal performance and a comprehensive understanding of antibiotic removal mechanisms in SD-MoS2.
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Research context

OpenAlex topics: MXene and MAX Phase Materials · 2D Materials and Applications · Advanced Photocatalysis Techniques

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

Affiliations

National Local Joint Laboratory of Engineering Application of Microwave Energy and Equipment Technology, Faculty of Metallurgical and Energy Engineering, Kunming University of Science and Technology, Kunming 650093, P. R. China

The Key Laboratory of Unconventional Metallurgy, Ministry of Education, Kunming 650093, P. R. China

Funding

Ministry of Science and Technology of the People's Republic of China · Natural Science Foundation of Yunnan Province · National Natural Science Foundation of China · Yunnan Science and Technology Major Project · Yunnan Provincial youth top notch talent support program · Yunnan Provincial Science and Technology Talents Program

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