journal article·2024-07-16

In Situ Growth of Columnar PEG on PEDOT and Its Antifouling Properties

Wenfeng Hai, Yang Liu, YuJia Tian, Zhiran Chen, Yingsong Chen, Wenji Bao, Tingfang Bai, Jinghai Liu, Yushuang Liu

Langmuir· Volume 40· Issue 28
Publisher page

Abstract

The antifouling properties of conductive polymers have received extensive attention for biosensor and bioelectronic applications. Polyethylene glycol (PEG) is a well-known antifouling material, but the controlled regulation of the surface topography of PEG without a template remains a challenge. Here, we show a columnar structure antifouling conductive polymer brush with enhanced antifouling properties and considerable conductivity. The method involves synthesizing the 3,4-ethylenedioxythiophene monomer modified with azide (EDOT-N 3 ), the electropolymerization of PEDOT-N 3, and the in situ growth of PEG polymer brushes on PEDOT through double-click reactions. The resultant columnar structure polymer brush exhibits high electrical conductivity (3.5 Ω·cm 2 ), ultrahigh antifouling property, electrochemical stability (capacitance retention was 93.8% after 2000 cycles of CV scans in serum), and biocompatibility.
Source: openalex_inverted_index · Quality: baseline

Research context

OpenAlex topics: Advanced Sensor and Energy Harvesting Materials · Conducting polymers and applications · Polymer Surface Interaction Studies

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

Affiliations

Inner Mongolia Key Laboratory of Carbon Nanomaterials, College of Chemistry and Chemical Engineering, Inner Mongolia Minzu University, Tongliao 028000, Inner Mongolia, China

Key Laboratory of Mongolian Medicine Research and Development Engineering, Ministry of Education, Tongliao 028000, Inner Mongolia, China

School of Medicine, Southeast University, Nanjing, Jiangsu Province 210000, China

School of Mongolian Medicine, Inner Mongolia Minzu University, Tong Liao 028000, Inner Mongolia, China

Funding

Government of Inner Mongolia Autonomous Region · Research Program of Science and Technology at Universities of Inner Mongolia Autonomous Region · Natural Science Foundation of Inner Mongolia Autonomous Region · National Natural Science Foundation of China · Program for Innovative Research Team in Universities of Inner Mongolia Autonomous Region

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